Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Hyperbranched poly(aryl ether ketone), preparation method and application thereof in viscosity modifier

A poly(aryl ether ketone), polycondensation reaction technology, applied in the application of hyperbranched poly(aryl ether ketone) as a viscosity modifier, preparation of A2+BB2' type of hyperbranched poly(aryl ether ketone), hyperbranched poly(aryl ether ketone) It can solve the problems of cumbersome monomer synthesis process, limited industrialization, and difficulty in gelation.

Inactive Publication Date: 2009-02-04
JILIN UNIV
View PDF1 Cites 18 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The product obtained by the single monomer method (SMM) has good solubility, and the reaction is not easy to gel, which is suitable for theoretical research, but the monomer synthesis process is cumbersome and the price is generally expensive, which limits the possibility of further industrialization
The dual monomer method (DMM) uses two simple and easy-to-get monomers to react, and can control the structure and end groups of hyperbranched polymers by changing the structure and reaction ratio of the two monomers, but it is easy to gel. The disadvantages greatly limit its development

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Hyperbranched poly(aryl ether ketone), preparation method and application thereof in viscosity modifier
  • Hyperbranched poly(aryl ether ketone), preparation method and application thereof in viscosity modifier
  • Hyperbranched poly(aryl ether ketone), preparation method and application thereof in viscosity modifier

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] Embodiment 1: Synthesis of fluorine-terminated hyperbranched polyaryletherketone (HPEEK-F)

[0050] BB 2 Preparation of 'type monomer 2, 4', 6-trifluorobenzophenone: using 2,6 difluorobenzoyl chloride and fluorobenzene to prepare by using anhydrous aluminum trichloride as a catalyst through the acylation of 2,6 difluorobenzoyl chloride and fluorobenzene. 88.25g (0.5mol) of 2,6-difluorobenzoyl chloride, 80.1g (0.6mol) of anhydrous aluminum trichloride, and 600ml of fluorobenzene as a solvent in excess, refluxed at 84°C for 8h, discharged in ice hydrochloric acid water, and weighed with petroleum ether. crystallization. For the NMR characterization of the synthesized product, see Image 6 (CDCl 3 , 500Hz, ppm) δ = 7.88-7.92 (c-H, 2H) δ = 7.44-7.48 (a-H.1H) δ = 7.14-7.18 (d-H, 2H) δ = 6.90-7.03 (b-H, 2H) (Bruker 500MHz NMR) .

[0051] Will A 2 Type monomer hydroquinone 1.10g (0.01mol), BB 2 2.36g (0.01mol) of 'type monomer 2,4',6-trifluorobenzophenone, 0.483g (0.003...

Embodiment 2

[0057] Embodiment 2: Synthesis of fluorine-terminated hyperbranched polyaryletherketone (HPEEK-F)

[0058] Will A 2 Type monomer hydroquinone 1.0725g (0.00975mol), BB 2'Type monomer 2,4', 2.36g (0.01mol) of 6-trifluorobenzophenone, 0.4709g (0.00325mol) of anhydrous potassium carbonate, 0.7235g (0.0065mol) of anhydrous sodium carbonate, and 14g of sulfolane In a three-neck flask equipped with a stirring device, nitrogen gas is passed, stirred, and the temperature is raised. The salt formation temperature is controlled at 140°C for 2 hours, 170°C for 2 hours for prepolymerization, and 210°C for 5 hours. The material is discharged into deionized water, crushed, washed three times with boiling deionized water, and dried. Reflux with ethanol for 5 times, and dry to obtain 2.5 g of hyperbranched polyaryletherketone (HFPEEK-F) whose terminal group is fluorine-terminated, and the yield is about 70%.

[0059] The glass transition temperature Tg of HPEEK-F measured by DSC is 149°C, a...

Embodiment 3

[0060] Embodiment 3: Synthesis of fluorine-terminated hyperbranched polyaryletherketone (HPEEK-F)

[0061] Will A 2 Type monomer hydroquinone 0.99g (0.009mol), BB 2 'Type monomer 2,4', 2.36g (0.01mol) of 6-trifluorobenzophenone, 0.4347g (0.0030mol) of anhydrous potassium carbonate, 0.6678g (0.0060mol) of anhydrous sodium carbonate, and 14g of sulfolane In a three-neck flask equipped with a stirring device, nitrogen gas is passed, stirred, and the temperature is raised. The salt formation temperature is controlled at 140°C for 2 hours, 170°C for 2 hours for prepolymerization, and 210°C for 5 hours. The material is discharged into deionized water, crushed, washed three times with boiling deionized water, and dried. Reflux with ethanol for 5 times, and dry to obtain 2.7 g of hyperbranched polyaryletherketone (HFPEEK-F) whose terminal group is fluorine-terminated, and the yield is about 80%.

[0062] The glass transition temperature Tg of HPEEK-F measured by DSC is 134°C, and t...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Glass transition temperatureaaaaaaaaaa
Glass transition temperatureaaaaaaaaaa
Glass transition temperatureaaaaaaaaaa
Login to View More

Abstract

The invention relates to a hyperbranched poly (ether ketone), a preparation method thereof and application of the material in viscosity modifiers. The hyperbranched poly(ether ketone) is prepared wit BB2-type monomers 2, 4, 6 trifluoro phenyl ketone and A2-type monomers hydroquinone, resorcin, bisphenol A, and hexafluoro-bisphenol A or biphenyl diphenol as reactants, potassium carbonate or sodium carbonate or the mixture of the potassium carbonate and the sodium carbonate as a salification agent, and sulfolane or N, N-dimethyl ketopyrrolidine as a solvent through mixing, salification, polycondensation reaction and after treatment. The solid content is 20 to 30 percent; the dosage of the salification agent is 1 to 1.1 time of the dosage of the A2 monomers. Fluorine terminated hyperbranched polyaryletherketone and hydroxy terminated superbranched polyaryletherketone are got respectively by adjusting the ratio of the dosages of the BB2-type and A2-type monomers. The hyperbranched poly (ether ketone) is characterized in that by adding the superbranched polyaryletherketone, the mechanical property and the thermostability of linear polyaryletherketone are not reduced while the melt viscosity of the linear polyaryletherketone is reduced.

Description

technical field [0001] The invention belongs to the field of macromolecular materials, in particular to a kind of hyperbranched polyaryletherketone and hyperbranched polyaryletherketone A 2 +BB 2 ' type preparation method, and the application of the hyperbranched polyaryletherketone in viscosity regulator. Background technique [0002] Hyperbranched polymers are a type of highly branched polymers with a three-dimensional ellipsoidal structure. They have high solubility, low viscosity, and a large number of terminal functional groups. The development and application of , nonlinear optics and other aspects have broad prospects, and have become a hot spot in the field of polymer research in recent years. [0003] As a special engineering plastic, linear polyaryletherketone has excellent heat resistance, chemical corrosion resistance and good mechanical properties, and is widely used in high-tech fields such as aerospace, electronics and nuclear energy. However, as a semi-cry...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08G65/40C08L71/10
Inventor 姜振华李秀杰张淑玲王贵宾关绍巍
Owner JILIN UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com