Foam sealing composition and its preparation method and use
A technology of composition and foam, which is applied in the direction of drilling composition, chemical instruments and methods, earthwork drilling and mining, etc., can solve the problems of poor plugging effect and gas channeling, and achieve the purpose of inhibiting gas channeling, reducing surface tension, improving The effect of recovery factor
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Embodiment 1
[0026] Add 90g of dodecylamine and 0.3% potassium hydroxide of amine weight to the reaction kettle, add 450g of ethylene oxide, and react at 200°C for 1 hour; then add 60g of sodium chloroacetate, continue to react at 50°C for 20 hours, and finally add hydrochloric acid Neutralize to pH<3, stand to separate layers, add 30% by weight NaOH aqueous solution to the oil phase for neutralization, and obtain anion-nonionic foaming agent.
[0027] Lauryl ammonium chloride and the anion-nonionic foam agent prepared by the present invention were respectively dissolved in water, stirred for 30 minutes, and mixed with a 0.5% weight aqueous solution, and then the above-mentioned foam agent was mixed according to cation: anion-nonionic foam agent mole Mix evenly at a ratio of 1:8 to obtain foam composition 1, the composition and structure of which are shown in Table 1.
[0028] The above composition is mixed with the gas for gas driving to form the required foam blocking composition.
Embodiment 2
[0030] Add 140g eicosylamine and potassium hydroxide with 1% weight of amine into the reaction kettle, add 180g ethylene oxide and 67g propylene oxide, and react at 200°C for 10 hours; then add 90g sodium chloroacetate, and continue the reaction at 80°C for 8 hours, finally add hydrochloric acid to neutralize to pH<3, let stand to separate layers, and add 30% by weight NaOH aqueous solution to the oil phase to neutralize to obtain anion-nonionic foaming agent.
[0031] Octadecyl ammonium bromide and the anion-nonionic foam agent prepared by the present invention were respectively dissolved in water, stirred for 30 minutes, and mixed with a 0.5% weight aqueous solution, and then the above-mentioned foam agent was mixed according to the cation: anion-nonionic foam agent mole Mix evenly at a ratio of 1:10 to obtain foam composition 2, the composition and structure of which are shown in Table 1.
[0032] The above composition is mixed with the gas for gas driving to form the requi...
Embodiment 3
[0034]75g of decylamine and potassium hydroxide of 3% by weight of the amine were added to the reactor, 315g of ethylene oxide and 151g of propylene oxide were added, and reacted at 150°C for 3 hours; then 195g of Br(CH 2 ) 5 COOH, continue to react at 100°C for 1 hour, finally add hydrochloric acid to neutralize to pH3 ) 2 The aqueous solution is neutralized to obtain an anionic-nonionic foam.
[0035] Myristyl ammonium chloride and the anion-nonionic foam agent prepared by the present invention were dissolved in water respectively, stirred for 30 minutes, and mixed with a 0.5% weight aqueous solution, and then the above-mentioned foam agent was mixed according to cation: anion-nonionic foam agent mole Mix evenly at a ratio of 1:1.4 to obtain foam composition 3, the composition and structure of which are shown in Table 1.
[0036] The above composition is mixed with the gas for gas driving to form the required foam sealing system.
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