Antitarnish crosslinked PVC material and preparation process thereof

A technology of cross-linked polyvinyl chloride and manufacturing process, which is applied in the field of anti-discoloration cross-linked polyvinyl chloride material and its manufacturing process, and can solve the problems of PVC radiation discoloration and aggravation

Active Publication Date: 2010-10-20
深圳市帝源新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Some functional additives are beneficial to radiation crosslinking, and are also beneficial to prevent PVC discoloration, but unfortunately there are also some functional additives that will aggravate the radiation discoloration of PVC

Method used

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  • Antitarnish crosslinked PVC material and preparation process thereof
  • Antitarnish crosslinked PVC material and preparation process thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0061] The anti-tarnish cross-linked PVC material component and content thereof of the present embodiment are:

[0062] Polyvinyl chloride (PVC resin S-70, Ningbo Formosa Plastics) 100 parts;

[0063] Filler (calcium carbonate, Dongguan Meilitai) 25 parts;

[0064] Plasticizer (TOTM, PN-1013, Zhongshan Liancheng; soybean oil, Japan Mitsubishi) 44 parts;

[0065] Stabilizer (composite non-toxic high temperature resistant stabilizer, Japan ADK) 12 parts;

[0066] Flame retardant (antimony trioxide, magnesium hydroxide, aluminum hydroxide, flash star antimony industry) 5 parts;

[0067] Cross-linking aid (TMPTMA, BASF, Germany) 4;

[0068]5 parts of processing aid (acrylic polymer, LG Chemical).

[0069] The manufacturing process of the anti-discoloration cross-linked PVC material of the present embodiment is as follows: add 25 kilograms of calcium carbonate powder to the 10,000-horsepower high-speed mixer, then add 50 kilograms of PVC powder, stir and mix the materials, and ...

Embodiment 2

[0072] The anti-tarnish cross-linked PVC material component and content thereof of the present embodiment are:

[0073] Polyvinyl chloride (PVC resin TG-1300, Guangdong Tosoh) 100 parts;

[0074] 22 parts of filler (nanometer calcium carbonate);

[0075] 40 parts of plasticizer (TOTM, Zhongshan Liancheng; soybean oil, Japan Mitsubishi);

[0076] Stabilizer (composite non-toxic high temperature resistant stabilizer, Japan ADK) 10 parts;

[0077] Flame retardant (antimony trioxide, magnesium hydroxide, aluminum hydroxide, flash star antimony industry) 4 parts;

[0078] 5 parts of cross-linking aid (TAIC, BASF, Germany);

[0079] 4 parts of processing aid (acrylate polymer, LG Chemical);

[0080] 1 part of dyeing agent (BASF, Germany).

[0081] The manufacturing process of the anti-discoloration cross-linked PVC material of the present embodiment is as follows: add 22 kilograms of calcium carbonate powder to the 10,000-horsepower high-speed mixer, then add 40 kilograms of PV...

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Abstract

The invention provides an antitarnish crosslinked PVC (Polyvinyl Chloride) material which is prepared from the following components in parts by weight: 100 parts of PVC resin, 20-30 parts of filler, 30-50 parts of plasticizer, 5-15 parts of composite stabilizer, 3-7 parts of flame retardant, 2-6 parts of crosslinking agent and 2-6 parts of processing aid. The invention also provides a preparation process of the antitarnish crosslinked PVC material. The non-toxic composite stabilizer and the processing aid are added to the antitarnish PVC material to obviously improve the optical stability of the PVC material in radiation processing, i.e. colors are unchanged after the material is radiated. The invention has low-cost and environment-friendly raw materials and wide application prospects.

Description

technical field [0001] The invention belongs to the technical field of polymer material modification, and in particular relates to an anti-discoloration cross-linked polyvinyl chloride material and a manufacturing process thereof. Background technique [0002] Polyvinyl chloride (PVC) material is the best material for wire and cable due to its excellent flame retardancy, electrical insulation, and adjustable hardness. However, due to the poor thermal stability of ordinary PVC, low heat distortion temperature, large compression permanent deformation, hardness greatly affected by ambient temperature, and narrow product temperature range, the application of soft PVC has been limited for a long time. Therefore, cross-linking modification is often used to improve heat softening resistance, pyrotechnic resistance and oil resistance. Crosslinking is an important method in plastic modification. Through crosslinking, a three-dimensional network structure is formed inside the materi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08K13/02C08K3/26C08K5/12C08K5/1515C08K5/098C08K3/22C08K5/103C08K5/3492B29B9/06
Inventor 熊陶曾美昌张万涛李佳鸿
Owner 深圳市帝源新材料科技股份有限公司
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