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Preparation method of polyethylene glycol/ZnO/Ag nanoparticle composite fiber material

A polyethylene glycol and composite fiber technology, which is applied in fiber processing, fiber chemical characteristics, spinning solution preparation, etc., can solve the problems of difficulty in setting solvent spinning parameters, complicated coaxial electrospinning devices, etc., and achieves good results. Application prospects, low cost, and the effect of improving dispersibility

Inactive Publication Date: 2012-10-03
CHANGZHOU UNIV
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AI Technical Summary

Problems solved by technology

[0004] Electrospinning technology is a technology in which a non-Newtonian fluid polymer solution overcomes surface tension and viscoelastic force under a high-voltage electric field, and performs stretching and bending motions to obtain nanometer to submicron fibers; this technology has simple equipment, low production cost, and is easy to use. Wide range of materials and large specific surface area; At present, there have been reports at home and abroad on the use of coaxial electrospinning devices to prepare metal oxides, but the coaxial electrospinning devices are relatively complicated, and there are difficulties in the selection of solvents and the setting of spinning parameters , while uniaxial electrospinning overcomes the above deficiencies

Method used

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  • Preparation method of polyethylene glycol/ZnO/Ag nanoparticle composite fiber material
  • Preparation method of polyethylene glycol/ZnO/Ag nanoparticle composite fiber material
  • Preparation method of polyethylene glycol/ZnO/Ag nanoparticle composite fiber material

Examples

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Effect test

example 1

[0028] Example 1: Nanoparticle composite fiber with Ag content of 0atom %

[0029] 4g Zn(NO 3 ) 2 ·6H 2 Add 10ml deionized water and 10ml deionized ethanol to O and 1gPVP and stir evenly, then mix and stir for 30min, add 2gPEG to 20ml dehydrated ethanol and stir, add the above mixed solution, stir magnetically at room temperature for 6h and then let it stand for 4h to obtain Uniform, transparent and viscous [PEG+PVP] / Zn(NO 3 ) 2 Spinning solution; the weight ratio of each component of the spinning solution is: Zn(NO 3 ) 2 ·6H 2 O / [PEG+PVP] / absolute ethanol / deionized water=4:3:30:10; add the configured spinning solution to the existing electrospinning device of the spinning device for electrospinning, the nozzle The caliber is 0.6mm, the working voltage is 15kV; the curing distance from the syringe needle nozzle to the receiving screen is 13cm; the indoor temperature is 15 o C, with a relative humidity of 45%, [PEG+PVP] / Zn(NO 3 ) 2 Composite nanofibers; the prepared...

example 2

[0031] Example 2: Nanoparticle composite fiber with Ag content of 5atom %

[0032] 3.886g Zn(NO 3 ) 2 ·6H 2 O and 0.114g AgNO 3 Mix, add 10ml of deionized water and stir evenly, dissolve 1gPVP and 2gPEG with 10ml of absolute ethanol and 20ml of absolute ethanol respectively, then mix the above solutions, stir magnetically at room temperature for 6h and then let stand for 4h to obtain Uniform, gray and viscous [PEG+PVP] / [Zn(NO 3 ) 2 +AgNO 3 ] spinning solution; the weight ratio of each component of the spinning solution is: [Zn(NO 3 ) 2 ·6H 2 O+ AgNO 3 ] / [PEG+PVP) / absolute ethanol / deionized water=4:3:30:10, where AgNO 3 with Zn(NO 3 ) 2 ·6H 2 The substance ratio of O is 0.05:1; the configured spinning solution is added to the existing electrospinning device of the spinning device for electrospinning, the nozzle diameter is 0.6mm, and the working voltage is 15kV; the needle nozzle of the syringe The curing distance to the receiving screen is 13cm; the indoor temp...

example 3

[0036] Example 3: Nanoparticle composite fiber with Ag content of 10atom %

[0037] 3.772g Zn(NO 3 ) 2 ·6H 2 O and 0.228g AgNO 3 Mix, add 10ml of deionized water and stir evenly, dissolve 1gPVP and 2gPEG with 10ml of absolute ethanol and 20ml of absolute ethanol respectively, then mix the above solutions, stir magnetically at room temperature for 6h and then let stand for 4h to obtain Uniform, gray and viscous [PEG+PVP] / [Zn(NO 3 ) 2 +AgNO 3 ] spinning solution; the weight ratio of each component of the spinning solution is: [Zn(NO 3 ) 2 ·6H 2 O+ AgNO 3 ] / [PEG+PVP] / absolute ethanol / deionized water=4:3:30:10, where AgNO 3 with Zn(NO 3 ) 2 ·6H 2 The mass ratio of O is 0.1:1; the configured spinning solution is added to the existing electrospinning device of the spinning device for electrospinning, the nozzle diameter is 0.6mm, and the working voltage is 15kV; the needle nozzle of the syringe The curing distance to the receiving screen is 13cm; the indoor temperatu...

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Abstract

The invention relates to the technical field of preparation of nanomaterials, in particular to a preparation method of a polyethylene glycol / ZnO / Ag nanoparticle composite fiber, and aims to provide the preparation method of a polyethylene glycol / ZnO / Ag nanoparticle composite fiber material. The preparation method comprises the following steps of: preparing spinning solution; preparing [PEG+PVP] / [Zn(NO3)2+AgNO3] composite nanofiber; and preparing ZnO / Ag composite nanofiber. The method has the advantages of simple process, low cost and capabilities of improving the dispersibility of the nanoparticles in polymer solution and the uniformity of the obtained fiber and being applied to a gas sensitive sensor.

Description

technical field [0001] The invention relates to the technical field of nanomaterial preparation, in particular to a preparation method of polyethylene glycol / ZnO / Ag nano particle composite fiber, which is applied in the field of gas sensitive sensors. Background technique [0002] In recent years, with the development of optoelectronic technology, the miniaturization and thin film of devices have become a trend. The application of nanomaterials and nanoparticle composite materials in the field of optoelectronics has received extensive attention from the scientific community; the preparation of polymer nanoparticle containing inorganic nanoparticles Fibers in particular have attracted much attention because such nanocomposites combine the unique properties of inorganic nanoparticles (such as high ratio of surface atoms to internal atoms and quantum size interaction, etc.) with the excellent properties of polymer nanofibers (such as very high Specific surface area and high pen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F9/08D01F8/18D01D1/02D01D5/00D01D10/02
Inventor 丁建宁李燕袁宁一
Owner CHANGZHOU UNIV
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