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Catalytic conversion method for producing high-octane petrol from crude oil

A technology of high-octane gasoline and catalytic conversion method, applied in catalytic cracking, cracking, petroleum industry and other directions, can solve the problems of poor gasoline properties, affecting gasoline octane number, and high energy consumption

Inactive Publication Date: 2011-06-29
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method has many disadvantages such as poor gasoline properties and high energy consumption.
[0004] In addition, the octane number of the heavy fraction of catalytic cracked gasoline is low, which affects the octane number of gasoline; the quality of catalytic cracked diesel oil is poor, but the catalytic cracked diesel oil contains more single-ring aromatics. If the single-ring aromatics in diesel oil are converted As a gasoline component, it is conducive to the increase of gasoline yield and at the same time can improve the octane number of gasoline
Therefore, the existing technology does not fully utilize the gasoline octane number and the gasoline potential content in diesel oil, and there is room for improvement in gasoline yield and quality

Method used

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  • Catalytic conversion method for producing high-octane petrol from crude oil
  • Catalytic conversion method for producing high-octane petrol from crude oil
  • Catalytic conversion method for producing high-octane petrol from crude oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0079] This example follows figure 1 The process of the test is carried out, and the raw material oil A is directly used as the raw material oil for catalytic cracking, and the test is carried out on the medium-sized device of the riser reactor, and the raw material oil A enters the reaction zone I. Reaction temperature 505°C, weight hourly space velocity 30h -1, the weight ratio of catalyst to raw oil is 10, and the weight ratio of water vapor to raw oil is 0.15 to carry out the cracking reaction; the reaction product oil gas and the catalyst to be born with charcoal are separated in the settler, and the product is carried out in the separation system according to the distillation range Cutting, so as to obtain products such as propylene, gasoline, diesel oil and catalytic wax oil (fraction greater than 330 ° C). The operating conditions and product distribution are listed in Table 2.

[0080] As can be seen from Table 2, the gasoline yield is as high as 43.28% by weight, i...

Embodiment 2

[0082] This example follows the attached image 3 The test is carried out according to the process, the raw material oil A is directly used as the easily cracked raw material oil of catalytic cracking, and the test is carried out on a medium-sized device with a riser reactor. The easy-cracked raw material oil enters the middle and upper part of the reaction zone I, and the difficult-to-cracked raw material oil enters the reaction zone I. bottom. At the bottom of reaction zone I, the refractory raw material oil is heated at a reaction temperature of 600°C and a weight hourly space velocity of 240h -1 , the weight ratio of catalytic cracking catalyst to refractory feed oil is 30, and the weight ratio of water vapor to refractory feed oil is 0.20 to carry out the cracking reaction; Hourly space velocity 90h -1 The cracking reaction is carried out under the condition that the weight ratio of the catalytic cracking catalyst to the easy-to-crack raw oil is 10, and the weight ratio...

Embodiment 3

[0085] This embodiment is the same as the test device of Example 2. The raw material oil B is used as the difficult-to-crack raw material oil of catalytic cracking, and the test is carried out on a medium-sized device with a riser reactor. The raw oil enters the bottom of reaction zone I. At the bottom of the reaction zone I, the refractory raw material oil is heated at a reaction temperature of 620°C and a weight hourly space velocity of 180h -1 , the weight ratio of catalytic cracking catalyst to refractory feed oil is 90, and the weight ratio of water vapor to refractory feed oil is 0.20 to carry out the cracking reaction; Hourly space velocity 60h -1 The cracking reaction is carried out under the condition that the weight ratio of catalytic cracking catalyst to easily cracked raw oil is 10, and the weight ratio of water vapor to easily cracked raw oil is 0.15; in addition, the supplementary part of the raw catalyst that has been stripped from the stripping section enters ...

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Abstract

The invention discloses a catalytic conversion method for producing high-octane petrol from crude oil. The catalytic conversion method comprises the following step of: blending and reacting pretreated crude oil serving as raw material oil and a large pore zeolite-containing catalyst in a catalytic conversion reactor, wherein a reaction temperature, an oil gas retention time and a weight ratio of the catalyst to the raw material oil are enough to obtain a reaction product which contains catalytic wax oil which accounts for 15 percent to 60 percent of the raw material oil; the weight houly space velocity is 25 to 100 hour <-1>; the reaction temperature is between 450 and 600 DEG C; and the weight ratio of the catalyst to the raw material oil is 1 to 30. While inferior crude oil is conversed into high-octane petrol by the method, the production rate of dry gas and coke is highly reduced, so that highly effective utilization of an oil resource is achieved.

Description

technical field [0001] The invention relates to a method for catalytic conversion of crude oil, in particular to a method for converting heavy crude oil into high-octane gasoline while greatly reducing dry gas and coke yields so as to realize efficient utilization of petroleum resources. Background technique [0002] With the development of the economy, the number of gasoline vehicles in the world is increasing year by year, so the demand for high-quality gasoline is increasing. Catalytic cracking (FCC) gasoline has good anti-knock performance and is one of the main sources of motor gasoline. [0003] The production of catalytic cracking gasoline and diesel oil generally uses straight-run vacuum distillate (VGO) as raw material and blends some residues such as atmospheric residue (AR) and vacuum residue (VR). Heavy raw materials such as residual oil contain high content of heavy metals such as residual carbon, sulfur, nitrogen, nickel, and vanadium. In order to improve the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G69/04C10G55/06C10G11/05C10G11/20
Inventor 唐津莲许友好崔守业汪燮卿
Owner CHINA PETROLEUM & CHEM CORP
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