The invention discloses a method for producing
polyaluminum chloride without heating. The method comprises the following concrete steps: (1) sequentially adding a waste aluminum
chloride liquor generated in a Friedel-Craft reaction, an aluminiferous
hydrochloric acid, an industrial
hydrochloric acid and water into a heat insulating reaction kettle to prepare a mixed acid in which the percentage of Al2O3 is 1% to 4% and the percentage of HCl is 12% to 18%; (2) adding aluminum oxidized
sludge into the mixed acid, stirring for 60-90 minutes until the aluminum oxidized
sludge is completely dissolved, heating to the
reaction temperature of 60 DEG C to 80 DEG C, controlling the percentage of the HCl in a semi-finished product to be 0.5% to 3.5% and the percentage of the Al2O3 in the semi-finished product to be not less than 5.0%; (3) adding
calcium aluminate powder into a semi-finished product liquid, regulating the percentage of the Al2O3 in the reaction liquid to be 11% to 12% and the basicity of the reaction liquid to be 60% to 90%, maintaining the temperature required by the reaction by utilizing the heat generated in the reaction, timing when the temperature rises to 90 DEG C, reaction under preserved temperature for 60-90 minutes and performing a filter pressing treatment to obtain a finished
polyaluminium chloride product. By adopting the method to prepare the
polyaluminium chloride, the production process is simple, no steam does need to be heated, the emission of acid mist and waste
slag is reduced, the production cost is lowered and the recycle of waste resources is realized; therefore, the method is an economical and practical production method which saves energy and reduces emissions.