A kind of light hydrocarbon oil catalytic conversion method

A catalytic conversion method and hydrocarbon oil technology, which is applied in the field of catalytic conversion of light hydrocarbon oil to produce low-carbon olefins, can solve the problems of rapid deactivation of catalysts, difficulty in realizing high-temperature reactions, and high conversion rate of cracking reactions, and reduce heat dissipation Effect of total surface area, avoidance of local hot spots, and reduction of catalyst damage

Active Publication Date: 2015-07-29
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] CN102039107A proposes a riser reaction-regeneration device, which aims to solve the problem that it is difficult to achieve high temperature reaction when using a riser reactor for cyclic reaction regeneration in the existing light oil / light hydrocarbon catalytic cracking process. The device uses a settler, The technical scheme of the stripper and the riser reactor juxtaposed with each other: the lower part of the riser reactor is outside the regenerator, the main reaction zone in the middle is set inside the regenerator, and the outlet of the upper part is connected to the gas-solid quick separator in the settler
[0011] CN101134160A proposes a reaction device for the production of low-carbon olefins by catalytic cracking, using the high-temperature regeneration flue gas of the catalytic cracking device as a heat source, and using light oil products such as naphtha as raw materials to carry out catalytic cracking reactions to produce low-carbon olefins. Due to the use of tubular reactors, it is difficult to solve the problem of rapid catalyst deactivation for highly active molecular sieve catalysts
[0012] Due to the high conversion rate of the cracking reaction of the catalytic cracking process, the high reaction temperature, and the high heat of the cracking reaction, compared with conventional catalytic cracking or other catalytic conversion methods, the heat required for the reaction is more, and the coke generated by its own cracking often cannot meet the requirements of the reaction. - Requirements for heat balance of the regenerative system itself

Method used

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  • A kind of light hydrocarbon oil catalytic conversion method

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Experimental program
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Effect test

Embodiment 1

[0103] The test was carried out according to the flow chart of the accompanying drawing, using straight-run naphtha as the raw material, the test was carried out on the medium-sized device of the riser reactor, and the preheated raw material oil entered the bottom of the riser, at a reaction temperature of 675°C and a reaction time of 2 seconds, The weight ratio of catalytic cracking catalyst to raw oil is 25, and the weight ratio of water vapor to raw oil is 0.55 to carry out the cracking reaction. The reaction product, water vapor and unborn catalyst enter the closed cyclone from the reactor outlet, and the reaction product and The catalyst is quickly separated, and the reaction product is cut according to the distillation range in the separation system after exchanging heat with the raw material, so as to obtain fractions such as dry gas, propylene, C4 and gasoline. The spent catalyst enters the regenerator under the action of gravity and contacts with air for regeneration. ...

Embodiment 2

[0106] This embodiment is tested according to the flow process of the accompanying drawing, using straight-run naphtha as raw material, the test is carried out on the medium-sized device of the riser reactor, the preheated raw material oil enters the bottom of the riser, and at a reaction temperature of 675 ° C and a reaction time 1.8 seconds, the weight ratio of the catalytic cracking catalyst to the raw oil is 25, and the weight ratio of the water vapor to the raw oil is 0.55 to carry out the cracking reaction, and the reaction product, water vapor and the raw catalyst enter the closed cyclone from the reactor outlet, The reaction product and the catalyst are quickly separated, and the reaction product is cut according to the distillation range in the separation system after exchanging heat with the raw material, so as to obtain fractions such as dry gas, propylene, C4 and gasoline, among which C4 returns to the reactor for further cracking into ethylene and propylene. The s...

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Abstract

The invention provides a light hydrocarbon oil catalytic conversion method. The method comprises the steps that a hydrocarbon oil raw material enters a riser reactor of a catalytic cracker to carry out a contact reaction with a catalyst, reaction oil and gas and the catalyst are subjected to gas-solid separation, the separated reaction oil and gas are led out of the catalyst cracker and are further separated and the separated spent catalyst is recycled after being regenerated, wherein the catalytic cracker comprises a regenerator (2), the riser reactor (1), a cyclone separator and a regeneration standpipe (9); the riser reactor (1), the cyclone separator and the regeneration standpipe (9) are arranged in the regenerator (2); an outlet of the riser reactor (1) is communicated with an inlet of the cyclone separator; a catalyst outlet of the cyclone separator is communicated with the regeneration standpipe (9); an opening of the regeneration standpipe (9) is formed in the bottom of the regenerator (2); the bottom of the riser reactor (1) extends out of the regenerator (2). The method provided by the invention has the beneficial effects of reducing the total radiating surface area of a reaction regeneration system, reducing the radiation energy consumption of the reactor and solving the problem of insufficient heat caused by insufficiency of cokes generated by cracking of light petroleum hydrocarbon.

Description

technical field [0001] The invention relates to a method for catalytic conversion of hydrocarbon oil in the absence of hydrogen, in particular to a method for catalytic conversion of light hydrocarbon oil to produce light olefins. Background technique [0002] As important basic organic raw materials for petrochemical industry, ethylene and propylene play a pivotal role in the petrochemical industry. In the production technology of hydrocarbon cracking to produce ethylene and propylene, tube furnace thermal cracking method accounts for the largest share of the world's ethylene and propylene production. Dominant, more than 98% of ethylene and 67% of propylene come from tube furnace cracking technology. With the increase of demand for propylene derivatives, the yield of propylene produced by thermal cracking can no longer meet the growing demand for propylene in the domestic and foreign markets. In the past 10 years, the growth rate of world propylene demand has been higher th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G55/06C07C11/04C07C11/06C07C4/06
CPCY02P20/584
Inventor 魏晓丽毛安国张久顺袁起民白风宇
Owner CHINA PETROLEUM & CHEM CORP
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