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A composite material with low expansion coefficient, high toughness and high thermal conductivity and its preparation method

A technology of functional composite materials and low expansion coefficient, applied in the direction of heat exchange materials, chemical instruments and methods, etc., can solve problems such as inability to coordinate high strength, high toughness and high fluidity, poor processing performance, and reduced mechanical properties , to achieve the effect of increasing added value, good processing performance and high toughness

Active Publication Date: 2015-10-28
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the obvious differences in physical and chemical properties between fillers and polymers will cause problems such as dispersion difficulties, poor processability and reduced mechanical properties when they are compounded with polymers, and often cannot coordinate high strength and high toughness and Paradox of High Mobility

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A performance of low expansion coefficient, high toughness and high thermal conductivity, the raw materials of the composite material include the following components and contents in parts by weight.

[0030] Component Weight Fraction

[0031]Polycarbonate (for polymer matrix) 100

[0032] Boron nitride (BN, for thermal conductivity) 20

[0033] Alumina (Al 2 o 3 , 3000 mesh, for thermal conductivity body) 10

[0034] Silane coupling agent (coupling agent for processing heat-conducting functional body) 0.6

[0035] Styrenic thermoplastic elastomer (for compatibilizer) 5

[0036] Silicone oil lubricant (processing aid for surface improvement) 4

[0037] First, (1) Dry the polycarbonate in a blast oven at 100°C for 3 hours; (2) Calcinate boron nitride and aluminum oxide at 800°C as raw materials for the heat-conducting functional body, cool to room temperature, and then use silane coupling Combined treatment.

[0038] Then, the polycarbonate after the above treatm...

Embodiment 2

[0040] A performance of low expansion coefficient, high toughness and high thermal conductivity, the raw materials of the composite material include the following components and contents in parts by weight.

[0041] Component Weight Fraction

[0042] Polycarbonate (for polymer matrix) 100

[0043] Boron nitride (BN, for thermal conductivity) 30

[0044] Silane coupling agent (coupling agent for processing heat-conducting functional body) 0.6

[0045] Styrene thermoplastic elastomer (for compatibilizer) 10

[0046] Pentaerythritol lubricants (for processing aids) 2

[0047] First, the polycarbonate is dried in a blast oven at 100°C for 3 hours; then the boron nitride is calcined at 800°C, cooled to room temperature, and then treated with a silane coupling agent.

[0048] Then, the above-mentioned treated polycarbonate, boron nitride treated with coupling agent, styrene-based thermoplastic elastomer and pentaerythritol-based lubricant are put into a high-mixer for pre-mixing...

Embodiment 3

[0050] A performance of low expansion coefficient, high toughness and high thermal conductivity, the raw materials of the composite material include the following components and contents in parts by weight.

[0051] Component Weight Fraction

[0052] Polycarbonate (for polymer matrix) 100

[0053] Aluminum Nitride (AlN, as a thermal conductivity body) 40

[0054] Silane coupling agent (coupling agent for processing heat-conducting functional body) 0.6

[0055] Styrene thermoplastic elastomer (for compatibilizer) 10

[0056] Pentaerythritol lubricants (for processing aids) 2

[0057] First, the polycarbonate is dried in a blast oven at 100°C for 3 hours; then the aluminum nitride is calcined at a high temperature of 800°C, cooled to room temperature, and then treated with a silane coupling agent.

[0058] Then, the polycarbonate after the above treatment, the aluminum nitride after the coupling agent treatment, the styrene-based thermoplastic elastomer and the pentaerythrit...

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Abstract

The invention relates to a high-toughness high-thermal conductivity functional composite material with a low expansion coefficient, and a preparation method thereof. Polycarbonate is taken as a base material; one or more heat conducting functional bodies, a compatilizer, and a processing agent are added. The weight of the heat conducting functional bodies is 30 to 40% of the weight of the polycarbonate, the weight of the compatilizer is 5 to 10% of the weight of the polycarbonate, and the weight of the processing agent is 0 to 5% of the weight of the polycarbonate. The high-toughness high-thermal conductivity functional composite material with the low expansion coefficient has performances that: the expansion coefficient is low, the toughness is high, the thermal conductivity is high and processing fluidity is excellent. The composite material can be used in shaping processing such as extrusion and injection processing, and can meet requirements for multiple functions of polymer materials, such as low expansion coefficient, high toughness and high thermal conductivity, in different fields. Application prospect of the composite material is promising, production technology is simple, operating control is convenient, quality is stable, producing efficiency is high and industrialization and market prospect is promising.

Description

technical field [0001] The invention relates to a functional composite material with low expansion coefficient, high toughness and high thermal conductivity and a preparation method thereof, belonging to the technical field of functional composite materials. Background technique [0002] With the rapid development of modern science and technology, composite materials formed of polymer materials and inorganic materials such as metals and ceramics have attracted more and more attention. However, compared with inorganic materials, polymer materials have relatively poor heat resistance and a much larger coefficient of thermal expansion (CTE). After the two are combined, as the temperature changes, thermal stress will be generated inside the composite material and the high Molecular materials produce cracking, warping, peeling and other undesirable phenomena. At the same time, with the development of miniaturization and high energy of electronic components, heat transfer has bec...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L69/00C09K5/14C08K9/06C08K3/38C08K3/22C08K3/28B29B9/06B29C47/92B29C45/78B29C48/92
CPCB29C47/92B29C47/827B29C2947/92704B29C2947/92895B29C48/40B29C48/875B29C48/92B29C2948/92704B29C2948/92895
Inventor 郭少云吴宏张先龙陈光顺
Owner SICHUAN UNIV
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