Titanium/copper laminated composite electrode plate and preparation method thereof

A composite electrode and composite plate technology, which is applied in the direction of electrodes, electrolysis process, electrolysis components, etc., can solve the problems of high internal resistance of titanium electrode materials, etc., and achieve the effects of uniform current distribution, high product purity and simple preparation process

Inactive Publication Date: 2009-11-11
KUNMING UNIV OF SCI & TECH
View PDF0 Cites 12 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to provide a titanium / copper composite material with simple preparation process, low production cost, high material utilization rate, high dimensional accuracy and good electrical conductivity and its preparation method for the problem of large internal resistance of titanium electrode materials.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Titanium/copper laminated composite electrode plate and preparation method thereof
  • Titanium/copper laminated composite electrode plate and preparation method thereof
  • Titanium/copper laminated composite electrode plate and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Example 1 The surface of a 120×120×0.8mm titanium plate is degreased, sandblasted, and cleaned, and the working parameters are spraying voltage 32V, current 160A, air pressure 0.5MPa, spraying distance 100mm CDM-1620 arc spraying machine spraying 0.6mm Thick copper layer is hot rolled at 600°C, followed by cold rolling to produce a titanium-copper clad plate. The copper surface is coated with a layer of copper solder, and a certain pressure is applied to superimpose two copper surfaces of the titanium-copper clad plate, heated at 600°C. Insulate in the furnace for 60 minutes, cold rolling, and welded by argon arc welding to obtain a titanium-clad copper composite plate. The coating is applied to electrolysis, and the cell voltage is reduced by 0.7V.

Embodiment 2

[0035] Example 2 Degrease, sandblast, and clean the surface of a 100×100×1.0mm copper plate. The working parameters of the arc spraying machine are spraying voltage 48V, current 200A, air pressure 0.5MPa, and spraying distance 100mm. Double-sided spraying of 0.8mm thick titanium layer, hot rolling at 900°C, followed by cold rolling to produce a titanium-copper clad composite plate, the coating is applied, and the cell voltage is reduced by 0.5V.

Embodiment 3

[0036] Example 3 Degrease, sandblast, and clean the surface of a 120×120×0.8mm titanium plate, put it into an argon atmosphere deposition chamber, preheat to 500°C and atomize and deposit a 0.6mm thick copper layer at a temperature of 500°C Hot rolling, followed by cold rolling to produce titanium-copper composite plate, the copper surface is coated with a layer of copper solder, a certain pressure is superimposed, kept in a heating furnace at 600°C for 60 minutes, cold rolled, and welded by argon arc welding. A titanium-copper-clad composite board is obtained, and the coating is applied, and the slot voltage is reduced by 0.2V.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
Login to view more

Abstract

The invention discloses a titanium / copper laminated composite plate used for insoluble anode and a preparation method thereof, belonging to the fields of nonferrous metal extraction, chlorine alkali industry and the like. The titanium / copper laminated composite plate with the inner core being copper and an outer layer being coated with titanium is prepared by adopting an electric arc spraying method, a fusion casting method or a spray deposition method. The three methods have simple preparation technique and easy operation, and adapt to industrial production; the prepared titanium / copper laminated composite plate has excellent interface coherency, conductivity and corrosion resistance, a coating titanium anode prepared by adopting the laminated composite plate as a substrate leads the internal resistance of electrode to be reduced, the current distribution to be even and the product purity to be high; and the bath voltage is reduced by 0.1 to 0.8V, compared with that of the coating titanium electrode, thus achieving the effects of saving energy and reducing consumption.

Description

technical field [0001] The invention relates to a preparation method for an insoluble anode substrate titanium / copper layered composite plate used in fields such as nonferrous metal extraction and chlor-alkali industry. Background technique [0002] Titanium electrodes are widely used in non-ferrous metal extraction and chlor-alkali industry due to their excellent corrosion resistance and dimensional stability. However, traditional coated titanium electrodes use titanium or titanium alloys as substrates, which have defects such as large internal resistance and low current efficiency. At present, the research focus at home and abroad is mainly on the alloy system and coating to improve the performance of the electrode, but this method has no obvious effect on reducing the internal resistance of the electrode. [0003] The titanium / copper layered composite material integrates the excellent corrosion resistance of titanium and the good conductivity of copper. When applied to ti...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C25B11/04C25B11/10
Inventor 竺培显黄文芳周生刚杨秀琴张瑾许健
Owner KUNMING UNIV OF SCI & TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap