Preparation method of super-hydrophobic porous mesh for oil water separation

An oil-water separation and superphobic technology, applied in separation methods, liquid separation, chemical instruments and methods, etc., can solve the problems of complex operation, high cost, membrane fouling, etc., and achieve simple operation, low cost, and controllable experimental parameters. Effect

Inactive Publication Date: 2014-06-11
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The preparation of porous materials by the hydrogen bubble template method is a simple, convenient, low-cost, and parameter-controllable method. This method can be deposited on copper mesh to obtain a three-dimensional porous network film. The porous film is prepared using dynamic hydrogen bubbles as a tem

Method used

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  • Preparation method of super-hydrophobic porous mesh for oil water separation
  • Preparation method of super-hydrophobic porous mesh for oil water separation
  • Preparation method of super-hydrophobic porous mesh for oil water separation

Examples

Experimental program
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Example Embodiment

[0019] Specific embodiment 1: This embodiment prepares a superhydrophobic mesh porous film according to the following steps:

[0020] Such as figure 2 As shown, the hydrogen bubble template electrodeposition method of porous mesh Sn film is a platinum sheet (1cm 2 ) Is used as the anode, and the counter electrode uses copper mesh (aperture 300μm, area 3*3cm 2 ) Is the cathode, and its electroplating device such as figure 1 Shown. The pretreatment of the copper mesh in the experiment included polishing, degreasing, acid etching, water washing, absolute ethanol soaking, acetone cleaning, and low-temperature blast drying. The composition of the plating solution is 0.01-0.2mol·L -1 SnSO 4 And 0.01-0.2mol·L -1 H 2 SO 4 , PH is controlled in the range of 4.0±0.5, and the current density range of electrodeposition is 0.1-6.0A·cm -2 , The deposition time is 5-40s. By adjusting the deposition parameters such as current density, deposition time, and composition of the plating solution, th...

Example Embodiment

[0023] Specific implementation manner 2: In this implementation manner, the superhydrophobic mesh porous film is prepared according to the following steps:

[0024] Hydrogen bubble template electrodeposition of mesh porous Sn film is a platinum sheet (1cm 2 ) Is used as the anode, and the counter electrode uses copper mesh (aperture 300μm, area 3*3cm 2 ) Is the cathode. The pretreatment of the copper mesh in the experiment included polishing, degreasing, acid etching, water washing, absolute ethanol soaking, acetone cleaning, and low-temperature blast drying. The composition of the plating solution is 0.05mol·L -1 SnSO 4 And 1.5mol·L -1 H 2 SO 4 , PH is controlled within the range of 4.0±0.5, and the current density of electrodeposition is 2.0A·cm -2 , The deposition time is 10s. The deposited mesh film should be rinsed immediately with distilled water, soaked in absolute ethanol and dried to obtain a mesh porous Sn film.

[0025] Such as image 3 As shown, the area of ​​the super...

Example Embodiment

[0026] Specific embodiment 3: In this embodiment, the superhydrophobic mesh porous film is prepared according to the following steps:

[0027] Hydrogen bubble template electrodeposition of mesh porous Sn film is a platinum sheet (1cm 2 ) Is used as the anode, and the counter electrode uses copper mesh (aperture 300μm, area 3*3cm 2 ) Is the cathode. The pretreatment of the copper mesh in the experiment included polishing, degreasing, acid etching, water washing, absolute ethanol soaking, acetone cleaning, and low-temperature blast drying. The composition of the plating solution is 0.1mol·L -1 SnSO 4 And 1.5mol·L -1 H 2 SO 4 , PH is controlled within the range of 4.0±0.5, and the current density of electrodeposition is 2.0A·cm -2 , The deposition time is 10s. The deposited mesh film should be rinsed immediately with distilled water, soaked in absolute ethanol and dried to obtain a mesh porous Sn film.

[0028] Soak the above mesh porous Ni film in an ethanol solution containing 5mmo...

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Abstract

The invention discloses a preparation method of a super-hydrophobic porous mesh for oil water separation. A porous meshy Sn film is prepared by using a hydrogen bubble template method. The concrete steps are realized under the following conditions that a platinum sheet is used as an anode, a copper wire mesh is used as an electrode cathode, a plating solution comprises the following components: 0.01-0.2mol.L<-1> of SnSO4 and 0.01-0.2mol.L<-1> of H2SO4, the pH value is equal to 4.0+/-0.5, the current density is 0.1-6.0A.cm<-2>, and the deposition time is 5-40s. The hydrogen bubble template method for preparing a porous material has the advantages of simplicity, convenience, low cost and parameter controllability; a three-dimensional porous meshy film can be obtained through depositing on the copper wire mesh by using the method; the porous film is prepared by taking a dynamic hydrogen bubble as a template; compared with a hard template method, the method has the advantages that the template is not needed to be removed, the problems such as high cost, complexity in operation and serious film pollution in the traditional method are solved, and the industrial production is expected to be realized.

Description

technical field [0001] The invention relates to a preparation method of a super-hydrophobic porous network film. Background technique [0002] Oily wastewater is a common wastewater in industry. Direct discharge will cause serious harm to the environment, indirectly pollute the atmosphere and soil, and seriously endanger human health. Oil-water separation technology has an important impact in petrochemical and other fields, including the recovery of sea waste oil, oil production wastewater, and the separation of organic solvents. Due to the large difference in surface tension between water and oil, choosing a surface with different wettability to water and oil can selectively adsorb one phase and repel the other phase. Enhancing the wettability of the surface can improve the separation efficiency. [0003] The superhydrophobic phenomenon ubiquitous in nature, the main factors affecting its wettability are the surface chemical composition and surface microstructure, accordin...

Claims

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Application Information

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IPC IPC(8): C25D1/08C25D3/30B05D5/08B01D17/022
Inventor 刘宇艳张恩爽吴松全吕通宫显云
Owner HARBIN INST OF TECH
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