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Preparation method of light calcium-alginate-base sponge body functional material

A calcium alginate-based sponge and functional material technology, which is applied in the preparation of sponge functional materials, can solve the problems of small processing capacity, poor moisture absorption and moisturizing performance, low efficiency, etc., and save spinning equipment and non-woven equipment , increase flexibility and elasticity, and reduce production costs

Active Publication Date: 2014-07-23
QINGDAO UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It not only requires expensive equipment and consumes a lot of energy, but also has a small amount of treatment at one time, making it difficult to produce on an industrial scale
[0008] On the other hand, calcium alginate fibers are made through processes such as sodium alginate dissolution, defoaming, wet spinning, calcium chloride solution solidification, dehydration, and hot drawing, and are cut into short fibers and then made with non-woven equipment. Non-woven fabrics, not only expensive equipment, large sewage discharge, huge ethanol consumption, many process steps, low efficiency, and although the fiber itself solves the problem of mechanical strength, because the fiber is non-porous, it is not a light-weight material and absorbs moisture. The defect of poor performance has not been overcome, and it is difficult to meet the requirements in terms of liquid absorption rate for medical accessories, and the price is very expensive, so the application is still greatly restricted

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Put sodium alginate powder, anhydrous calcium chloride, anhydrous magnesium chloride, sodium carboxymethyl cellulose, sodium percarbonate, and manganese dioxide in a V-shaped Rotate and blend evenly in a blender, then use 80% ethanol aqueous solution to form a paste in a fully automatic dough kneader, roll the film, and react in a wet state for 60 minutes. After coagulation, wash with 55% ethanol solution containing 0.01% EDTA until there is no magnesium ion and chloride ion to obtain a light calcium alginate-based sponge membrane.

Embodiment 2

[0030] Put sodium alginate powder, anhydrous calcium chloride, aluminum trichloride, cellulose sodium salt, sodium peroxoborate, and manganese dioxide in a V-shape with a weight ratio of 60:15:10:10:14.8:0.2. Rotate and blend evenly in the mixer, and then use 95% ethanol aqueous solution to form a paste in a fully automatic dough kneader, roll the film, and react in a wet state for 50 minutes. After coagulation, wash with 60% ethanol solution containing 0.05% EDTA until there is no aluminum ion and chloride ion to obtain a light calcium alginate-based sponge membrane.

Embodiment 3

[0032] Put sodium alginate powder, calcium chloride dihydrate, magnesium sulfate heptahydrate, hydroxyethyl cellulose, calcium peroxide, and manganese dioxide in a V-shape with a weight ratio of 51.5:13:12.5:17.5:5:0.5 Rotate and blend evenly in the mixer, and then use 90% ethanol aqueous solution to form a paste in a fully automatic dough kneader, then roll the film, and react for 50 minutes in a wet state. After coagulation, wash with 65% ethanol solution containing 0.3% EDTA until there is no magnesium ion and chloride ion to obtain a light calcium alginate-based sponge membrane.

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PUM

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Abstract

The invention discloses a preparation method of a light calcium-alginate-base sponge body functional material. The preparation method comprises the following steps: in room temperature, evenly mixing sodium alginate powder with soluble calcium salt, magnesium salt or aluminum salt, a reinforcing agent, peroxide and a catalyst to obtain a mixture; moistening with an alcohol-water solution to form paste; rolling by molding equipment to form a film material or a plate material; and then sequentially performing infiltration, complexation for pore formation, and expansion for pore formation. The preparation method has the characteristics of simple technology, low control difficulty, low equipment investment, energy-saving effect, low production cost and the like and is applicable to large-scaled industrial production; the prepared light calcium-alginate-base sponge body functional material is the same in structure and composition regardless of interior or exterior, good in quality, light in weight, high in mechanical strength, and excellent in imbibition performance and air permeability, and can be widely applicable to the fields of antibacterial materials, flame-resistant materials, adsorbing materials, acoustic materials, vibration-absorptive materials and the like; the market prospect is extensive.

Description

technical field [0001] The invention relates to a preparation method of a sponge functional material, in particular to a preparation method of a light calcium alginate-based sponge functional material. Background technique [0002] Seaweed is one of the largest renewable resources in the ocean. In terms of kelp alone, the annual regeneration capacity exceeds 15 million tons. my country's total seaweed production in 2012 was more than 1.2 million tons. Among them, the output of kelp exceeds 1 million tons, accounting for more than 90% of the world's total output. It is the country with the largest amount of kelp cultured in the world and has a huge resource advantage. [0003] But at present, the utilization of kelp is mainly used directly as food or to extract food additives, and the price per ton ranges from 4,000 yuan to tens of thousands of yuan, and the added value is low. How to use the advantages of kelp resources to transform into high value-added industrial advant...

Claims

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Application Information

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IPC IPC(8): C08J9/26C08J9/06C08J3/24C08L5/04
Inventor 李群李子超王艳玮李晓雯赵昔慧王剑平刘倩倩
Owner QINGDAO UNIV
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