A kind of green environment-friendly compound solvent for printing ink and preparation method thereof

A green, environmentally friendly, compound solvent technology, applied in inks, applications, household appliances, etc., can solve problems such as health and safety hazards of operators, high residual solvent value in printed matter, relatively high toxicity of toluene, etc., and achieve bright appearance and bright colors , Improve the effect of market competitiveness

Active Publication Date: 2011-12-07
佛山市南海秉盈包装材料有限公司
View PDF0 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although this ink has excellent printability, good post-press processing performance, and fast drying, but due to (1) the relative toxicity of toluene, the residual solvent value of printed matter is high; (2) the thermal stability of chlorinated polypropylene is poor , in the process of production and storage, it is easy to release chlorine to form hydrogen chloride, which makes the ink highly acidic and severely corrodes the printing plate roller; (3) the organic volatiles produced by benzene-soluble ink can destroy the ozone layer, and The use process will also cause harm to the health and safety of the operators, and the residues left in the packaged products will cause a certain degree of pollution to the food in the package under certain conditions.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A kind of green environment-friendly compound solvent for printing ink, its formula comprises solvents such as dimethyl carbonate, diethyl carbonate, ethyl acetate, butyl acetate and cyclohexane, and its raw material components and volume percentage are as follows:

[0027] Dimethyl carbonate 10%,

[0028] Diethyl carbonate 10%,

[0029] Ethyl acetate 10%,

[0030] Butyl acetate 10%,

[0031] Cyclohexane 60%.

[0032] The preparation method of the green and environment-friendly composite solvent for the printing ink:

[0033] a, preparation of dimethyl carbonate: the liquid phase reactant methanol is injected into the mixing chamber with a constant flow rate to preheat, and after complete gasification, it is mixed with the reactant (CO, O 2 ) and carrier gas N 2 Mix well, enter the filling CuCl 2 -PdCl 2 -The fixed-bed reactor of KOH / C catalyst, reaction condition T=403K, P=0.64MPa, O 2 :CO:N 2 =1:8:5, the mixed gas in the reaction passes through the reaction b...

Embodiment 2

[0038] A kind of green environment-friendly compound solvent for printing ink, its formula comprises solvents such as dimethyl carbonate, diethyl carbonate, ethyl acetate, butyl acetate and cyclohexane, and raw material component and volume percentage are as follows:

[0039] Dimethyl carbonate 10%,

[0040] Diethyl carbonate 20%,

[0041] Ethyl acetate 10%,

[0042] Butyl acetate 10%,

[0043] Cyclohexane 50%.

[0044] The preparation method of the green environment-friendly solvent for the composite printing ink:

[0045] a, preparation of dimethyl carbonate: the liquid phase reactant methanol is injected into the mixing chamber with a constant flow rate to preheat, and after complete gasification, it is mixed with the reactant (CO, O 2 ) and carrier gas N 2 Mix well, enter the filling CuCl 2 -PdCl 2 -The fixed-bed reactor of KOH / C catalyst, reaction condition T=403K, P=0.6MPa, O 2 :CO:N 2 =1:6:5, the mixed gas in the reaction passes through the reaction bed, and is...

Embodiment 3

[0050] A kind of green environment-friendly compound solvent for printing ink, its formula comprises solvents such as dimethyl carbonate, diethyl carbonate, ethyl acetate, butyl acetate and cyclohexane, and raw material component and volume percentage are as follows:

[0051] Dimethyl carbonate 10%,

[0052] Diethyl carbonate 15%,

[0053] Ethyl acetate 10%,

[0054] Butyl acetate 15%,

[0055] Cyclohexane 50%.

[0056] The preparation method of the green and environment-friendly composite solvent for the printing ink:

[0057] a, preparation of dimethyl carbonate: the liquid phase reactant methanol is injected into the mixing chamber with a constant flow rate to preheat, and after complete gasification, it is mixed with the reactant (CO, O 2 ) and carrier gas N 2 Mix well, enter the filling CuCl 2 -PdCl 2 -The fixed-bed reactor of KOH / C catalyst, reaction condition T=413K, P=0.64MPa, O 2 :CO:N 2 =1:8:5, the mixed gas in the reaction passes through the reaction bed, a...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to a green and environment-friendly compound solvent for printing oil and a preparation method thereof, belonging to the technical field of organic mixed solvent. Dimethyl carbonate and diethyl carbonate are oxosynthesized by carbonyl, reaction products are respectively rectified and collected to obtain 90-94 DEG C fraction and 125-128 DEG C fraction, and dimethyl carbonate, diethyl carbonate, acetic ether, butyl acetate and cyclohexane are dispersedly regulated to be even in a certain volume ratio to obtain the product. The printing ink solvent is colourless and clear, non-benzene and non-ketone with short boiling range, low aromatic hydrocarbon content and good dissolving nature on resin, causes good fluidity of the printing ink, has good transitivity and rapid solvent release property, good high-temperature stability, excellent dot reproducibility and lustre performance, high stability in storage, is not easy to separate out of the printing ink, and can be used as a prinking oil solvent of food package.

Description

technical field [0001] The invention relates to a high-solubility polymer resin, which is a green and environment-friendly composite solvent for plastic printing ink, and belongs to the technical field of organic mixed solvents. Background technique [0002] With the development of economy and society, countries all over the world pay more and more attention to environmental pollution. The printing industry occupies an important position in the national economy. Colorful printed matter brings civilization to human beings and also causes environmental pollution. The development of the printing industry is closely related to the development of the ink industry. Ink is currently one of the largest sources of pollution in the printing industry, and the amount of volatile organic compound (VOC) pollution caused by ink has reached hundreds of thousands of tons every year. These organic volatiles mainly come from the solvent of the ink. [0003] With the improvement of living sta...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C09D11/10C09D11/033
Inventor 蒋平平张萍波韩秋菊吴士华汪建中丁全柱
Owner 佛山市南海秉盈包装材料有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products