Radiation-sensitive colored composition, color filter, and display device
A coloring composition, color filter technology, applied in the direction of filter, nonlinear optics, optics, etc., can solve the problems of reduced chromaticity characteristics, insufficient solvent resistance, etc., and achieve the effect of excellent characteristics
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[0180] Hereinafter, an embodiment of the present invention will be described more specifically with reference to examples. However, the present invention is not limited to the following examples.
[0181]
Synthetic example 1
[0183] In a flask equipped with a condenser and a stirrer, 100 parts by mass of propylene glycol monomethyl ether acetate was added and replaced with nitrogen. Heating to 80°C, at this temperature, 50 parts by mass of propylene glycol monomethyl ether acetate, 20 parts by mass of methacrylic acid, 10 parts by mass of styrene, 5 parts by mass of benzyl methacrylate, methacrylic acid -15 parts by mass of 2-hydroxyethyl ester, 23 parts by mass of 2-ethylhexyl methacrylate, 12 parts by mass of N-phenylmaleimide, succinic acid mono(2-acryloyloxyethyl) A mixed solution of 15 parts by mass of the ester and 6 parts by mass of 2,2'-azobis(2,4-dimethylvaleronitrile) was polymerized for 1 hour while maintaining the temperature. Thereafter, the temperature of the reaction solution was raised to 100° C., and polymerization was carried out for 1 hour to obtain a binder resin solution (solid content concentration=40% by mass). Mw of the obtained binder resin was 11200, and Mn was 6000. Thi...
Synthetic example 2
[0185] In a flask equipped with a condenser tube and a stirrer, 25 parts by mass of 3-methacryloxymethyl-3-ethyloxetane, 18 parts by mass of methacrylic acid, succinic acid mono-2-acryloyl 9 parts by mass of oxyethyl ester, 10 parts by mass of N-phenylmaleimide, 24 parts by mass of benzyl methacrylate, and 14 parts by mass of hydroxyethyl methacrylate are dissolved in 300 parts by mass of propylene glycol monomethyl ether acetate 6 parts by mass of 2,2'-azobisisobutyronitrile and 6 parts by mass of 2,4-diphenyl-4-methyl-1-pentene were further added to the parts, followed by nitrogen purge for 15 minutes. ). After nitrogen purging, the reaction liquid was heated to 80°C while stirring and nitrogen bubbling, and polymerized for 5 hours.
[0186] To 200 parts by mass of the obtained copolymer solution, 13.4 parts by mass of 2-methacryloyloxyethyl isocyanate and 0.2 parts by mass of 4-methoxyphenol as a polymerization inhibitor were added and reacted at 90°C. 2 hours. The react...
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Abstract
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