A blue light curable ink composition for textiles and digital jet printing curing method thereof

A composition and textile technology, applied in the field of blue light curable ink composition for textiles and its digital jet printing and curing, can solve the problems of softness, elasticity, toughness and other wearing properties that are not suitable for flexible textiles, and can solve the problems of subsequent processing and consumption. Water energy consumption problem, good tensile strength, safe and efficient printing fabric effect

A composition and textile technology, applied in the field of blue light curable ink composition for textiles and its digital jet printing and curing, can solve the problems of softness, elasticity, toughness and other wearing properties that are not suitable for flexible textiles, and can solve the problems of subsequent processing and consumption. Water energy consumption problem, good tensile strength, safe and efficient printing fabric effect

CN103788771BActive Publication Date: 2015-10-21ZHEJIANG SCI-TECH UNIV
7 Cites 4 Cited by

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A blue light curable ink composition for textiles and digital jet printing curing method thereof
  • A blue light curable ink composition for textiles and digital jet printing curing method thereof
  • A blue light curable ink composition for textiles and digital jet printing curing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A kind of blue light curing digital inkjet printing ink composition for textiles, its each component is as follows:

[0028] The first component, oligomer: urethane acrylate (self-made) 60wt%,

[0029] Monomer: butyl acrylate (Jiangsu Sanmu) 10wt%,

[0030] Monomer: SM612 (Jiangsu Sanmu) urethane monoacrylate 10wt%,

[0031] Monomer: isobornyl acrylate (Aladdin reagent) 20wt%;

[0032] The second component, based on the first component as 100%,

[0033] Blue light initiator: Chivacure534 (Taiwan Chi Titanium) 1wt%,

[0034] Activator: Chivacure OPD (Taiwan Chi Titanium) 1wt%,

[0035] Colorant: Disperse Turquoise Blue SGL (Zhejiang Longsheng) 2wt%,

[0036] Hyperdispersant Tech-5401 (Tiger polymer) 0.4wt%.

[0037] Among them, the blue light initiator Chivacure534 is bis-2,6-difluoro-3-pyrrole phenyl titanocene; the activator Chivacure OPD is isooctyl 4-dimethylaminobenzoate;

[0038] The viscosity of self-made urethane acrylate is lower than 1.0Pa·s, and commerc...

Embodiment 2

[0042] A kind of blue light curing digital inkjet printing ink composition for textiles, its each component is as follows:

[0043] The first component, oligomer: urethane acrylate (self-made) 60wt%,

[0044] Monomer: butyl acrylate (Jiangsu Sanmu) 10wt%,

[0045] Monomer: SR285 (Sartomer) tetrahydrofuran acrylate 10wt%,

[0046] Monomer: hydroxyethyl methacrylate (Aladdin reagent) 20wt%;

[0047] The second component, based on the first component as 100%,

[0048] Blue light initiator: Chivacure534 (Taiwan Chi Titanium) 1wt%,

[0049] Activator: Chivacure OPD (Taiwan Chi Titanium) 1wt%,

[0050] Colorant: 6505 Qinglianseyuan RNC (Hangzhou Xinchen Pigment) 1wt%,

[0051] Hyperdispersant Tech-5401 (Tiger polymer) 0.6wt%.

[0052] Among them, the blue light initiator Chivacure534 is bis-2,6-difluoro-3-pyrrole phenyl titanocene; the activator Chivacure OPD is isooctyl 4-dimethylaminobenzoate; the raw material and synthesis method of self-made polyurethane acrylate With emb...

Embodiment 3

[0055] A kind of blue light curing digital inkjet printing ink composition for textiles, its each component is as follows:

[0056] The first component, oligomer: urethane acrylate (self-made) 60wt%,

[0057] Monomer: Styrene (Tianjin Kemiou Chemical) 15wt%,

[0058] Monomer: tetrahydrofurfuryl acrylate (Shanghai TCI reagent) 5wt%,

[0059] Monomer: isooctyl acrylate (Aladdin reagent) 20wt%,

[0060] The second component, based on the first component as 100%,

[0061] Blue light initiator: camphorquinone (Sigma Aldrich) 0.5wt%,

[0062] Activator: IHT-PI EDB (Yingli Technology) 0.5wt%,

[0063] Colorant: Disperse Red 3B (Zhejiang Zhenguang Chemical Industry) 2wt%,

[0064] Hyperdispersant Tech-5401 (Tiger polymer) 0.4wt%.

[0065] Among them, the blue light initiator camphorquinone is 1,7,7-trimethyl-bicyclo[2.2.1]heptane-2,3-dione; the activator IHT-PIEDB is 4-dimethylaminobenzoic acid ethyl Ester; The raw material and synthetic method of self-made polyurethane acrylat...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
surface tensionaaaaaaaaaa
Login to View More

Abstract

The invention relates to the technical field of light curing ink, and in particular relates to a blue light curing ink composition for textile and a digital jet printing and curing method of the blue light curing ink composition. The blue light curing ink composition for textile comprises a first component and a second component, wherein the first component comprises oligomer and active diluent, and the oligomer accounts for 40-60wt% of the total weight of the oligomer and the active diluent; the second component comprises 0.25-1wt% of blue light initiator, 0.25-1.5wt% of activating agent, 0.1-5wt% of coloring agent and 0.1-1wt% of dispersion stabilizer by taking the weight of the first component as 100%. According to the blue light curing ink formulation and the digital jet printing processing method of the formulation, monomer and the oligomer are used for replacing macromolecule adhesive, so that the ink is guaranteed to have good stability and fluidity in the digital jet printing process; after digital jet printing, polymerization crosslinking between the monomer and the oligomer can be rapidly triggered on the surface of the fiber fabric by the ink on the printed fabric within a few minutes, even tens of seconds under the irradiation of blue light.

Description

technical field [0001] The invention relates to the technical field of light-curable ink, in particular to a composition of blue light-curable ink for textiles and a digital jet printing curing method thereof. Background technique [0002] Digital inkjet printing of textiles has revolutionary significance to traditional printing processing. However, in the dye-based digital inkjet printing process, post-processing such as steaming, water washing, and drying is still required, and there are problems of water consumption and energy consumption. In addition, due to the affinity of dyes to fibers, dye-based digital printing has printing limitations on substrates and cannot meet the printing requirements of multi-component blended fabrics. It is an effective way to solve the above problems to use pigment ink instead of dye ink in digital inkjet printing. However, due to the macromolecular binder contained in the paint ink, it is very easy to cause nozzle clogging and affect the...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
21 Oct 2015
Publication
CN103788771B
IPC
C09D11/30
Inventors
邵建中; 黄益