Metal-phase carrier loaded catalyst as well as preparation method and application

A technology of carrier loading and metal phase, which is applied in the field of catalysis, can solve the problems of pollution in the preparation process, insufficient catalytic activity, high chemical activity, etc., and achieve the effect of easy availability of raw materials, meeting the requirements of catalytic performance, and high permeability

Active Publication Date: 2014-04-30
ECO ENVIRONMENTAL ENERGY RES INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, these prior art catalysts have defects such as low melting point, high chemical activity, in

Method used

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  • Metal-phase carrier loaded catalyst as well as preparation method and application
  • Metal-phase carrier loaded catalyst as well as preparation method and application
  • Metal-phase carrier loaded catalyst as well as preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] This example provides the preparation of a nickel oxide-alumina catalyst supported by sintered nickel metal fiber carrier.

[0036] ① Weigh 15 grams of nickel metal fibers with a diameter of 8 microns and a length of 2 to 5 mm, 2.5 grams of cellulose fibers with a length of 0.1 to 1 mm and 1.5 liters of water, and add them to the mixer, fully stir to form a uniformly dispersed fiber slurry and then transfer In the paper machine, add water to 8.5 liters, stir, drain and shape; after drying, bake at 500°C in air for 1 hour; then sinter at 950°C in hydrogen for 1 hour, and the thickness of the product is controlled by pressing At 1 mm, a sintered metal nickel fiber support is obtained, expressed as 8-Ni-SMF;

[0037] ② Cut the sintered metal nickel fiber carrier obtained in step ① into discs with a diameter of 16 mm, weigh 5 grams and place them in a 50 ml beaker. At room temperature, pipette the suspension containing 0.1 g of aluminum powder with a particle size of 1 to ...

Embodiment 2

[0051] This example provides the preparation of a nickel oxide-alumina catalyst supported by sintered red copper metal fiber carrier.

[0052] ① Weigh 15 grams of copper metal fibers with a diameter of 8 microns and a length of 2 to 5 mm, 2.5 grams of cellulose fibers with a length of 0.1 to 1 mm, and 1.5 liters of water, and add them to the mixer, fully stir to form a uniformly dispersed fiber slurry and then transfer In the paper machine, add water to 8.5 liters, stir, drain and shape; after drying, bake in air at 250°C for 1 hour; then sinter in hydrogen at 900°C for 1 hour to obtain a sintered metal copper fiber carrier. Expressed as 8-Cu-SMF;

[0053] ② Cut the sintered metal red copper fiber carrier obtained in step ① into discs with a diameter of 16 mm, weigh 5 grams and place them in a 50 ml beaker. At room temperature, pipette an equal volume of suspension containing 0.4 grams of aluminum powder with a particle size of 1 to 3 microns to impregnate the metal phase car...

Embodiment 3

[0060] This example provides the preparation of an iron oxide-alumina catalyst supported on a red copper fiber carrier.

[0061]① Weigh 15 grams of copper metal fiber (expressed as Cu-fiber) with a diameter of 30 microns and a length of 5-10 mm, and at room temperature, pipette the suspension containing 0.075 grams of aluminum powder with a particle size of 1-3 microns. After impregnating the metal phase carrier with equal volume of liquid and drying to disperse the aluminum powder particles on the surface of the metal phase carrier, the solid-solid alloying reaction between the aluminum powder particles and the surface layer of the metal phase carrier was carried out at 600°C in a high-purity protective atmosphere for 2 hours. Obtain a metal phase carrier with surface alloying;

[0062] ② The product obtained in step ① is subjected to an aluminum extraction treatment with a 5% hydrochloric acid aqueous solution at room temperature to 60° C. for 1 hour, rinsed with distilled w...

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Abstract

The invention relates to a metal-phase carrier loaded catalyst as well as a preparation method and application of catalyst in preparation of methane and methane synthesized gas reaction by catalyzing carbon oxide or (and) carbon dioxide. The metal-phase carrier loaded catalyst comprises active component metal oxide which is loaded on a metal-phase carrier and auxiliary metal oxide, the general formula of the metal-phase carrier loaded catalyst is as follows: xM1O-yM2O/ZT, wherein M1O represents the active component metal oxide, M2O represents the auxiliary metal oxide, ZT represents the metal-phase carrier, x represents the mass percent of the active component metal oxide in the catalyst, and y represents the mass percent of the auxiliary metal oxide in the catalyst. The catalyst has the advantages of high activity, high stability, excellent heat conduction property, high permeability, convenience in use, long service life, simplicity in preparation and the like, the heat effect difficulty in strong heat discharging/suction reaction in the chemical industry field can be effectively solved, and the catalyst can be used in the methanation process and the methane-producing synthesized gas reaction.

Description

technical field [0001] The invention belongs to the technical field of catalysis, and relates to a catalyst and its preparation method and application, in particular to a catalyst supported by a metal phase and its preparation method and application. The catalyst can be used to catalyze the addition of carbon monoxide or (and) carbon dioxide Hydrogen reacts in the synthesis of methane and reforming of methane to synthesis gas. Background technique [0002] Natural gas is a safe, clean and high-quality energy, the main component of which is methane (CH 4 ), has the advantages of high calorific value and low pollution, and is widely used in power generation, chemical industry and civil use. Since Sabatier and Senderens first used carbon monoxide and hydrogen to synthesize methane on a nickel-based catalyst in 1902, the methanation reaction has developed rapidly and has been widely used in gas purification processes. [0003] The key to the methanation process is the developm...

Claims

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Application Information

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IPC IPC(8): B01J23/755B01J23/83B01J23/78B01J23/889B01J23/888C07C9/04C07C1/04C07C1/12C01B3/40C01B3/26
CPCB01J21/04B01J23/70B01J23/76B01J35/023C01B3/34C01B2203/0238C01B2203/0244C01B2203/1241Y02P20/141
Inventor 路勇李亚坤柴瑞娟刘晔徐彬周晓莹萧锦诚
Owner ECO ENVIRONMENTAL ENERGY RES INST
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