The invention discloses a polar crystal La3SbS4OCl2 and a preparation method thereof, and relates to the technical field of intraocular lens, the crystal is a sulfur-oxygen-chlorine mixed anion compound with a non-centrosymmetric structure, the crystal system is a hexagonal crystal system, the space group is P63mc, and the unit cell parameter unit cell volume is prepared in a way that under the protection of inert gas according to the stoichiometric ratio of La3SbS4OCl2, elemental lanthanum, lanthanum trichloride, elemental antimony, antimony trioxide and elemental sulfur are mixed and then put into a quartz tube, vacuumized, heated to 920-980 DEG C, a solid-phase chemical reaction is performed, and cooling is performed, thereby obtaining the product. According to the invention, the anti-laser-damage functional element is utilized to regulate and control the SbS3 triangular pyramid structure units of the polar functional element to realize equidirectional arrangement, so that the spontaneous polarization intensity is increased, the non-centrosymmetric structure is assembled on the molecular level, and the polar crystal La3SbS4OCl2 is successfully synthesized. The polar crystal has strong spontaneous polarization intensity and high laser damage threshold.