Comprehensive extraction and processing method of industrial wastewater
An industrial wastewater, comprehensive extraction technology, applied in heating water/sewage treatment, oxidized water/sewage treatment, water/sewage multi-stage treatment, etc. , energy saving, considerable economic benefits
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[0034] Embodiment: Taking the industrial wastewater containing sodium bromide, sodium acetate and methyl alcohol as an example, the treatment steps are as follows:
[0035] 1) Oxidation: In the oxidation kettle 1, at normal temperature, pass chlorine gas into the wastewater for oxidation until the pH is 7-0.5;
[0036] 2) esterification: then in esterification still 2, add industrial waste acid (hydrochloric acid) to carry out esterification reaction as catalyzer, waste acid add-on is 10wt% of waste water weight, in esterification still 2 internal esterification, the reaction time is 5-60 minutes, the reaction temperature is 55-65°C;
[0037] 3) Rectification: the reaction liquid in step 2) enters the middle part of the rectification tower 3, methyl acetate is fractionally distilled at the top of the tower at 55-58 °C, and methanol is separated at the upper middle part at 63-66 °C;
[0038] 4) Hydrolysis and distillation: Methyl acetate enters the hydrolysis and rectification...
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