Hydroximic acid functionalized polymer/inorganic composite chelating adsorption material and preparation method thereof
An inorganic composite, chelating adsorption technology, applied in chemical instruments and methods, adsorption water/sewage treatment, other chemical processes, etc. problem, to achieve the effects of excellent adsorption and desorption performance, strong selective identification, and simple preparation process
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Embodiment 1
[0021] Example 1: In a four-neck flask, add 10g of salicylic hydroxamic acid and 100ml of N,N-dimethylformamide, after the salicylic hydroxamic acid is fully dissolved, add 1,4 - Dichloromethoxybutane 21mL, stir well and add 1.2mL of SnCl 4 , constant temperature reaction for 13h, and then let the reaction solution stand overnight, a white precipitate was precipitated, filtered with suction, washed with ethanol, and dried in vacuo to obtain chloromethyl salicylic hydroxamic acid with a yield of 75%.
[0022] 0.83g chloromethyl salicylic hydroxamic acid and 0.2 g grafted particles PHEMA / SiO 2 Add it to 20mL dimethyl sulfoxide, raise the temperature to 110°C, and add 1.5g sodium carbonate, N 2 Under protection, react at constant temperature for 10 hours, filter, wash with distilled water and solvent repeatedly, and dry in vacuum to obtain the salicylic hydroxamic acid functionalized polymer / inorganic composite chelating adsorption material SHA-PHEMA / SiO 2 . The bonding ratio ...
Embodiment 2
[0023] Example 2: In a four-necked flask, add 9g of salicylic hydroxamic acid and 80mL of 1,4-dioxane. After the salicylic hydroxamic acid is fully dissolved, add 1,4- Dichloromethoxybutane 18mL, after stirring evenly, add 1.0mL of SnCl 4 , constant temperature reaction for 12h, and then let the reaction solution stand overnight, a white precipitate was precipitated, filtered with suction, washed with ethanol, and dried in vacuo to obtain chloromethyl salicylic hydroxamic acid with a yield of 69%.
[0024] 0.15g chloromethyl salicylic hydroxamic acid and 0.2g grafted particles PHEMA / SiO 2 Add to 12ml of N,N-dimethylformamide, raise the temperature to 90°C, and add 1.3g of sodium carbonate, N 2 Under protection, react at constant temperature for 10 hours, filter, wash with distilled water and solvent repeatedly, and dry in vacuum to obtain the salicylic hydroxamic acid functionalized polymer / inorganic composite chelate adsorption material SHA-PHEMA / SiO 2 . The bonding rate o...
Embodiment 3
[0025] Example 3: In a four-neck flask, add 8g of salicylic hydroxamic acid and 100ml of N,N-dimethylacetamide, after they are fully dissolved, add 1,4-dimethoxylate dropwise through a constant pressure dropping funnel at 5°C Chloromethoxybutane 15mL, after stirring evenly, add 0.8mLTiCl 4 , constant temperature reaction for 10h, and then let the reaction solution stand overnight, a white precipitate precipitated, filtered, washed with ethanol, and dried in vacuo to obtain chloromethyl salicylic hydroxamic acid with a yield of 60%.
[0026] 0.55g chloromethyl salicylic hydroxamic acid and 0.2g grafted particles PHEMA / SiO 2 Add it to 17mL of mixed solvent of dimethyl sulfoxide and N,N-dimethylformamide (V:V=1:1), raise the temperature to 100°C, and add 1g of sodium bicarbonate, N 2 Under protection, react at constant temperature for 9 hours, filter, wash with distilled water and solvent repeatedly, and dry in vacuum to obtain the salicylic hydroxamic acid functionalized polyme...
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