Composition containing vinyl alcohol polymer

一种组合物、乙烯醇的技术，应用在含颜料涂层、印刷、纺织品和造纸等方向，能够解决无法溶解、未消除等问题，达到高耐水性或抗粘连性、耐水性或抗粘连性优异、操作性优异的效果

Inactive Publication Date: 2014-05-14
KURARAY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in these silyl group-containing PVAs, setting the upper limit of the above-mentioned product (P×S) to 370 does not eliminate the need to increase the content of monomer units having silyl groups to improve the performance of silyl group-containing PVA. Trade-off relationship between characteristics and improvement of water solubility, etc.
That is, as described in paragraph 0009 of the above-mentioned Japanese Patent Laid-Open No. 2004-43644, when the product (P×S) is 370 or more, there is an inconvenience in the following operations, that is, if the PVA containing a silyl group is prepared, When adding alkali or acid to the aqueous solution, it cannot be dissolved
In other words, the above-mentioned silyl group-containing PVA cannot be said to sufficiently solve the above-mentioned inconvenience.
[0005] In addition, for films obtained from compositions containing PVA, higher water resistance (including boiling water resistance) or anti-blocking properties may be required in accordance with various usage forms, etc.

Method used

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  • Composition containing vinyl alcohol polymer
  • Composition containing vinyl alcohol polymer
  • Composition containing vinyl alcohol polymer

Examples

Experimental program
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Effect test

Embodiment

[0191] Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited to these examples. In addition, in the following examples and comparative examples, unless otherwise specified, parts and % represent parts by mass and % by mass, respectively.

[0192] It should be noted that the monomer (monomer A) having a silyl group used in Examples and Comparative Examples is as follows:

[0193] MAmPTMS : 3-Methacrylamidopropyltrimethoxysilane

[0194] MAmOTMS : 8-Methacrylamidopropyltrimethoxysilane

[0195] MAmDDTMS: 12-Methacrylamidododecyltrimethoxysilane

[0196] MAmODTMS: 18-methacrylamidooctadecyltrimethoxysilane

[0197] 4-PTMS : 4-pentenyltrimethoxysilane

[0198] VMS : Vinyltrimethoxysilane

[0199] MAmMTMS : Methacrylamidomethyltrimethoxysilane

[0200] AMPTMS : 2-acrylamido-2-methylpropyltrimethoxysilane.

[0201] In addition, the compound (B) and polyamide polyamine epichlorohydrin resin (C) used in ...

Synthetic example 1

[0212] [Synthesis Example 1] Preparation of PVA1

[0213] In a 6L detachable flask equipped with a stirrer, a reflux cooling pipe, a nitrogen introduction pipe, a comonomer dropping port, and an initiator adding port, 1,500 g of vinyl acetate, 500 g of methanol, and 1.87 g of methanol having the above formula In the MAmPTMS of the monomer (monomer A) of the group represented by (1), nitrogen substitution was performed in the system for 30 minutes while nitrogen bubbling was performed. In addition, as a delay solution (delay solution), MAmPTMS was dissolved in methanol to prepare a comonomer solution with a concentration of 8%, and nitrogen replacement was performed by bubbling with nitrogen gas. The temperature rise of the reactor was started, and when the internal temperature reached 60°C, 0.8 g of 2,2'-azobisisobutyronitrile (AIBN) was added to start polymerization. The delayed solution was added dropwise, and the polymerization was carried out at 60° C. for 2.7 hours while...

Embodiment 1

[0231] (composition and film preparation)

[0232] A 4% aqueous solution of PVA1 prepared was added to a 10% aqueous solution of titanium lactate (Ti compound: TC-310 manufactured by Matsumoto Pharmaceutical Co., Ltd.), so that the titanium lactate solid content relative to 100 mass parts of PVA solid content was 10 mass parts, and obtained Composition of Example 1. This composition was cast at 20° C. to obtain a film with a thickness of 40 μm.

[0233] (Composition and Preparation of Thermosensitive Recording Material)

[0234] 90 g of aluminum hydroxide powder (manufactured by Showa Denko Co., Ltd., Higilite H42) was poured into 210 g of distilled water, and stirred by hand. Then, it was stirred at a rotation speed of 13,500 rpm for 5 minutes using a homomixer (manufactured by IKA-Labortechnik, T-25-SI type) to prepare a dispersion liquid of aluminum hydroxide (aluminum hydroxide concentration: 30%). In addition, the PVA1 obtained above was dissolved in water to prepare a...

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Abstract

The purpose of the present invention is to provide a composition with which it is possible to obtain a film that is superior in terms of being handled and has high water resistance and blocking resistance; a coating agent comprising the composition; a coated object obtained using the coating agent; a thermosensitive recording material; an ink jet recording material; a peelable paper stencil; and a method for producing a coated object. The present invention relates to a composition comprising a vinyl alcohol polymer (A), which contains repeating units having groups represented by formula (1) and which satisfies formula (I), and compound (B) comprising at least one atom selected from the group consisting of silicon, titanium, and zirconium, wherein the content of compound (B) is 0.01 to 900 parts by mass per 100 parts by mass of vinyl alcohol polymer (A). 370<=P*S<=6,000 (I) P: viscosity-average degree of polymerization, S: content of repeating units (mol%).

Description

technical field [0001] The present invention relates to a composition containing a vinyl alcohol polymer, a coating agent containing the composition, a coated product obtained by using the coating agent, a heat-sensitive recording material, an inkjet recording material and a release paper base paper, and a coating method of preparation. Background technique [0002] Polyvinyl alcohol polymers represented by polyvinyl alcohol (hereinafter sometimes abbreviated as "PVA") are known as water-soluble synthetic polymers and are widely used as raw materials for synthetic fiber vinylon, paper processing agents, fiber processing agents, Adhesives, stabilizers for emulsion polymerization and suspension polymerization, adhesives for inorganic substances, films, etc. Compared with other water-soluble synthetic polymers, PVA is particularly excellent in strength characteristics and film-forming properties. Therefore, compositions containing PVA exhibit the above-mentioned characteristi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L29/04B41M5/00B41M5/337B41M5/50B41M5/52C08F8/12C08F216/06C08F230/08C08K3/36C08K5/54C09D7/12C09D129/04
CPCB41M5/443B41M5/529B41M2205/32C08F216/06C09D5/26C09D129/04C09D143/04C08F230/085D21H17/36D21H19/20D21H19/60D21H27/001C08K3/36C08K5/544C08K5/098C08K5/54C09D133/24
Inventor 田冈悠太新居真辅仲前昌人
Owner KURARAY CO LTD
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