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Hyperbranched triazine charring agent microcapsule flame retardant and preparation method thereof

A hyperbranched triazine and microencapsulation technology, applied in the field of flame retardants, can solve the problems of deteriorating the comprehensive physical properties of flame retardant materials, poor dispersion performance of flame retardant materials, and high polarity of flame retardants, and achieve excellent flame retardant effect. , good flame retardant performance, high carbon-forming effect

Active Publication Date: 2014-04-30
UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In order to solve the shortcomings of the above-mentioned prior art, the present invention proposes a triazine hyperbranched macromolecular char-forming agent with good thermal stability and high char-forming rate as a capsule material, and microencapsulates the flame retardant A coated hyperbranched triazine char-forming agent microencapsulated flame retardant and a preparation method thereof to solve the problem of high polarity of existing flame retardants, poor dispersion performance in flame retardant materials, deterioration of comprehensive physical properties of flame retardant materials, etc. problem

Method used

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  • Hyperbranched triazine charring agent microcapsule flame retardant and preparation method thereof
  • Hyperbranched triazine charring agent microcapsule flame retardant and preparation method thereof

Examples

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Embodiment 1

[0036]In this embodiment, the hyperbranched triazine char-forming agent microencapsulated flame retardant is based on cyanuric chloride, diamine, a solvent for dispersing cyanuric chloride, a solvent for dissolving diamine, a flame retardant, a surfactant, and an acid-binding agent. cyanuric chloride and diamine under the action of acid-binding agent and surfactant to obtain hyperbranched triazine char-forming agent as the coating layer, and the flame retardant as the core microencapsulated flame retardant. Wherein the diamine is selected piperazine, the solvent for dispersing cyanuric chloride is selected ethanol, the solvent for dissolving diamine is selected acetone, the flame retardant is selected aluminum hydroxide, the surfactant is selected OP-10, and the acid-binding agent is selected NaOH, as follows To prepare:

[0037] a. Dissolve 44.79g (0.52mol) of piperazine in 14.5L of acetone to obtain a piperazine solution; disperse 46.10g (0.25mol) of cyanuric chloride in 250...

Embodiment 2

[0044] In this embodiment, the hyperbranched triazine char-forming agent microencapsulated flame retardant is based on cyanuric chloride, diamine, a solvent for dispersing cyanuric chloride, a solvent for dissolving diamine, a flame retardant, a surfactant, and an acid-binding agent. cyanuric chloride and diamine under the action of acid-binding agent and surfactant to obtain hyperbranched triazine char-forming agent as the coating layer, and the flame retardant as the core microencapsulated flame retardant. Among them, ethylenediamine is selected as the diamine, ethanol is selected as the solvent for dispersing cyanuric chloride, water is selected as the solvent for dissolving diamine, nickel-iron double hydroxide is selected as the flame retardant, and tetradecyl trimethyl chloride is selected as the surfactant. Ammonium, acid-binding agent select Na for use CO , prepare according to the following steps:

[0045] a. Dissolve 30.05g (0.5mol) of ethylenediamine in 240ml of wat...

Embodiment 3

[0052] In this embodiment, the hyperbranched triazine char-forming agent microencapsulated flame retardant is based on cyanuric chloride, diamine, a solvent for dispersing cyanuric chloride, a solvent for dissolving diamine, a flame retardant, a surfactant, and an acid-binding agent. cyanuric chloride and diamine under the action of acid-binding agent and surfactant to obtain hyperbranched triazine char-forming agent as the coating layer, and the flame retardant as the core microencapsulated flame retardant. Wherein diamine selects N-aminoethylpiperazine for use, the solvent for dispersing cyanuric chloride selects ethanol for use, the solvent for dissolving diamine selects water and ethanol mixed solvent for use, flame retardant selects inorganic aluminum hypophosphite for use, surfactant selects Pingpingjia, Acid-binding agent selects KOH for use, prepares according to the following steps:

[0053] a. Dissolve 19.38g (0.15mol) of N-aminoethylpiperazine in a mixed solution of...

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Abstract

The invention discloses a hyperbranched triazine charring agent microcapsule flame retardant. The hyperbranched triazine charring agent microcapsule flame retardant is characterized in that a solvent of cyanuric chloride, diamine and disperse cyanuric chloride, a solvent into which diamine is dissolved, a flame retardant, a surfactant and an acid-binding agent are taken as raw materials; the microcapsule flame retardant taking a hyperbranched triazine charring agent as a coating layer and taking the flame retardant as a core is obtained from the cyanuric chloride and the diamine under the action of the acid-binding agent and the surfactant. The hyperbranched triazine charring agent microcapsule flame retardant disclosed by the invention is continuous in reaction process, short in reaction time, and high in production efficiency, the reaction cost is reduced, the flame retardant has better heat stability, high charring property, good dispersion property and good flame retardant property in a polymer; the flame retardant product is good in overall performance; the hyperbranched triazine charring agent microcapsule flame retardant can be widely applied to polymer materials such as plastics, rubber, coatings and adhesives, and has a broad application prospect.

Description

technical field [0001] The invention relates to the field of flame retardants, in particular to a halogen-free flame retardant coated with in-situ polymerization and a hyperbranched triazine char-forming agent as a capsule material and a flame retardant as a core material and a preparation method thereof. Background technique [0002] Flame retardant is an additive that can make polymers and related materials difficult to catch fire or slow down the burning speed. Flame retardants can be divided into halogen-containing flame retardants and halogen-free flame retardants according to whether they contain halogen. Among them, halogen-containing flame retardants will produce more smoke and toxic corrosive gases during combustion, which will pollute the environment. For this reason, the EU promulgated two directives in 2003, the "Waste Electrical and Electronic Equipment Directive" (referred to as "WEEE") and the "Directive on the Prohibition of the Use of Certain Hazardous Subst...

Claims

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Application Information

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IPC IPC(8): C08K9/10C08K3/22C08K3/32C08K3/02C08K3/38C08G73/06
Inventor 胡源汪碧波宋磊温攀月
Owner UNIV OF SCI & TECH OF CHINA
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