Method for preparing anticorrosive protective paint with polyaniline/attapulgite clay composite particle and application thereof

A technology of anti-corrosion protection and composite particles, applied in anti-corrosion coatings, coatings, etc., can solve problems such as damage to human health, and achieve the effect of less usage, excellent protection performance, and improved density

Inactive Publication Date: 2012-05-30
HUAIYIN INSTITUTE OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the need for a large amount of organic solvents, a large amount of organic volatiles are released, especially aromatic hydrocarbons, formaldehyde, etc., which have serious damage to human health

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Prepare the anticorrosion coating according to the following specific steps:

[0023] (1) Attapulgite minerals are obtained through ore dressing, crushing and sieving Attapulgite powder;

[0024] (2) Fully mix attapulgite powder, aniline and hydrochloric acid, slowly add hydrogen peroxide solution dropwise under strong stirring, react at room temperature for 12 hours, suction filter after the reaction, wash repeatedly with deionized water until the filtrate is colorless, and dry Grind into powder and pass through a 400 mesh sieve to obtain dark green polyaniline / attapulgite composite particles; wherein the molar ratio of hydrogen peroxide, aniline and hydrochloric acid is 1.2:1:1, the concentration of hydrochloric acid is 1mol / L, and attapulgite powder The mass ratio of body and aniline is 10:90;

[0025] (3) Fully mix toluene and azobisisobutyronitrile according to a certain ratio, stir and heat to 70°C, slowly drop into methyl methacrylate, butyl acrylate and acrylic...

Embodiment 2

[0029] Prepare the anticorrosion coating according to the following specific steps:

[0030] (1) Attapulgite minerals are obtained through ore dressing, crushing and sieving Attapulgite powder;

[0031] (2) Fully mix attapulgite powder, aniline and hydrochloric acid, slowly add hydrogen peroxide solution dropwise under strong stirring, react at room temperature for 12 hours, suction filter after the reaction, wash repeatedly with deionized water until the filtrate is colorless, and dry Grind into powder and pass through a 400 mesh sieve to obtain dark green polyaniline / attapulgite composite particles; wherein the molar ratio of hydrogen peroxide, aniline and hydrochloric acid is 1.2:1:1, the concentration of hydrochloric acid is 1mol / L, and attapulgite powder The mass ratio of body and aniline is 20:80;

[0032] (3) Fully mix toluene and azobisisobutyronitrile according to a certain ratio, stir and heat to 70°C, slowly drop into methyl methacrylate, butyl acrylate and acrylic...

Embodiment 3

[0036] Prepare the anticorrosion coating according to the following specific steps:

[0037] (1) Attapulgite minerals are obtained through ore dressing, crushing and sieving Attapulgite powder;

[0038] (2) Fully mix attapulgite powder, aniline and hydrochloric acid, slowly add hydrogen peroxide solution dropwise under strong stirring, react at room temperature for 12 hours, suction filter after the reaction, wash repeatedly with deionized water until the filtrate is colorless, and dry Grind into powder and pass through a 400 mesh sieve to obtain dark green polyaniline / attapulgite composite particles; wherein the molar ratio of hydrogen peroxide, aniline and hydrochloric acid is 1.2:1:1, the concentration of hydrochloric acid is 1mol / L, and attapulgite powder The mass ratio of body and aniline is 30:70;

[0039](3) Fully mix toluene and azobisisobutyronitrile according to a certain ratio, stir and heat to 70°C, slowly drop into methyl methacrylate, butyl acrylate and acrylic ...

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PUM

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Abstract

The invention discloses a method for preparing anticorrosive protective paint with polyaniline / attapulgite clay composite particle and an application thereof. The method comprises the following steps: firstly preparing polyaniline / attapulgite clay composite particles through the in-situ method; secondly preparing acrylic acid / methylmethacrylate / butyl methacrylate terpolymer solution; and finally mixing the polyaniline / attapulgite clay composite particles with the terpolymer solution in a certain ratio, and performing ultrasonic stirring to obtain the anticorrosive protective paint. The methoduses the polyaniline / attapulgite clay composite particles as the main raw material to prepare the anticorrosive protective paint; and the paint has good uniformity, adhesivity, coating processing property and corrosion resistance, thus effectively increasing the economic value added of attapulgite clay and effectively saving resources and energy.

Description

technical field [0001] The invention relates to a method and application for preparing an anti-corrosion protective coating by using polyaniline / attapulgite composite particles, and belongs to the manufacturing technology of material protective coating in the field of metal protection. Background technique [0002] Corrosion of metal is a phenomenon in which metal is destroyed by chemical or electrochemical action of environmental medium. Corrosion of metals spreads across various industries and brings huge losses to the national economy. According to the survey and statistics of developed countries in the world, the direct economic loss caused by corrosion accounts for 1-4% of the total output value of the national economy, the annual corroded and rusted steel accounts for about 20% of the output, and about 30% of the equipment is scrapped due to corrosion. In my country, the economic loss caused by metal corrosion is as high as 30 billion yuan per year, accounting for 4% ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D133/12C09D179/02C09D5/08C08G73/02C08F220/14
Inventor 丁红燕周广宏章跃林岳宾陈露露周中超
Owner HUAIYIN INSTITUTE OF TECHNOLOGY
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