Method for preparing high-quality gas by biomass pyrolysis desulphurization and decarbonization
A biomass and high-quality technology, applied in biofuels, coke ovens, indirect heating and dry distillation, etc., can solve the problems of high cost in the oxygen production process, reduced system economy, reduced energy density of gas products, and easy deactivation costs of catalysts. Achieve the effects of eliminating damage and environmental pollution, wide application range, and reducing operating costs
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Embodiment 1
[0024] Using sawdust powder of about 50 mesh as raw material (moisture content 10%), firstly mix it evenly with calcium oxide powder (about 100 mesh) of 0.7 times the mass, after mixing, add the quantitative feeder 1 into the jacketed pyrolyzer 3, and Biomass pyrolysis and calcium oxide absorb CO at 600-700°C 2Cooperate with the catalytic tar cracking reaction for 10-20 minutes; the pyrolysis gas is separated from solid phase substances such as pyrolysis residual carbon and calcium carbonate at the tail of the jacketed pyrolyzer 3, and then purified by the dust collector 4, and then passed through the combustion chamber 10 high temperature zone, the tar macromolecules in the pyrolysis gas undergo secondary cracking at 900-1000°C, and the obtained gas tar content is 40 mg / Nm 3 Below, the approximate range of each gas volume content is H 2 41%, CH 4 27%, CO 16%, CO 2 3.5%, the calorific value of gas reaches 17MJ / Nm 3 ; The high-quality gas obtained is finally collected an...
Embodiment 2
[0027] About 50 mesh wood powder (water content 10%) and 0.5 times the mass of calcium oxide powder (about 100 mesh) are mixed evenly and added to the pyrolyzer. The other steps are the same as in Example 1 and will not be repeated. mg / Nm 3 Below, the approximate range of each gas volume content is H 2 38%, CH 4 28%, CO 20%, CO 2 4.5%, the calorific value of gas reaches 17.3MJ / Nm 3 .
Embodiment 3
[0029] About 80 mesh of rice husk powder (water content 11%) and 0.3 times the mass of calcium oxide powder (about 100 mesh) are mixed evenly and added to the pyrolyzer. Other steps are the same as in Example 1 and will not be repeated. The amount of gas tar obtained is 45mg / Nm 3 Below, the approximate range of each gas volume content is H 2 30%, CH 4 27%, CO 25%, CO 2 6.5%, the calorific value of gas reaches 16.9MJ / Nm 3 .
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