The present invention provides a method for enhancing electrical characteristics of organic electronic devices, especially for an organic thin-film transistors, comprising the steps of: providing a substrate with a gate and an insulator layer formed thereon; preparing an organic solution by mixing materials of an organic semiconductor polymer, an organic insulator polymer, a conducting particle and a solvent; forming an organic semiconductor layer on top of the insulator layer between the source and the drain using the organic solvent. Wherein, the organic semiconductor polymer can be a polymer selected from the group consisting of poly(3-alkylthiophene) (P3AT) with different alkyl side groups of 2, 4, 6, 8, 10, 12, and 18, as the P3HT is a P3AT with alkyl side group of 6, and the organic insulator polymer can be a polymer selected from the group consisting of poly(methylmethacrylate) (PMMA), and polybutylene terephthalate (PBT), etc. and the conducting particle can be a kind of particle selected from the group consisting of carbon nanotubes (CNTs), C60, and nano silver particle, and so on, and the solvent can be a solvent selected from the group consisting of xylene, toluene, and THF, and so forth.