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Nylon 6 slice prepared by using waste fishing net and preparation method thereof

A technology for fishing nets and nylon, applied in the field of nylon 6 slices and its preparation, can solve the problems that the mechanical properties and appearance cannot meet the basic requirements of use, engineering plastics lose their use value, and the molecular weight of nylon 6 slices is low, so as to achieve great social effects and economic benefits. Benefits, low cost, less impurities

Inactive Publication Date: 2010-08-18
CGN JUNER NEW MATERIALS +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the long-term immersion of waste fishing nets in water, the molecular chains have been degraded and broken to varying degrees due to the effects of external sunlight, salt, microorganisms, etc. When the relative molecular weight is reduced to below 10,000, PA6 will lose its basic use as an engineering plastic. value
In addition, due to the special environment used in water, a large amount of impurities such as sediment, aquatic plants, and shells are usually adhered to the fishing net wire, and these impurities also bring many difficulties to the recovery and application of PA6.
Nylon 6 slices directly recovered without treatment have low molecular weight, many impurities, dark color, and the mechanical properties and appearance cannot meet the basic requirements for use.

Method used

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  • Nylon 6 slice prepared by using waste fishing net and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The recovered waste fishing nets are added to a high-speed crusher and broken into fragments with a diameter of less than 10 mm, then poured into a large drum washing machine to wash away the sediment and centrifugally dried, and then dried to a moisture content of 0.2% ( percent by weight).

[0029] With 98Kg above-mentioned dried waste fishing net fragments and 0.5Kg bisoxazoline, 0.5Kg hindered phenolic stabilizer: antioxidant 1098 (Yabao), 0.5Kg phosphite stabilizer: antioxidant 168 (Yabao ) and 0.5Kg magnesium stearate are mixed at a high speed in a high-speed mixer for 2min, and then added from the first feeder (main feed) into the twin-screw extruder that the die head is equipped with an 800-mesh metal filter screen, and the twin-screw extruder The temperature of the machine from the feed section to the head is: 245°C, 245°C, 245°C, 235°C, 230°C, 220°C, 220°C, 210°C, the temperature of the die head is 235°C, and it is water-cooled after extrusion , dicing, and t...

Embodiment 2

[0031] After the reclaimed waste fishing nets are processed to meet the requirements according to the treatment method in Example 1, the above-mentioned dried waste fishing net fragments of 98Kg are stabilized with 0.5Kg epoxy-based styrene-acrylate oligomer and 0.5Kg hindered phenol hindered phenols. Agent: Antioxidant 1098 (Abemarle), 0.5Kg phosphite stabilizer: Antioxidant 168 (Abemarle) and 0.5Kg polyester lubricant AC540 (Honeywell) mixed in a high-speed mixer for 2min Finally, feed it from the first feeder (main feed) into the twin-screw extruder with a 800-mesh metal filter installed in the die head. The temperature of the twin-screw extruder from the feeding section to the die head is: 245°C, 245°C, 235°C, 230°C, 220°C, 220°C, 210°C. The temperature of the die head is 235°C. After extrusion, it is water-cooled, pelletized, and then packaged to obtain PA6 slices.

Embodiment 3

[0033] After the reclaimed waste fishing nets are processed to meet the requirements according to the treatment method in Example 1, the above-mentioned dried waste fishing net fragments of 95Kg are mixed with 0.5Kg bisoxazoline, 0.5Kg epoxy-based styrene-acrylate oligomer, 1.5 Kg hindered phenolic stabilizer: antioxidant 1098 (Albemarle), 1.0Kg phosphite stabilizer: antioxidant 168 (Albemarle), 0.5KG cuprous iodide and 0.5Kg magnesium stearate, 0.5Kg Polyester lubricant AC540 (Honeywell) was mixed at a high speed in a high-speed mixer for 2 minutes, and then added from the first feeder (main feed) to a twin-screw extruder with a 800-mesh metal filter installed on the die head. The temperature of the screw extruder from the feed section to the head is: 245°C, 245°C, 245°C, 235°C, 230°C, 220°C, 220°C, 210°C, the temperature of the die head is 235°C, and the extrusion Afterwards, it is water-cooled, cut into pellets, and then packaged to obtain PA6 slices.

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PUM

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Abstract

The invention discloses a nylon 6 slice prepared by using a waste fishing net. A raw material of the nylon 6 slice comprises the following components in percentage by weight: 95 to 98 percent of the waste fishing net, 0.5 to 1.0 percent of chain extender, 1.0 to 3.0 percent of compound heat stabilizer and 0.5 to 1.0 percent of lubricant. The nylon 6 slice has mechanical properties and mobile processing performance equivalent to that of a PA6 fresh material slice, has a light color and fewer impurities, can partially or completely replace a nylon 6 fresh material slice to be used for spinning or modifying engineering plastics and other raw materials, reduces environmental pollutions, realizes the cyclic utilization of resources, and has great social effects and economic benefits.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a nylon 6 slice prepared by using waste fishing nets and a preparation method thereof. Background technique [0002] my country has a long coastline and many inland rivers and lakes. Fishing and aquaculture are very common. A large number of fishing nets are used every year, and many waste and rotten fishing nets are discarded. Fishing nets are basically made of nylon 6 after spinning. If discarded at will, they cannot be degraded in a short time, which brings great harm to the environment and aquatic animals and plants. [0003] Nylon 6 (referred to as PA6), which is polymerized from caprolactam, is the final product of the petroleum industry, and it is also a type of basic resin with the largest output, the most varieties, the widest range of uses, and excellent comprehensive performance among the five general-purpose engineering plastics. The molecular weight of nylon 6 for e...

Claims

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Application Information

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IPC IPC(8): C08L77/02C08K13/02C08K5/353B29B9/06B29C47/92B29C48/40B29C48/92
CPCB29C48/92B29C48/05B29C2948/92704B29C48/04B29C48/40B29C48/9185B29C2948/92895B29C2948/92904
Inventor 黄志杰陈佰全杨丰富
Owner CGN JUNER NEW MATERIALS
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