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Method for extracting purified complanatuside from milk vetch seed

A technology of sarcoside and sarcoside, which is applied in the field of natural medicinal chemistry, can solve the problems of large solvent residues, etc., and achieve the effects of low production cost, high product purity and short production cycle

Inactive Publication Date: 2012-07-11
苏州宝泽堂医药科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method uses a large amount of organic solvent and toxic methanol solution, and the solvent residue is large

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Take 5 kg of Astragalus complanatus raw material and put it into a small extraction tank, add 8 times the amount of 2% sodium hydroxide solution to percolate and extract until the percolate color becomes lighter, combine the percolate, and add a tubular composite ultrafiltration membrane system with a molecular weight cut-off of 6000. Filter, concentrate the permeate into an extract, add hydrochloric acid to adjust the pH to 3.5, filter the precipitate, heat the precipitate to reflux and dissolve, let it cool, extract twice with 5 times the volume of petroleum ether, add 2.2% CTS Chinese medicine clarifier to the water layer, Leave it to stand, centrifuge, and put the clear liquid on the HZ818 macroporous adsorption resin column, first wash away impurities with water, then eluted with 50% ethanol, collect the eluate, and concentrate it into an extract. Suspend 4 kg of 100-200 mesh silica gel with ethyl acetate and add it to a stainless steel chromatography column with a c...

Embodiment 2

[0020] Take 5kg of Astragalus complanatus raw material and put it into a small extraction tank, add 15 times the amount of 3% lime water solution and ultrasonically extract 4 times, 1 hour each time, combine the extracts, add a tubular composite ultrafiltration membrane system with a molecular weight cutoff of 4000 to ultrafiltration. After the liquid is concentrated into an extract, add hydrochloric acid to adjust the pH to 3.0, filter out the precipitate, heat the precipitate to dissolve under reflux, let it cool, extract 3 times with 4 times the volume of petroleum ether, add 1.5% deacetyl chitosan to the water layer, and let it stand. After centrifugation, the clear liquid was applied to the ADS-21 macroporous adsorption resin column, first washed with water to remove impurities, and then eluted with 70% ethanol, the eluate was collected and concentrated into an extract. Suspend 6 kg of 200-280 mesh silica gel with ethyl acetate and add it to a stainless steel chromatography...

Embodiment 3

[0022] Take 10kg of Astragalus complanatus raw material and put it into a small extraction tank, add 20 times the amount of 5% ammonia water alcohol solution (alcohol concentration is 50%), decoct, filter, combine the extracts, and add a tubular composite ultrafiltration membrane system with a molecular weight cut-off of 5000. After the permeate is concentrated into an extract, add hydrochloric acid to adjust the pH to 4.0, filter out the precipitate, heat the precipitate to dissolve under reflux, let it cool, extract twice with 8 times the volume of petroleum ether, add 1.2% CTS Chinese medicine clarifier to the water layer, and statically After setting, centrifuging, the clear liquid is applied to the LS-303 macroporous adsorption resin column, the impurities are first washed with water, and then eluted with 40% ethanol, the eluate is collected, and concentrated into an extract. After suspending 10 kg of 150-250 mesh silica gel with ethyl acetate, evenly add it to a stainless ...

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Abstract

The invention discloses a method for extracting purified complanatuside from milk vetch seed. The method comprises the following steps of: extracting milk vetch seed with alkaline water or an alkaline diluted alcohol solution; filtering; adding an extracting solution into an ultrafiltration membrane system; collecting a permeate; adjusting the pH of the permeate to 3-5; dissolving precipitates with hot water; cooling; removing fat-soluble impurities with petroleum ether; adding a precipitating agent into a water layer for clarifying; and adsorbing a liquid with macroporous resin, separating and purifying with a medium-pressure silica gel column and recrystallizing with chloroform-methanol to obtain a high-purity product, wherein the purity of the obtained product can be over 98 percent. In the method, a membrane separating technology is adopted, so that the purity of complanatuside is increased, the damages of resin are reduced, and the service life of resin is prolonged; and moreover, the production period of the medium-pressure silica gel column is short; and most edible ethanol is used in extracting and purifying processes, so that pollution is low.

Description

Technical field: [0001] The invention belongs to the technical field of natural medicinal chemistry, and particularly relates to a method for extracting and purifying asides from Astragalus complanatus. Background technique: [0002] Astragalus complanatus is derived from the dried mature seeds of the legume Astragalus complanatus R.Br. Gan, Wen. Return to the liver and kidney channels. It has the effects of invigorating the kidney and yang, consolidating essence and reducing urine, nourishing the liver and improving eyesight. Used for kidney deficiency, low back pain, seminal emission, premature ejaculation, enuresis, frequent urination, turbidity, dizziness, dim eyesight. It has been reported in the literature that Astragalus complanatus has effects on hemorheology, immune function, blood pressure and cerebral blood flow, and also has antipyretic and analgesic, sedative, cold tolerance, anti-fatigue, anti-inflammatory, lipid-lowering and liver-protective effects. The chemic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07H17/07C07H1/08
Inventor 李法庆刘东锋
Owner 苏州宝泽堂医药科技有限公司