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Preparation method for spectrograde calcium oxide

A calcium oxide, spectrally pure technology, applied in the direction of calcium/strontium/barium oxide/hydroxide, etc., can solve the problem that it can only be used in pesticides, papermaking, food, petrochemical, and cannot meet the needs of the rapid development of the electronics industry. problems such as low purity of calcium oxide, to achieve the effect of improving market competitiveness, low cost and low impurity content

Inactive Publication Date: 2011-04-20
TIANJIN CHEM REAGENT RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Spectrally pure calcium oxide is widely used in the diffusion and doping process of semiconductor production in the electronics industry. The synthesis method currently used is the reaction of calcium chloride and ammonium carbonate to obtain calcium carbonate, which is heated and dehydrated to obtain calcium oxide. The oxidation obtained by this method Calcium has low purity and high impurity content. This product can only be used in pesticides, papermaking, food, petrochemical, etc., and cannot meet the needs of the rapid development of the electronics industry.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A preparation method of spectrally pure calcium oxide, the steps of which are:

[0018] 1. Prepare ammonium carbonate solution:

[0019] 10kg of distilled water is put into a plastic barrel, and ammonia gas is fed to obtain ammonia water, and the relative density is controlled at 18 ° Be, and then carbon dioxide is fed, and the pH value is controlled at 8.5 to obtain an ammonium carbonate solution for subsequent use;

[0020] 2. Purification of calcium nitrate:

[0021] Put 2kg of calcium nitrate into 2000mL of distilled water, heat to dissolve at 50°C, adjust the pH value to 10 with calcium hydroxide, filter to obtain the purified calcium nitrate solution, and set aside;

[0022] 3. Synthetic calcium carbonate:

[0023] Heat the calcium nitrate solution purified in step 2 to 50°C, add the ammonium carbonate solution used in step 1 while stirring, control the pH value at 5, filter, add ammonium carbonate solution to the filtrate until the precipitation is complete, an...

Embodiment 2

[0027] A preparation method of spectrally pure calcium oxide, the steps of which are:

[0028] 1. Prepare ammonium carbonate solution:

[0029] 10kg of distilled water is put into a plastic barrel, and ammonia gas is fed to obtain ammonia water, and the relative density is controlled at 22 ° Be, and then carbon dioxide is fed, and the pH value is controlled at 9 to obtain an ammonium carbonate solution for subsequent use;

[0030] 2. Purification of calcium nitrate:

[0031] Put 1 kg of calcium nitrate into 1000 mL of distilled water, heat to dissolve at 60°C, adjust the pH value to 11 with calcium hydroxide, filter to obtain the purified calcium nitrate solution, and set aside;

[0032] 3. Synthetic calcium carbonate:

[0033] Heat the calcium nitrate solution purified in step 2 to 60°C, add the ammonium carbonate solution used in step 1 while stirring, control the pH value at 6, filter, add ammonium carbonate solution to the filtrate until the precipitation is complete, an...

Embodiment 3

[0037] A preparation method of spectrally pure calcium oxide, the steps of which are:

[0038] 1. Prepare ammonium carbonate solution:

[0039] 10kg of distilled water is put into a plastic bucket, feed ammonia gas to obtain ammonia water, control the relative density at 20 ° Be, then feed carbon dioxide, and control the pH value at 8.5 to obtain ammonium carbonate solution for subsequent use;

[0040] 2. Purification of calcium nitrate:

[0041] Put 1.5kg of calcium nitrate into 1500mL of distilled water, heat to dissolve at 55°C, adjust the pH value to 10 with calcium hydroxide, filter to obtain the purified calcium nitrate solution, and set aside;

[0042] 3. Synthetic calcium carbonate:

[0043] Heat the calcium nitrate solution purified in step 2 to 55°C, add the ammonium carbonate solution used in step 1 while stirring, control the pH value at 5.5, filter, add ammonium carbonate solution to the filtrate until the precipitation is complete, and wash the precipitate with...

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Abstract

The present invention relates to the field of preparation methods for inorganic compounds, in particular to a preparation method for spectrograde calcium oxide. The invention is characterized by reacting purified calcium nitrate with ammonium carbonate to generate calcium carbonate; then burning and drying to obtain high-purity calcium oxide. The present invention has the advantages of simple process steps, low cost, easily-controlled operation, and high production efficiency; and can achieve the calcium oxide product with high purity, low impurity content and improved competitive power.

Description

technical field [0001] The invention relates to the field of preparation methods of inorganic compounds, in particular to a preparation method of spectrally pure calcium oxide. Background technique [0002] Spectrum pure calcium oxide is widely used in the diffusion and doping process of semiconductor production in the electronics industry. The synthesis method currently used is the reaction of calcium chloride and ammonium carbonate to obtain calcium carbonate, which is heated and dehydrated to obtain calcium oxide. The oxidation obtained by this method Calcium has low purity and high impurity content. This product can only be used in pesticides, papermaking, food, petrochemicals, etc., and cannot meet the needs of the rapid development of the electronics industry. Contents of the invention [0003] The purpose of the present invention is to overcome the deficiencies of the prior art and provide a method for preparing spectrally pure calcium oxide with low impurity conten...

Claims

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Application Information

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IPC IPC(8): C01F11/02
Inventor 胡建华
Owner TIANJIN CHEM REAGENT RES INST