Low-silver-copper-based brazing filler metal and preparation method thereof

A technology of silver-copper and brazing material, which is applied in the direction of manufacturing tools, welding equipment, metal processing equipment, etc., can solve the problem of reducing the oxidation and deformation of base materials, failing to meet the needs of motors, and high silver content in high-silver copper-phosphorus brazing filler metals, etc. problems, to achieve good compactness, good fatigue performance, corrosion resistance and excellent creep strength

Active Publication Date: 2014-03-12
HANGZHOU HUAGUANG ADVANCED WELDING MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The temperature range between the solidus line and the liquidus line of the existing low-silver copper-phosphorus solder is too large, while the high-silver copper-phosphorus solder has a relatively high silver content and high production and use costs, which will gradually fail to meet the needs of brazing on motors , thus hindering the development of solder in the motor industry
[0006] On the other hand, the smelting of Sn-containing copper-based solder in the industry is prone to Sn segregation, resulting in poor control of the composition of the Sn-containing copper-based solder, resulting in insufficient solder performance. It is urgent to develop a method that can avoid Sn segregation. smelting preparation process
[0007] Chinese Patent No. 200510023129.5 discloses a patent titled "a copper-based brazing alloy", which selectively adds manganese, zinc, silver, nickel, silicon, Tin, aluminum, lithium, rare earth, the welding process performance is similar to that of silver solder, and the cost is more than 1 times lower than that of general silver solder; but this brazing alloy cannot replace BCu80AgP with 15% silver in the motor industry, patented There is no mention of the solution to the Sn se

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-6

[0045] The preparation method of embodiment 1-6 comprises the following steps:

[0046] (1) Pretreatment before smelting: Before smelting, Sn is processed, and bulk Sn is prepared into filamentous Sn;

[0047] (2) Smelting: During the smelting process, Sn is added in the form of filament Sn, which increases the contact area between Sn and the melt, facilitates the uniform distribution of Sn in the melt, and solves the problem of Sn segregation; use dry plant ash As a covering agent, plant ash has the advantages of large coverage area and dense coverage, which effectively reduces the oxidation and burning loss of Sn during the smelting process, and also reduces the hydrogen absorption and oxygen content of the melt during refining;

[0048] (3) Subsequent processing of smelting: After smelting, brazing materials are obtained through continuous casting, continuous extrusion, molding, and cleaning.

Embodiment 7-12

[0049] The preparation method of embodiment 7-12 comprises the following steps:

[0050] (1) Pretreatment before smelting: Before smelting, Sn is processed, and bulk Sn is prepared into filamentous Sn;

[0051] (2) Smelting: During the smelting process, Cu, P, Ni, and Ag elements are added first when feeding, and Sn is added after complete melting. Immediately after the feeding is completed, a covering agent is added to keep warm and prevent the burning of easily oxidized elements; Sn is added in the form of filament Sn, which increases the contact area between Sn and the melt, facilitates the uniform distribution of Sn in the melt, and solves the problem of Sn segregation; using dry plant ash as a covering agent, plant ash has a large coverage area , dense coverage and other advantages, effectively reducing the oxidation and burning loss of Sn during the smelting process, and also reducing the hydrogen absorption and oxygen content of the melt during refining;

[0052] (3) S...

Embodiment 13-23

[0053] The preparation method of embodiment 13-23 comprises the following steps:

[0054] (1) Pretreatment before smelting: Before smelting, Sn is treated to prepare bulk Sn into filamentous Sn; according to the actual needs of production, Ni is first smelted with Cu to make an intermediate alloy Cu- Ni, followed by subsequent smelting;

[0055] (2) Smelting: During the smelting process, Cu-P, Cu, Cu-Ni, and Ag elements are added first when feeding, and Sn is added after complete melting. Immediately after the feeding is completed, a covering agent is added to keep warm and prevent the burning of easily oxidized elements. Sn is added in the form of filament Sn, which increases the contact area between Sn and the melt, is conducive to the uniform distribution of Sn in the melt, and solves the problem of Sn segregation; using dry plant ash as a covering agent, plant ash It has the advantages of large coverage area and compact coverage, which effectively reduces the oxidation an...

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PUM

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Abstract

The invention relates to a low-silver-copper-based brazing filler metal and a preparation method thereof. The low-silver-copper-based brazing filler metal comprises Ag, Cu and P, wherein Sn, Ni and rare earth are further added, the weight percentages of the components are as follows: 1.5%-2.5% of Ag, 5.5%-6.6% of P, 5%-7% of Sn, 1.0-2.5% of Ni, not more than 0.05% of rare earth and the balance of Cu; the preparation method of the low-silver-copper-based brazing filler metal comprises the following steps of preparing Sn to filament Sn, smelting, continuously casting, continuously extruding, forming and cleaning to obtain the brazing filler metal. The brazing filler metal has the advantages of reasonable formulation design, lower brazing filler metal melting temperature, good wettability and mobility, stable quality of a soldered joint and long service life; a BCu80AgP copper-phosphorus brazing filler metal can be replaced, and the production cost of motor brazing is greatly reduced. The preparation method of the brazing filler metal can effectively solve a segregation problem of Sn, a preparation process is optimized, and the quality of the prepared brazing filler metal is remarkably improved.

Description

technical field [0001] The invention relates to a low-silver copper-based solder and a preparation method thereof, which is suitable for brazing in industries such as motors and machinery, and belongs to the field of brazing materials. Background technique [0002] In recent years, due to the increasingly fierce market competition and limited precious metal resources, the requirements of "reducing costs and reducing the amount of precious metal silver" have been put forward for brazing materials commonly used in machinery, motors and other industries. 15% BCu80AgP requires brazing material manufacturers to develop new brazing materials with lower silver content. [0003] Copper-phosphorus solders with less silver content are common on the market at present, such as BCu89PAg copper-phosphorus solder containing 5% silver, BCu91PAg copper-phosphorus solder containing 2% silver, etc. Although these copper-phosphorus solders are relatively low in price, they are The corrosion re...

Claims

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Application Information

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IPC IPC(8): B23K35/30B23K35/40
CPCB23K35/302B23K35/40C22C9/02
Inventor 余丁坤陈融黄世盛郭志刚李艳
Owner HANGZHOU HUAGUANG ADVANCED WELDING MATERIALS CO LTD
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