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Phosphor-nitrogen fire-retardant polyethylene composite material and preparation method thereof

A composite material, phosphorus nitrogen flame retardant technology, applied in the field of polymer materials, can solve the problems of poor flame resistance, easy to burn and fire, and achieve the effects of good durability, excellent processing performance and simple preparation process

Inactive Publication Date: 2014-06-25
QINGDAO XINZHAN PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, polyethylene has the disadvantage of poor flame resistance. Sometimes the cables made of it are easy to burn and cause fires under high temperature, heat generation, discharge and other conditions.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A phosphorus-nitrogen flame-retardant polyethylene composite material, the components of which are: 65% polyethylene, 25% pentaerythritol polyphosphate melamine salt, 5% magnesium hydroxide, 2.5% anti-ultraviolet agent, polyethylene 1.5% wax, 0.5% aluminum-titanium composite coupling agent, 0.5% compound of hindered phenol antioxidant 1010 and phosphite antioxidant 168.

[0019] Preparation method: (1) weigh each component according to the weight ratio for use; (2) mix polyethylene, pentaerythritol polyphosphate melamine salt, magnesium hydroxide, anti-ultraviolet agent, polyethylene wax, aluminum-titanium composite couple The joint agent and the compound of hindered phenol antioxidant 1010 and phosphite antioxidant 168 are added to the high-speed mixer, and fully mixed for 10-30 minutes; (3) Add the above-mentioned mixed materials into the twin-screw extruder machine for melting and kneading, and then extrusion, cooling, granulation, and drying to obtain a phosphorus-n...

Embodiment 2

[0021] A phosphorus-nitrogen flame-retardant polyethylene composite material, the components of which are proportioned by mass percentage: polyethylene 60%, pentaerythritol phosphate melamine salt (PPM) and pentaerythritol phosphate (PEPA) compound flame retardant 30%, Zinc borate 6%, hindered amine light stabilizer 2%, ethylene bis stearamide (EBS) 1.2%, aluminum-titanium composite coupling agent 0.3%, hindered phenol antioxidant 1010 and phosphite antioxidant 168 Compound 0.5%.

[0022] Preparation method: (1) weigh each component according to the weight ratio for use; (2) mix polyethylene, pentaerythritol phosphate melamine salt (PPM) and pentaerythritol phosphate (PEPA) compound flame retardant, zinc borate , hindered amine light stabilizer, ethylene bisstearamide (EBS), aluminum-titanium composite coupling agent, hindered phenol antioxidant 1010 and phosphite antioxidant 168 are added to the high-speed mixer, fully Mix for 10 to 30 minutes; (3) Add the above-mentioned mi...

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PUM

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Abstract

The invention discloses a phosphor-nitrogen fire-retardant polyethylene composite material and a preparation method thereof. The material is composed of the following components in percentage by weight: 50% to 80% of polyethylene, 15% to 30% of phosphor-nitrogen fire retardant, 3% to 8% of fire retardant synergist, 1% to 3% of stabilizing agent, 0.5% to 2% of dispersant, 0.1% to 1% of coupling agent, and 0.1% to 1% of antioxidant. The polyethylene composite material is enhanced by adding a phosphor-nitrogen fire retardant, has a good fire retardant performance, reaches a UL94-0 fire-retardant grade, and has the advantages of little smoke, no toxicity, good durability, high thermal stability, and excellent processing property. Moreover the preparation method of the phosphor-nitrogen fire-retardant polyethylene composite material has the advantages of simpleness, practicability, and convenient operation.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a phosphorus-nitrogen flame-retardant polyethylene composite material and a preparation method thereof. Background technique [0002] Polyethylene is a light, non-toxic, thermoplastic material with excellent electrical insulation and chemical corrosion resistance. It is cheap and easy to form and process. It is widely used in electrical appliances, chemicals, food, machinery and other industries, among which it is used in wires Especially in the cable industry. At the same time, polyethylene has the disadvantage of poor flame resistance, and the cables made of it are sometimes easy to burn and cause fires under high temperature, heat generation, discharge and other conditions. Therefore, the flame retardant problem of polyethylene has gradually been paid attention to. In recent years, the call for environmental protection has been increasing. While using flame retarda...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08L85/02C08K13/02C08K5/521
CPCC08L23/06C08K3/38C08K5/34928C08K5/521C08K13/02C08L2201/02C08L2201/22C08L2205/025
Inventor 不公告发明人
Owner QINGDAO XINZHAN PLASTIC
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