Polyimide super capacitor and preparation method thereof
A supercapacitor and polyimide technology, applied in the field of capacitors, can solve the problems of small operating temperature range, poor electrochemical stability, poor thermal stability, etc., and achieve good electrochemical stability and thermal stability, and a wide operating temperature range. , the effect of improving heat resistance
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[0031] A kind of preparation method of polyimide supercapacitor, it comprises the following steps:
[0032] (1) Preparation of pole piece: Mix porous carbon material, conductive agent, adhesive, and solvent evenly in proportion to prepare an electrode slurry with a viscosity of 1500cps-8500cps, coat it on the current collector, and bake it Drying, rolling, slitting, and sheeting to obtain positive and negative electrodes;
[0033] (2) Preparation of battery cells: The positive and negative pole pieces are prepared into battery cells with polyimide diaphragms in a winding or superimposed manner, and the polyimide diaphragms are used to insulate and separate the pole pieces;
[0034] (3) Liquid injection encapsulation: put the positive and negative electrodes in the cell into the case, and connect the guide pins respectively, the guide pins pass through the container shell, then inject electrolyte, seal, and obtain a polyimide supercapacitor.
Embodiment 1
[0036] (1) Production of pole pieces: Mix activated carbon, conductive carbon black, adhesive, and deionized water with a total mass of 1000g in a mass ratio of 45:10:15:30, and adjust them into a uniform mixture in a vacuum mixer. The slurry, the viscosity of the slurry is 8500cps, the slurry is evenly coated on the aluminum foil, then dried at 90-100 ℃, rolled, cooled and cut, the positive electrode is cut into 98mm long, 12.5mm Wide, the negative electrode is cut to be 115mm long and 12.5mm wide, and its surface density is 90m 2 / g.
[0037] (2) Preparation of battery cells: select a polyimide diaphragm with a thickness of 20um, and stack and wind it into rolls in the order of polyimide diaphragm, positive electrode sheet, polyimide diaphragm, and negative electrode sheet.
[0038] (3) Liquid injection packaging: put the above-mentioned battery cells into an aluminum container shell with a diameter of 10 mm and a height of 20 mm, and inject electrolyte solution. The solute...
Embodiment 2
[0041](1) Production of pole pieces: Mix activated carbon with a total mass of 1000g, conductive carbon black, conductive agent, and deionized water at a mass ratio of 15:10:15:60, and adjust them into a uniform mixture in a vacuum mixer. Slurry, the viscosity of the slurry is 1500cps, the slurry is evenly coated on the aluminum foil, then dried at 90-100°C, rolled, cooled and then cut, the positive electrode is cut to 190mm long and 17.5mm wide , the negative electrode is cut to be 210mm long and 17.5mm wide, and its surface density is 92m 2 / g.
[0042] (2) Preparation of battery cells: select a polyimide separator with a thickness of 25 μm, and stack and wind it into a roll in the order of polyimide separator, positive electrode sheet, polyimide separator, and negative electrode sheet.
[0043] (3) Liquid-injection packaging: put the above-mentioned cells into an aluminum container shell with a diameter of 12.5mm and a height of 25mm, and inject electrolyte solution. The s...
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