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Method for preparing functionalized EVA (Ethylene Vinyl Acetate) thin film

A functional and thin-film technology, applied in the direction of chemical instruments and methods, layered products, glass/slag layered products, etc., can solve the problems of reduced service life, damage, and accelerated aging of the interlayer film of laminated glass, and achieve high transmittance high effect

Inactive Publication Date: 2014-05-07
广州保均塑料科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This is mainly due to the transparent film formed by metal oxide or doped metal oxide. When the radiation acts on the film, the plasmon resonance wavelength of the transparent film is much smaller than the incident wavelength, so that the incident wavelength has no transmission in the infrared region and becomes highly reflective. ; but for ultraviolet and visible light transmittance, therefore, usually in the interlayer film of laminated glass, organic ultraviolet absorbers are added to shield the ultraviolet rays of 300-380nm. When the organic ultraviolet absorbers absorb the energy of ultraviolet rays and convert them into heat energy, The aging of the interlayer film of laminated glass is accelerated; on the other hand, when the interlayer film of laminated glass is processed in an autoclave, the organic ultraviolet absorber may be thermally decomposed and damaged, and its service life is reduced; at the same time, the nanoparticles with infrared reflection are only Only when the particles are nano-sized, the transparency of the interlayer film of laminated glass will not be affected; while the amount of nanoparticles with infrared reflection effect added to the interlayer film of interlayer glass cannot exceed 2%, if it is greater than 2%, the interlayer film Therefore, the existing technology shows that: 1) While shielding infrared rays, visible light is partially weakened; 2) Since the glass surface is coated with a transparent film of doped metal oxide, long-term exposure to the air is easy to cause oxidation and deterioration; 3) The organic ultraviolet absorber of the interlayer film of laminated glass, although it shields ultraviolet rays, the aging of the interlayer film of laminated glass is accelerated due to the conversion of the energy absorbed by ultraviolet rays into heat energy

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Mix the slurry of nano-cerium doped tin antimony oxide and the slurry of nano-yttrium oxide (mass ratio: 1:1), the solid content of the mixed slurry is 16.5%, in the nano-cerium-doped tin oxide, cerium-doped The amount of antimony tin oxide is 5% of the weight of antimony tin oxide; the mixed slurry is evenly coated on the EVA (0.76mm) film through the glue coating machine, the thickness of the wet glue is 50 μm, and the film is dried; the film is sandwiched between two Between pieces of float glass (thickness 3mm) to obtain a sandwich glass, then place the sandwich glass in a sealed silica gel bag with an air pressure of 0.06MPa for 20 minutes, and then place the silica gel bag with the built-in sandwich glass in Put it in an oven at 135°C and keep it for 20 minutes to bond the glass and the interlayer film together. The laminated glass thus prepared can shield 98.8% of ultraviolet rays with a wavelength of 300-380nm and 98.8% of infrared rays with a wavelength of 780-2...

Embodiment 2

[0027] Mix nano cerium-doped tin antimony oxide slurry and nano silicon oxide slurry (mass ratio: 10:1), the solid content of the slurry is 16.5%, and the doping amount of cerium is 8% of the weight of tin antimony oxide; The glue coating machine evenly coats the slurry on the EVA (0.76mm) film, the thickness of the wet glue is 100μm, and it is dried to form a film; the film is sandwiched between two float glass plates (thickness: 3mm), In order to obtain a sandwich glass, place the sandwich glass in a sealed silica gel bag with an air pressure of 0.06MPa to degas for 20 minutes, then place the silica gel bag with the built-in sandwich glass in a vacuum oven at 135°C for 20 minutes, so that The glass and the interlayer film are bonded together, and the laminated glass thus prepared can shield 98.9% of ultraviolet rays of 300-380nm, shield 61% of infrared rays of 780-2500nm, and have a visible light transmittance of 75%.

Embodiment 3

[0029] Mix nano-cerium-doped tin-antimony oxide slurry and nano-alumina slurry (mass ratio: 5:1), the solid content of the slurry is 18.5%, and the doping amount of nano-cerium is 10% of the weight of tin-antimony oxide; The slurry is evenly coated on the EVA (0.38mm) film by a glue spreader, and the thickness of the wet glue is 50 μm, and it is dried to form a film; the film is sandwiched between two float glass plates (the thickness of the glass plate is 3mm) ) to obtain a sandwich glass, then place the sandwich glass in a sealed silica gel bag with an air pressure of 0.04MPa for 20 minutes, and then put the silica gel bag with the built-in sandwich glass in an oven at 135°C for 20 minutes , so that the glass and the interlayer film are bonded together, the laminated glass thus prepared can shield 98.6% of the ultraviolet rays of 300-380nm, shield 55% of the infrared rays of 780-2500nm, and the visible light transmittance is 81%.

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Abstract

The invention discloses a method for preparing a functionalized EVA (Ethylene Vinyl Acetate) thin film. The method comprises the following step of: uniformly coating inorganic nano-oxide slurry and nano-cerium-doped antimony tin oxide slurry on an EVA thin film. According to the method, the production process of the nano-cerium-doped antimony tin oxide / EVA thin film can be continuous and can be applicable to large, medium and small-sized enterprises. The functionalized EVA thin film prepared by the method has a relatively-high ultraviolet and infrared shielding rate and a high transmittance of visible light.

Description

technical field [0001] The invention relates to a preparation method of functionalized EVA film. Background technique [0002] In order to improve the efficiency of solar photoelectric conversion; prevent the temperature rise of building doors and windows and the inside of vehicle window glass, reduce indoor electricity consumption and reduce the consumption of power energy in the car; usually use Low-e glass, coated glass and laminated glass, etc.; Chinese patent ZL200510031338.4 Use controllable precipitation to prepare tin antimony oxide doped with rare earth (cerium) and zinc to prepare conductive film; Chinese patent CN00138041.9 discloses that PET (polyethylene terephthalate) low-emissivity film is placed between two PVB films 间与玻璃粘结而成;中国专利CN1898174B和CN101514083A公开了用ITO和ATO涂布于白玻璃表面形成隔热膜;中国专利CN101602580A、CN1898175B、CN1960953B、CN101243022A、CN102167520A、CN102251236A、CN101243023A、CN1989081B和CN101006023B等 Disclosed indium oxide, tin oxide, antimony oxide, tin-doped indium ox...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C27/12B32B17/06
Inventor 曾和平余力曾功昶
Owner 广州保均塑料科技有限公司