Pickling and passivating treatment process for stainless steel pipes

A technology of pickling passivation and treatment process, which is applied in the direction of metal material coating process, etc., can solve the problems of insufficient passivation film formation, poor finish, and large corrosion of metal substrates, so as to improve the quality of pickling passivation and simplify Process and equipment, the effect of improving the service life

Inactive Publication Date: 2011-10-19
扬州华宇管件有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the prior art, when stainless steel pipe fittings are pickled and passivated, the process is complicated and there are many steps. The ratio of pickling and passivation solution is often determined by each manufacturer according to its own materials and production experience. The determined ratio is different. Stable, the use effect is not ideal, there are shortcomings such as incomplete removal of oxides on the surface of the pipe fittings after pickling, insufficient passivation film formation, poor finish, etc.
In addition, there are also problems such as slow descaling speed, low efficiency, high corrosion to metal substrates, low corrosion inhibition rate, acid mist generated during cleaning and passivation operations, which affects the health of operators, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] A pickling and passivation treatment process for stainless steel pipe fittings, comprising the following steps:

[0039] A) Preprocessing

[0040] Use alkaline degreasing solution (the main components are sodium hydroxide, sodium carbonate, sodium phosphate, sodium silicate, the total concentration is 3-5%) for degreasing and cleaning, put the stainless steel workpiece to be treated into the solution, and immerse it for 15 minutes. Remove surface oil, dust, metal grinding dust and other impurities and stains. If there are foreign objects on both sides of the weld, it can be removed with a stainless steel wire brush, stainless steel shovel or grinding wheel.

[0041] Rinse the cleaned stainless steel workpiece with clean water (chloride ion content does not exceed 25mg / l).

[0042] B) Dosing

[0043] Prepare the pickling passivation solution according to the mass percentage concentration of the following formula:

[0044] Nitric acid (specific gravity 1.42) 20%

[0...

Embodiment 2

[0063] A pickling and passivation treatment process for stainless steel pipe fittings, comprising the following steps:

[0064] A) Preprocessing

[0065] Sodium hydroxide solution with a concentration of 3-5% is used for degreasing and cleaning, and the stainless steel pipe fittings to be treated are put into the solution and soaked for 15 minutes to remove surface oil, dust, metal grinding dust and other impurities and stains. Use gasoline or other cleaning agents to deal with oil stains and other dirt. The scale of the stainless steel hot-processed parts can be removed by mechanical sandblasting, and the sandblasting adopts pure silicon spray or aluminum oxide spray.

[0066] Rinse the cleaned stainless steel workpiece with clean water (chloride ion content does not exceed 25mg / l).

[0067] B) Dosing

[0068] Prepare the pickling passivation solution according to the mass percentage concentration of the following formula:

[0069] Nitric acid (specific gravity 1.42) 22% ...

Embodiment 3

[0088] Carry out the pickling passivation treatment of stainless steel fittings by the method for embodiment 1, difference is that described efficient corrosion inhibitor consists of:

[0089] Dichloromethane 18%

[0090] Adipic acid 5%

[0091] Emulsifier OP-10 8%

[0092] Cuprous Chloride 2%

[0093] Isopropanol 4%

[0094] Propylene Glycol 4%

[0095] The rest is water.

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PUM

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Abstract

The invention discloses a pickling and passivating treatment process for stainless steel pipes, which comprises the steps of pretreatment, liquid preparation and pickling and passivating treatment, wherein the pickling and passivating liquid consists of 20 to 22 percent of nitric acid (with specific gravity of 1.42), 30 to 50 grams per liter of potassium dichromate, 30 to 50 grams per liter of additive and the balance of water. In the pickling and passivating treatment process, pickling and passivating are accomplished in one step to form silvery white bright beautiful surfaces of the stainless steel pipes and form high-quality passivated films, so that the surface quality of the treated metal pipes is improved and the treated metal pipes have high corrosion resistance; the descaling speed and the descaling efficiency are high; the corrosion of the metal substrates is small and the corrosion inhibition rate is high; and acid mist in a cleaning operation process is avoided, and the long-existing NOx and HF serious pollution problem of stainless steel continuous pickling and passivating is solved.

Description

technical field [0001] The invention relates to a stainless steel material surface treatment process, in particular to a stainless steel pipe fitting pickling passivation treatment process. Background technique [0002] The corrosion resistance of stainless steel is mainly due to the fact that the surface is covered with a very thin (about 1nm) dense passivation film, which is isolated from the corrosive medium and is the basic barrier for stainless steel protection. Stainless steel workpieces will form an oxide film when placed in the air, but the protection of this film is not perfect. Usually, it needs to be thoroughly cleaned first, including alkali cleaning and pickling, and then passivated with an oxidant to ensure the integrity and stability of the passivation film. One of the purposes of pickling is to create favorable conditions for passivation treatment and ensure the formation of high-quality passivation film. [0003] During the manufacturing process of stainle...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23G1/08C23G1/06C23C22/26
Inventor 蒯尧山何广熟衡长桥
Owner 扬州华宇管件有限公司
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