Colored curable resin composition, colored pattern forming method, colored pattern, method for manufacturing color filter, liquid crystal display element
A technology of curable resin and coloring pattern, which is applied in the direction of optical components, photoplate making process of pattern surface, instruments, etc.
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[0128] As the preparation method of titanium black, there is a method of heating and reducing the mixture of titanium dioxide and metallic titanium under a reducing atmosphere (Japanese Patent Application No. 49-5432). The method of reduction in reducing atmosphere (JP-A-57-205322), the method of reducing titanium dioxide or titanium hydroxide at high temperature in the presence of ammonia (JP-A-60-65069, JP-A-61-201610 ), a method of attaching a vanadium compound to titanium dioxide or titanium hydroxide and reducing it at high temperature in the presence of ammonia (JP-A-61-201610), etc., but these methods are not limited.
[0129] Examples of commercially available titanium black include titanium black 10S, 12S, 13R, 13M, and 13M-C manufactured by Mitsubishi Materials.
[0130] As examples of other black pigments, nigrosine, iron oxide-based black pigments, and three-color organic pigments of red, green, and blue can be mixed and used as black pigments.
[0131] In additio...
Embodiment 1
[0398] Components of the following compositions were mixed to prepare a pigment dispersion.
[0399] [Pigment dispersion]
[0400] ·Pigment (a)
[0401] C.I. Pigment Red 254 5 parts
[0402] C.I. Pigment Red 177 5 parts
[0403] ·Dispersion resin
[0404] Byk-161 by Bitsuku Chemi Co., Ltd. (active ingredient: 30 13.3 parts by mass%)
[0405] ·(b) Solvent
[0406] Propylene glycol monomethyl ether acetate 32.7 parts
[0407] In addition, the following components were mixed separately to prepare a transparent resist solution.
[0408] [Composition of transparent resist solution]
[0409] ・(c) Binder resin
[0410] 2.0 parts of acrylic resin (c1) represented by the following formula (6)
[0411] 2.0 parts of acrylic resin (c2) (A) shown in Table 1
[0412] ·(c3) Monomer
[0413] Dipentaerythritol hexaacrylate 4.0 parts
[0414] ·(d) Photopolymerization initiator
[0415] 0.4 parts of 2-(2-chlorophenyl)-4,5-diphenylimidazole dimer
[0416] 0.2 parts of 4,4'-bis(dieth...
Embodiment 2~4
[0447] Except having changed the binder resin (c2) in Example 1 into the compound shown in Table 2, it carried out similarly to Example 1, prepared the composition for coloring pattern formation, and evaluated it.
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