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A kind of manufacturing process of crystalline nano pet plastic

A production process and crystallization technology, applied in the field of plastic material production technology, can solve the problems of difficult processing, poor impact resistance, slow crystallization speed of PET plastic, etc., and achieve easy processing, strong impact resistance, and ensure high purity. Effect

Active Publication Date: 2015-07-29
SUZHOU XIANGYUAN SPEICAL FINE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Plastic is one of the four basic materials of modern industry with steel, wood and cement because of its wide range of uses and good performance. PET plastic is polyethylene terephthalate plastic, commonly known as polyester resin. It is The condensation polymer of terephthalic acid and ethylene glycol, together with PBT, is collectively referred to as thermoplastic polyester, or saturated polyester. The molecular structure of PET plastic is highly symmetrical, and it has a certain crystal orientation ability, so it has high film-forming properties. PET plastics have good optical properties and weather resistance, amorphous PET plastics have good optical transparency, and PET plastics have excellent abrasion resistance, friction resistance, dimensional stability and electrical insulation. Bottles are widely used because of their high strength, good transparency, non-toxicity, impermeability, light weight, and high production efficiency. However, PET plastics have slow crystallization speed, poor impact resistance, and are not easy to process.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A kind of manufacturing process of crystalline nano-PET plastic of the present embodiment, its processing step is as follows:

[0023] (1) Raw material preparation; under the conditions of reaction temperature 250-300°C and reaction pressure 2-2.5MPa, using zinc compound as catalyst, crude terephthalic acid is made into high-purity terephthalic acid (PTA), whichever is its purity 98%;

[0024] (2) Blending; mixing the terephthalic acid prepared in step (1) with ethylene glycol (EG), the mass ratio of the terephthalic acid to ethylene glycol (EG) is 1:1.5~2, Add CaCO to the mixed solution 3 Inorganic filler, the mass content of described filler is 3%~5%;

[0025] (3) Esterification: add a catalyst to the mixture of step (2), under the action of the catalyst, terephthalic acid and ethylene glycol undergo an esterification reaction, and the catalyst is acetate of zinc, cobalt, and manganese The mixture with antimony trioxide, the amount of the catalyst is 0.01%~0.05% of...

Embodiment 2

[0035] Example 2: The rest are the same as in Example 1, the difference is that the purity of the terephthalic acid prepared in step (1) is medium, and in this example, the cost is relatively low, but the reaction rate for making plastic is slow , the efficiency is low, and the physical properties of the plastic are reduced.

Embodiment 3

[0036]Embodiment 3: the rest are the same as the above-mentioned embodiment 1, the difference is that in the step (6), the crystallization accelerator is changed: sodium benzoate is organic montmorillonite, in this implementation, the corresponding reaction temperature increases, crystallization Effect is worse than embodiment 1.

[0037] It is known from practical application that the production of raw materials goes through six steps of preparation, blending, esterification reaction, polycondensation reaction, reinforcement modification, crystallization and separation, so that PET rubber not only has excellent physical and mechanical properties in a wide temperature range, but also has excellent electrical properties. Excellent insulation, creep resistance, fatigue resistance, friction resistance, good dimensional stability, fast crystallization rate, easy molding and processing, and strong impact resistance. Phthalic acid ensures the high purity of plastic products and impr...

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Abstract

The invention discloses a production process for crystallized nano PET (Polythylene Terephthalate) plastic. The production process comprises the following steps: (1) preparing raw materials; (2) blending: mixing terephthalic acid prepared in the step (1) with ethylene glycol (EG), wherein the mass ratio of the terephthalic acid to the ethylene glycol (EG) is 1 to (1.5-2), adding a CaCO2 organic filling agent into a mixed solution, wherein the mass content of the filling agent is 3%-5% (3) carrying out an exchange reaction; (4) carrying out a condensation polymerization reaction; (5) enhancing and modifying; and (6) crystallizing and separating. According to the production process, after the raw materials are subjected to a series of treatment, PET rubber not only has a good physical and mechanical performance, good electrical insulating property, good creep resistance, good fatigue resistance, good wear resistance and good size stability in a wide temperature range, but also has a rapid crystallization rate and is easy to mold and process; the PET rubber has the characteristics of strong shock resistance and the like.

Description

technical field [0001] The manufacturing process of plastic materials involved in the present invention, in particular, relates to a manufacturing process of crystalline nano-PET plastics. Background technique [0002] At present, plastics have been widely used in the construction industry, packaging materials, household daily necessities and automobiles and other fields. Plastic is one of the four basic materials of modern industry with steel, wood and cement because of its wide range of uses and good performance. PET plastic is polyethylene terephthalate plastic, commonly known as polyester resin. It is The condensation polymer of terephthalic acid and ethylene glycol, together with PBT, is collectively referred to as thermoplastic polyester, or saturated polyester. The molecular structure of PET plastic is highly symmetrical, and it has a certain crystal orientation ability, so it has high film-forming properties. PET plastics have good optical properties and weather res...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08G63/183C08G63/86C08K13/06C08K9/04C08K3/32C08K3/02C08K3/34C08K3/26C08K3/22C08K5/098
Inventor 周建颜玉荣
Owner SUZHOU XIANGYUAN SPEICAL FINE CHEM
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