Polycarbonate containing nonlinear optical chromophores, synthesis method and application thereof

A technology of nonlinear optics and polycarbonate, applied in the direction of nonlinear optics, optics, instruments, etc., can solve the problems of difficult control of the amount of chromophore molecules attached to nonlinear optics, poor material reproducibility, etc., to achieve convenient operation, The effect of simple synthesis method

Inactive Publication Date: 2014-06-04
TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although post-functionalization can attach different nonlinear optical chromophore molecules, the amount of attachment of nonlinear optical chromophore molecules is not easy to control through post-functionalization, and the reproducibility of the material is poor.

Method used

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  • Polycarbonate containing nonlinear optical chromophores, synthesis method and application thereof
  • Polycarbonate containing nonlinear optical chromophores, synthesis method and application thereof
  • Polycarbonate containing nonlinear optical chromophores, synthesis method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] A polycarbonate (PC-TCFC-1) containing a nonlinear optical chromophore molecule was synthesized with the following structure:

[0039]

[0040] The synthetic route is as follows:

[0041]

[0042] Dissolve bisphenol A (80mg, 0.350mmol) and d-TCF (100mg, 0.256mmol) in 5mL of dry 1,2-dichloroethane in a 50mL two-necked bottle. After the above materials are dissolved, drop Add 0.5 mL of pyridine to obtain a mixed solution, install a reflux condenser with a drying tube on the top and a dropping funnel on a two-necked flask, heat the mixed solution to 83°C to reflux the mixed solution, and weigh 250 mg (0.708 mmol) of bisphenol A After dissolving dichloroformate with 20mL of dry 1,2-dichloroethane, use a dropping funnel to slowly add the obtained bisphenol A dichloroformate solution to the solution containing d-TCF, In the mixed solution of bisphenol A and pyridine, after the dropwise addition was completed, the polymerization reaction was continued at 83° C. for 3 ho...

Embodiment 2

[0045] Polycarbonate (PC-TCFC-2) containing nonlinear optical chromophore molecules was synthesized with the following structure:

[0046]

[0047] Dissolve bisphenol A (50mg, 0.219mmol) and d-TCF (150mg, 0.385mmol) in 5mL of dry 1,2-dichloroethane in a 50mL two-necked bottle. 0.5mL pyridine to obtain a mixed solution, install a reflux condenser with a drying tube on the top and a dropping funnel on a two-necked flask, heat the mixed solution to 83°C to reflux the mixed solution, and weigh 250mg (0.708mmol) of bisphenol A After dissolving chloroformate with 20mL of dry 1,2-dichloroethane, use a dropping funnel to slowly add the obtained bisphenol A dichloroformate solution to the solution containing d-TCF, bis In the mixed solution of phenol A and pyridine, after the dropwise addition was completed, the polymerization reaction was continued at 83° C. for 3 hours. After the polymerization reaction is finished, cool to room temperature, pour the obtained polymer solution int...

Embodiment 3

[0050] Synthesis of polycarbonate PC-TCFC-2 containing nonlinear optical chromophore molecules, its synthetic route is as follows:

[0051]

[0052] Dissolve 0.113g of sodium hydroxide (2.83mmol) in 5mL of water to prepare an aqueous solution of sodium hydroxide, add d-TCF (300mg, 0.769mmol), bisphenol A (100mg, 0.438mmol) and 4mg of benzyltriethylamine chloride Add it to the aqueous sodium hydroxide solution, and after it is completely dissolved, add 5mL of dichloromethane to the resulting aqueous solution to obtain a mixed solution, and lower the temperature of the mixed solution to (0±5)°C in an ice-salt bath; weigh 500mg (1.416mmol) Bisphenol A dichloroformate, after dissolving in 20mL of dry dichloromethane, slowly add the bisphenol A dichloroformate solution to the temperature (0±5)℃ containing d-TCF, bisphenol A and benzyltriethylamine chloride mixed solution and stirred, after the dropwise addition, the temperature was slowly raised to room temperature, and continue...

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Abstract

The present invention relates to a polycarbonate containing nonlinear optical chromophores, a synthesis method and an application thereof. According to the present invention, bischloroformate and nonlinear optical chromophores containing double hydroxyl groups are subjected to copolymerization so as to successfully introduce the nonlinear optical chromophore molecule into the polymer chain segment of the polycarbonate, and concurrently a bisphenol monomer is introduced to adjust the number of the nonlinear optical chromophore molecules in the chain segment so as to effectively prepare the suspension connection type polycarbonate electro-optic material containing a certain amount of the nonlinear optical chromophore molecules; after the polycarbonate containing the nonlinear optical chromophores is dissolved with an organic solvent and then is subjected to film coating, the maximum electro-optic coefficient of the prepared polarized electro-optic polymer film is 75 pm/V, wherein the prepared electro-optical material has a high glass transition temperature, such that the nonlinear optical chromophore molecules have good orientational stability in the material; and the polycarbonate containing the nonlinear optical chromophores has the following structure.

Description

technical field [0001] The invention relates to organic / polymer electro-optical materials, in particular to polycarbonate containing nonlinear optical chromophoric groups and its synthesis method and application. Background technique [0002] With the increasing use of organic electro-optic materials in the fields of signal processing and communication, the research of organic electro-optic materials has also received more and more attention. Compared with traditional inorganic / semiconductor electro-optic materials, organic electro-optic materials have more excellent electro-optic properties. Of course, in order to put organic electro-optic materials into practical applications, there are still many problems to be solved, such as enhancing the stability of materials and further improving the electro-optic properties of materials. [0003] Polycarbonate is a class of excellent optical materials, which has been widely used in the preparation of organic electro-optic materials...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G64/38C08G64/24G02F1/361
Inventor 邱玲邓国伟甄珍薄淑晖周婷婷黄鹤燕司鹏彭诚诚
Owner TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
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