Hyperbranched triazine charring agent microcapsule flame retardant and preparation method thereof
A hyperbranched triazine and microencapsulation technology, applied in the field of flame retardants, can solve the problems of deteriorating the comprehensive physical properties of flame retardant materials, poor dispersion performance of flame retardant materials, and high polarity of flame retardants, and achieve excellent flame retardant effect. , good flame retardant performance, high carbon-forming effect
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Embodiment 1
[0036]In this embodiment, the hyperbranched triazine char-forming agent microencapsulated flame retardant is based on cyanuric chloride, diamine, a solvent for dispersing cyanuric chloride, a solvent for dissolving diamine, a flame retardant, a surfactant, and an acid-binding agent. cyanuric chloride and diamine under the action of acid-binding agent and surfactant to obtain hyperbranched triazine char-forming agent as the coating layer, and the flame retardant as the core microencapsulated flame retardant. Wherein the diamine is selected piperazine, the solvent for dispersing cyanuric chloride is selected ethanol, the solvent for dissolving diamine is selected acetone, the flame retardant is selected aluminum hydroxide, the surfactant is selected OP-10, and the acid-binding agent is selected NaOH, as follows To prepare:
[0037] a. Dissolve 44.79g (0.52mol) of piperazine in 14.5L of acetone to obtain a piperazine solution; disperse 46.10g (0.25mol) of cyanuric chloride in 250...
Embodiment 2
[0044] In this embodiment, the hyperbranched triazine char-forming agent microencapsulated flame retardant is based on cyanuric chloride, diamine, a solvent for dispersing cyanuric chloride, a solvent for dissolving diamine, a flame retardant, a surfactant, and an acid-binding agent. cyanuric chloride and diamine under the action of acid-binding agent and surfactant to obtain hyperbranched triazine char-forming agent as the coating layer, and the flame retardant as the core microencapsulated flame retardant. Among them, ethylenediamine is selected as the diamine, ethanol is selected as the solvent for dispersing cyanuric chloride, water is selected as the solvent for dissolving diamine, nickel-iron double hydroxide is selected as the flame retardant, and tetradecyl trimethyl chloride is selected as the surfactant. Ammonium, acid-binding agent select Na for use CO , prepare according to the following steps:
[0045] a. Dissolve 30.05g (0.5mol) of ethylenediamine in 240ml of wat...
Embodiment 3
[0052] In this embodiment, the hyperbranched triazine char-forming agent microencapsulated flame retardant is based on cyanuric chloride, diamine, a solvent for dispersing cyanuric chloride, a solvent for dissolving diamine, a flame retardant, a surfactant, and an acid-binding agent. cyanuric chloride and diamine under the action of acid-binding agent and surfactant to obtain hyperbranched triazine char-forming agent as the coating layer, and the flame retardant as the core microencapsulated flame retardant. Wherein diamine selects N-aminoethylpiperazine for use, the solvent for dispersing cyanuric chloride selects ethanol for use, the solvent for dissolving diamine selects water and ethanol mixed solvent for use, flame retardant selects inorganic aluminum hypophosphite for use, surfactant selects Pingpingjia, Acid-binding agent selects KOH for use, prepares according to the following steps:
[0053] a. Dissolve 19.38g (0.15mol) of N-aminoethylpiperazine in a mixed solution of...
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