C14H4Br8 and synthesizing process

A technology of octabromodiphenylethane and its synthesis method, which is applied in the field of engineering plastics, can solve the problems of uneven dispersion, reduced plastic strength, and high melting point, and achieve the effects of good dispersion effect, reduced loss, and simple operation method

Active Publication Date: 2008-08-20
山东兄弟科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] The purpose of the present invention is to solve the disadvantages of high bromine content flame retardants in the prior art, which have a high melting point and exist in solid form during use and processing, and tend to be u

Method used

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  • C14H4Br8 and synthesizing process

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0038] Example 1:

[0039] (1) In a 1000mL four-necked bottle, put 72.8g of diphenylethane into 400mL of dibromomethane and dissolve it in 400mL of dibromomethane, then add 7.28g of iron powder, cool down with ice water, slowly add 175mL of bromine dropwise, keep the temperature below 20°C during the dropwise addition, add After keeping warm for 2 hours, add 50mL of 15% sodium sulfite to neutralize until the system is white or colorless, then separate into layers at rest, discard the water layer, and separate the materials;

[0040] (2) Add 100mL of 15% hydrochloric acid and 50mL of water respectively, raise the temperature and reflux for 30min, let the layers stand still, discard the water layer, and separate the materials;

[0041] (3) Add 300mL of water and 10mL of OS (MS-1) surfactant respectively, heat up and distill, raise to 85°C, the material precipitates, filter with suction, and dry in an oven at 100°C to obtain a white powder of octabromodiphenylethane 320g, yield ...

Example Embodiment

[0050] Example 2:

[0051] Others are the same as in Example 1, and the organic solvent is changed to 600ml of dichloromethane to obtain 322g of octabromodiphenylethane as a white powder, with a yield of 96.40%.

[0052] Analysis test: bromine content 80.06%, melting point 165-175 ℃, volatile matter 0.15%, whiteness 90.4.

Example Embodiment

[0053] Example 3:

[0054] Others are the same as in Example 1, the catalyst is replaced by 20 g of iron tribromide to obtain 320 g of white powder octabromodiphenylethane, the yield is 93.46%, the bromine content is 80.10%, the melting point is 165-175°C, the volatile matter is 0.15%, and the whiteness 90.4.

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Abstract

The invention relates to an additive flame retardant agent, in particular to an eight bromine diphenyl ethane and a synthesis method thereof, which is used for the engineering plastic field. The additive flame retardant agent uses an organic solvent to dissolute raw materials and products, adopts iron powder and ferric sesquibromide as a catalyst, and has short reaction time and good reaction effect; a solvent is recovered by concentration and distillation during the period of crystallization, and the organic solvent loss is greatly decreased. The additive flame agent is low in raw material cost and simple in operation method; the prepared product of 8 bromine diphenyl ethane is whitish and exists in form of solid with bromine content being 78 to 80 percent and melting point being between 150 to 180 DEG C, is easy in storage and transportation and low in melting point, exists in form of melting during the using and processing process, has good compatibility with plastic and good dispersing effect, and does not change the strength of the added plastic.

Description

technical field [0001] The invention relates to an additive flame retardant, specifically octabromodiphenylethane and its synthesis method, which are used in the field of engineering plastics. Background technique [0002] Brominated flame retardants are the most important and effective ones among halogen-containing flame retardants. They have high flame retardancy, low addition amount, and little influence on product processing and use characteristics. [0003] Many studies have shown that the refractory effect of halogenated organic compounds decreases in the order of iodine, bromine, chlorine, and fluorine. But in fact, iodide is unstable and in short supply, so it has not been used in practice. Chlorine and fluorine compounds are not as flame retardant as bromine. The flame retardant effect of bromine is generally 2.5-4 times higher than that of chlorine. This is because in structure, the binding strength of H-Br is greater than that of H-Cl, so the flame retardant eff...

Claims

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Application Information

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IPC IPC(8): C07C25/18C07C17/12C08K5/02
Inventor 郭秀安杨喜生柴家启
Owner 山东兄弟科技股份有限公司
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