Synergistic Degradation of Organic Matter Using Visible Light Photoelectricity-Fenton
A technology of synergistic degradation and visible light, applied in the direction of protection devices against harmful chemicals, etc., can solve the problems of human injury, hinder the popularization and application, high cost, and achieve the effect of reducing compounding, improving photocatalytic efficiency and easy operation.
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Embodiment 1
[0028] Polish the Ti-based substrate with a purity >99.6% with metallographic sandpaper of 500#, 1000#, and 1500# in sequence until the surface is smooth, and then immerse in a volume ratio of HF:HNO 3 :H 2 Chemical polishing was carried out in the polishing solution of O=1:4:5 for 30 s, and then cleaned in an ultrasonic cleaner with acetone and pure water in sequence. The treated Ti-based substrate was used as the anode, the graphite electrode was used as the cathode, and the distance between the anode and the cathode was 4 cm. 4 The mixed solution of F and glycerol is used as the electrolyte, the volume ratio of glycerol to water is 1:9, and it contains NH 4 The concentration of F is 0.5 wt%. Use copper wires as wires to connect the two stages to a DC stabilized power supply for electrochemical anodic oxidation. In this reaction, the controlled voltage was 30 V, and the anodic oxidation time was 90 min, to obtain amorphous mesoporous TiO 2 Thin film electrode; after 120 ...
Embodiment 2
[0032] Polish the Ti-based substrate with a purity >99.6% with metallographic sandpaper of 500#, 1000#, and 1500# in sequence until the surface is smooth, and then immerse in a volume ratio of HF:HNO 3 :H 2 Chemical polishing was carried out in the polishing solution of O=1:4:5 for 30 s, and then cleaned in an ultrasonic cleaner with acetone and pure water in sequence. The treated Ti-based substrate was used as the anode, the graphite electrode was used as the cathode, and the distance between the anode and the cathode was 5 cm, and the NH 4 The mixed solution of F and glycerol is used as the electrolyte, the volume ratio of glycerol to water is 1:9, and it contains NH 4 The concentration of F is 0.3 wt%. Use copper wires as wires to connect the two stages to a DC stabilized power supply for electrochemical anodic oxidation. In this reaction, the controlled voltage was 10 V, and the anodic oxidation time was 150 min to obtain amorphous mesoporous TiO 2 Thin film electrode;...
Embodiment 3
[0036] Polish the Ti-based substrate with a purity >99.6% with metallographic sandpaper of 500#, 1000#, and 1500# in sequence until the surface is smooth, and then immerse in a volume ratio of HF:HNO 3 :H 2 Chemical polishing was carried out in the polishing solution of O=1:4:5 for 30 s, and then cleaned in an ultrasonic cleaner with acetone and pure water in sequence. The treated Ti-based substrate was used as the anode, the graphite electrode was used as the cathode, and the distance between the anode and the cathode was 3 cm. 4 The mixed solution of F and glycerol is used as the electrolyte, the volume ratio of glycerol to water is 1:9, and it contains NH 4 The concentration of F is 0.2 wt%. Use copper wires as wires to connect the two stages to a DC stabilized power supply for electrochemical anodic oxidation. In this reaction, the controlled voltage was 40 V, and the anodic oxidation time was 90 min to obtain amorphous mesoporous TiO 2 Thin film electrode; after 120 m...
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