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Process for preparing hydrogen storage sodalite composite material

A technology of composite materials and sodalite, which is applied in the field of production and preparation of inorganic functional materials, can solve the problems of low hydrogen storage capacity and achieve the effects of high industrialization, simple synthesis and high product performance

Inactive Publication Date: 2009-08-12
DALIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the van der Waals force between the medium and hydrogen, the hydrogen storage capacity of such materials is relatively low, and the hydrogen storage capacity at room temperature is even lower.
At present, there is a lack of a new material preparation technology that can increase the force between zeolite and hydrogen, so as to increase the hydrogen storage capacity of zeolite materials

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Example 1: Weigh 1.0 g of sodalite raw material, grind it for 15-30 minutes, and then sieve it. Mix with 100ml of nickel nitrate solution with a concentration of 0.1mol / L, and conduct ion exchange at a constant temperature of 60°C for 12h under the condition of electromagnetic stirring. After suction filtration and drying, reduce under hydrogen atmosphere at 600°C for 2h, and cool down to room temperature naturally to obtain a black powder sample. The hydrogen storage capacity of the obtained sodalite composite material can reach 16ml / g under normal pressure.

Embodiment 2

[0021] Example 2: Weigh 0.5 g of sodalite raw material, grind it for 15-30 minutes, and then sieve it. Mix with 50ml of ferrous sulfate solution with a concentration of 0.1mol / L, and conduct ion exchange at a constant temperature of 25°C for 4h under the condition of electromagnetic stirring. After suction filtration and drying, reduce under hydrogen atmosphere at 400°C for 4h, and cool down to room temperature naturally to obtain a black powder sample. The hydrogen storage capacity of the obtained sodalite composite material can reach 14ml / g under normal pressure.

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PUM

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Abstract

The invention discloses a method for preparing hydrogen storage sodalite composite material, belonging to the field of producing and preparing inorganic functional material. The method is characterized in that dried sodalite material is ground, is screened by 100-mesh sieve for separation and then added with transition metal ion water solution; after that, the material which is processed by ion exchange is obtained by ion exchange, suction filtration and drying at the constant temperature is obtained. The obtained material is deacidized under reducing atmosphere, and the sodalite composite material having higher adsorbance for hydrogen under the normal pressure can be obtain after procedure temperature reduction. The method has the advantages that the sodalite composite material having more hydrogen storage quantity under the normal pressure can be prepared; no detrimental impurity and waste emission can be caused in the whole preparation process; the method has remarkable advantages on preparation cost, production performance, process flow, environment-friendly property, economic profit and the like; the raw material is high in industrialization degree, low in cost, simple and convenient in synthesis, low in facility requirement, high in product performance and applicable to commercial process.

Description

technical field [0001] The invention belongs to the field of production and preparation of inorganic functional materials, and relates to a preparation method of a sodalite composite material with relatively large adsorption capacity for hydrogen under normal temperature and pressure. Background technique [0002] Existing hydrogen storage technologies can be roughly divided into five types: liquid hydrogen storage, high-pressure hydrogen storage, organic compound hydrogen storage, metal compound hydrogen storage and media adsorption hydrogen storage. [0003] Liquid hydrogen storage, due to the extremely low boiling point of hydrogen (20K), this method consumes a lot of energy, costs high, requires high equipment materials, and has harsh operating and service conditions. It is mostly used in high-tech fields such as rockets, spacecraft, and satellite launches; High-pressure hydrogen storage has high requirements on the material of hydrogen storage container, poor storage an...

Claims

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Application Information

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IPC IPC(8): C01B33/32B01J20/16C01B3/02
Inventor 胡涛孟长功吴晓金谭震
Owner DALIAN UNIV OF TECH
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