Polyester resin special for winding steel paint base and preparation thereof
A technology of polyester resin and primer, applied in polyester coatings, coatings, anti-corrosion coatings, etc., can solve the problems of limited processing performance of pre-coated coils, poor pertinence, and failure to achieve processing effects, etc., to achieve Ease of large-scale production, low requirements for production equipment, and high solid content
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Embodiment 1
[0026] A special polyester resin for the primer in coil coatings, which comprises the following components in parts by weight:
[0027] 35 parts of ethylene glycol
[0028] 35 parts of terephthalic acid
[0029] Dibutyltin dilaurate 0.1 part
[0030] 3 parts xylene
[0031] 20 parts of ethylene glycol butyl ether.
[0032] The production method is as follows:
[0033] 1. Fill the reaction kettle with a stirrer, a thermometer (including two thermometers: one for measuring the liquid phase temperature, and one for measuring the gas phase temperature), a reflux condenser, and a water separator. Phthalic acid and catalyst dibutyltin dilaurate through N 2 Protection, start heating up. Start stirring intermittently when the material is 160°C, observe the material in the kettle until it is completely dissolved before starting the stirring formally. Control the temperature of the liquid material in the kettle between 150 and 250°C, and the temperature of the gas phase at 95°C a...
Embodiment 2
[0037] A special polyester resin for the primer in coil coatings, which comprises the following components in parts by weight:
[0038] Glycerin 40 parts
[0039] Trimellitic anhydride 40 parts
[0040] Dibutyltin diacetate 0.1 part
[0041] S-100# 3 copies
[0042] 20 parts of cyclohexanone.
[0043] The production method is as follows:
[0044] 1. Put glycerin, trimellitic anhydride and catalyst in a reaction kettle equipped with a stirrer, a thermometer (including two thermometers: one for measuring liquid phase temperature and one for measuring gas phase temperature), reflux condenser and water separator Dibutyltin diacetate, through CO 2 Protection, start heating up. Start stirring intermittently when the material is 160°C, observe the material in the kettle until it is completely dissolved before starting the stirring formally. Control the temperature of the liquid material in the kettle between 150 and 250°C, and the temperature of the gas phase at 95°C and 105°C...
Embodiment 3
[0048] A special polyester resin for the primer in coil coatings, which comprises the following components in parts by weight:
[0049] Pentaerythritol 30 parts
[0050] 30 parts of isophthalic acid
[0051] Monobutyltin oxide 0.1 parts
[0052] 3 parts xylene
[0053] 20 parts of n-butanol.
[0054] The production method is as follows:
[0055] 1. Fill the reaction kettle with a stirrer, a thermometer (including two thermometers: one for measuring the liquid phase temperature, and one for measuring the gas phase temperature), a reflux condenser, and a water separator with a formula amount of pentaerythritol and resorcinol. Formic acid and catalyst monobutyltin oxide, pass through N 2 Protection, start heating up. Start stirring intermittently when the material is 160°C, observe the material in the kettle until it is completely dissolved before starting the stirring formally. Control the temperature of the liquid material in the kettle between 150 and 250°C, and the tem...
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