Hierarchical porous ZSM-5 zeolite catalyst for preparing acrolein through glycerin dehydration as well as preparation method and application of hierarchical porous ZSM-5 zeolite catalyst
A ZSM-5 and zeolite catalyst technology, which is applied in the direction of molecular sieve catalysts, carbon-based compound preparation, chemical instruments and methods, etc., can solve the problems of fast deactivation and achieve low cost, simple synthesis, and high selectivity.
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Embodiment 1
[0030] Prepare the initial gel in the following molar ratios: 1SiO 2 : 0.004Al 2 o 3 : 0.14Na 2 O : 0.3KCl : 0.1TPABr : 30H 2 O, silica sol, aluminum sulfate, and sodium hydroxide were dissolved in deionized water respectively, and potassium chloride, tetrapropylammonium bromide, and 5wt% 200nm-sized MFI seed crystals were added under constant stirring. The above mixture was stirred and aged at room temperature for 2 hours, then put into a stainless steel static crystallization kettle with a polytetrafluoroethylene liner, and reacted at 140° C. for 12 hours.
[0031] After crystallization, cool, filter and wash with deionized water for 3-4 times, and then dry the obtained sample at 80-120°C. The product is calcined in a muffle furnace or a tube furnace to remove the template agent, generally in an air atmosphere at 550 ° C for 4 to 6 hours. Then use ammonium nitrate solution with a concentration of 5wt% at 80°C for three consecutive ion exchanges (solution volume / produc...
Embodiment 2
[0033] Prepare the initial gel in the following molar ratios: 1SiO 2 : 0.004Al 2 o 3 : 0.15Na 2 O : 0.3KCl : 0.1TPABr : 60H 2 O, silica sol, aluminum sulfate, and sodium hydroxide were dissolved in deionized water respectively, and potassium chloride, tetrapropylammonium bromide, and 5 wt % MFI seed crystals of 200 nm in size were added under constant stirring. The above mixture was stirred and aged at room temperature for 2 hours, then put into a stainless steel static crystallization kettle with a polytetrafluoroethylene liner, and reacted at 120° C. for 12 hours.
[0034] After crystallization, cool, filter and wash with deionized water for 3-4 times, and then dry the obtained sample at 80-120°C. The product is calcined in a muffle furnace or a tube furnace to remove the template agent, generally in an air atmosphere at 550 ° C for 4 to 6 hours. Then use ammonium nitrate solution with a concentration of 5wt% at 80°C for three consecutive ion exchanges (solution volum...
Embodiment 3-6
[0036] The steps in this embodiment are exactly the same as those in Embodiment 1 above. The difference is that during the preparation of the reaction mixture, the Na used 2 O / Si 2 O changed from 0.14 to 0.10, 0.12, 0.16, 0.18.
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