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Ultraviolet curable ink receptive layer for color filter, and method of producing color filter

A technology for an ink-receiving layer and a manufacturing method, which is applied in the directions of replication/marking methods, inks, nonlinear optics, etc., can solve problems such as inability to display black, poor contrast, panel damage, etc.

Inactive Publication Date: 2013-09-18
NIPPON STEEL CHEMICAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, the conventional paper medium is naturally full-color display, and expectations for the colorization of electronic paper are very high
[0003] As the technology of electronic paper capable of color display proposed so far, for example, the medium forming the color filter in the reflective liquid crystal device has all been commercialized, but since these usually use polarizers, the light utilization efficiency is low, and only Capable of darker white display
In addition, since black cannot be displayed, the contrast ratio is also poor
[0004] In addition, as a bright reflective display device, there is an electrophoretic method. The principle of the electrophoretic method is to move charged white particles and black particles through an electric field. However, the scattering reflectance of the white particles in this electrophoretic method is less than 40% at most, and further improvement is required. reflection efficiency
However, this surface treatment method needs to set conditions for making the contact angle of each transparent support substrate the same, which is not suitable for mass production, and the control range is also limited.
In addition, when the inkjet method is used to directly form a colored area on the panel, this surface treatment method may cause damage to the panel.

Method used

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  • Ultraviolet curable ink receptive layer for color filter, and method of producing color filter
  • Ultraviolet curable ink receptive layer for color filter, and method of producing color filter
  • Ultraviolet curable ink receptive layer for color filter, and method of producing color filter

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0102] [Preparation of colored inkjet ink (R1: red, G1: green, B1: blue)]

[0103] As shown in Table 1, firstly, diethylene glycol monoethyl ether acetate was dispersed in a bead mill as a solvent in the presence of a polymer dispersant using fine pigments for color filters to prepare red, green and Blue dispersion. Based on this dispersion liquid, the compositions shown in Table 1 were mixed, and the mixed solution was filtered through a 1 μm microfilter under pressure to prepare colored inkjet inks of various colors (colored inks). Table 1 shows the conjugate property values.

[0104] Table 1

[0105] Pigment ink composition

R1

G1

B1

PE-4A (liquid resin)

28.4 copies

29.1 copies

26.9 copies

EGDAC

60.4 copies

60.5 copies

60.4 copies

KBM-5103

0.6 copies

O. 6 servings

O. 6 servings

Irgcure907

3.9 copies

3.9 copies

3.7 copies

BYK-378

O. 1 copy

O. 1 copy

O. 1 ...

Synthetic example 1

[0138] 54.5g (0.384mol) of isobutyl methacrylate (iBMA), 76.8g (0.768mol) of methyl methacrylate (MMA), 2, 2'-Azobis[2-methyl-butyronitrile) (AIBN) 1.0g (0.006mol) and PGMEA (propylene glycol monomethyl ether acetate) 200g, at 80~85℃, under nitrogen atmosphere,

[0139] Stir for 8 hr to polymerize. After cooling to room temperature, PGMEA was added so that the solid content could be adjusted to 30%, and resin solution 1 was obtained. The resin P1 contained in the obtained resin solution 1 could not be measured at Mw=65000 and an acid value of 1 or less. The glass transition temperature is 45-50°C.

Synthetic example 2

[0141] 33.0g (0.384mol) of methacrylic acid (MAA), 6.15g (0.0433mol) of isobutyl methacrylate (MPA) and 2.21g of AIBN ( 0.012mol) and PGMEA80g, at 80-85°C under nitrogen atmosphere, stir for 8hr to polymerize. Furthermore, 48.8 g (0.384 mol) of glycidyl methacrylate (MGA), 1.44 g (0.0055 mol) of triphenylphosphine, 0.055 g of 2,6-di-tert-butyl-cresol, and 83 g of PGMEA were placed in the flask, It stirred at 80-85 degreeC for 16 hr, and obtained the (meth)acrylate resin containing a polymerizable double bond. According to the IR measurement of the obtained polymerizable double bond-containing (meth)acrylate resin, at 1409cm -1 (vinyl), 1186cm -1 (Carboxyl) peak was observed. From this, it was confirmed that it was a (meth)acrylate resin containing a polymerizable double bond. Further, it was diluted with PGMEA to adjust the resin solution 2 with a solid content concentration of 30%. The average molecular weight Mw=19000 of the resin P2 contained in the obtained resin solu...

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PUM

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Abstract

The prevent invention provides an ultraviolet curable ink receptive layer for a color filter to colorize the system of conventional monochrome electronic papers without the luminosity being deteriorated in a simple and inexpensive way, and a method of producing the color filter. The color filter is obtained by using the receptive layer with coloring ink, and forms colored regions under the condition that the coloring ink of multiple colors ejected by the ink-jet method is not mixed with the adjacent coloring ink of a different color. The receptive layer is formed by receiving the coloring ink by a transparent resin film composed of a transparent resin composition in which transparent resin is dissolved, and applying ultraviolet curing. The present invention further provides the method of producing the color filter, in which after the transparent resin film composed of a transparent resin composition is created, the coloring ink of multiple colors is ejected on the transparent resin film by the ink-jet method, and the transparent film is dried and irradiated by ultraviolet light, thereby curing the transparent film and forming the colored regions.

Description

technical field [0001] The present invention relates to a method for producing an ultraviolet curable receiving layer for forming a colored region of a color filter and a color filter. A receiving layer and a method of manufacturing a color filter using the same. Background technique [0002] Electronic paper is actively being developed as an electronic medium replacing paper. Compared with CRT and liquid crystal displays, which are conventional displays, the characteristics required for electronic paper include: it is composed of a reflective display element, has high white reflectance and high contrast, has a memory effect in display, and can be used as an electronic paper. Low-voltage drive, thin and light, and cheap. In particular, white reflectance and contrast of the same quality as paper are required as display characteristics. In addition, the conventional paper medium is naturally full-color display, and expectations for colorization of electronic paper are very ...

Claims

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Application Information

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IPC IPC(8): G03F7/004G03F7/027G02B5/20B41M5/00
CPCC08L2201/10C09D11/00G02F1/133514
Inventor 藤城光一板原俊英斋藤亨浦野和久吉冈敬裕今野高志安藤智典
Owner NIPPON STEEL CHEMICAL CO LTD
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