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A kind of preparation method of strontium aluminate long afterglow luminescent material

A technology of luminescent materials and strontium length, applied in luminescent materials, chemical instruments and methods, etc., can solve problems such as easy hydrolysis, coarse particles, poor compatibility, etc., achieve short production cycle, uniform particle size, and improve the effect of dispersion

Active Publication Date: 2015-10-07
SHUANGLE CHEM PIGMENT YANGZHOU CITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Purpose of the invention: The purpose of the invention is to address the deficiencies in the prior art and provide a method for preparing a strontium aluminate long-lasting luminescent material with lipophilicity and high specific surface area , to solve the problems of coarse particles, easy hydrolysis, and poor compatibility of strontium aluminate long-lasting luminescent powder in the application of ink, paint, and textile fields

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Example 1: A preparation method of strontium aluminate long afterglow luminescent material, comprising the following steps:

[0026] (1) Weigh 18g of aluminum nitrate nonahydrate and 5g of anhydrous strontium nitrate, dissolve them in 100 ml of distilled water, add 0.3g of boric acid, add 46g of urea as an expanding agent, and mix evenly.

[0027] (2) Weigh 0.05g of europium oxide and 0.05g of dysprosium oxide, add 0.1M nitric acid to the mixture to dissolve, pH=5-6, keep warm at 60-80°C until the mixture is completely dissolved.

[0028] (3) Mix the above two solutions and add 1.1g nano-TiO 2 , aged at 60-80°C for 10 min.

[0029] (4) Put the mixed solution into a crucible and put it in a muffle furnace at 400°C. Raise the temperature from 400°C to 600°C at a heating rate of 5°C / min, hold for 20 minutes, then raise the temperature to 900°C at a heating rate of 10°C / min, and hold for 20 minutes. Cool down to room temperature and sample. That is, the strontium alumi...

Embodiment 2

[0031] Example 2: A preparation method of strontium aluminate long afterglow luminescent material, comprising the following steps:

[0032] (1) Weigh 18g of aluminum nitrate nonahydrate and 5g of anhydrous strontium nitrate, dissolve in 20 ml of distilled water, add 0.3g of boric acid, add 2.3g of oxalic acid as an expanding agent, and mix evenly.

[0033] (2) Weigh 0.05g of europium oxide and 0.05g of dysprosium oxide, add 0.1M nitric acid to the mixture to dissolve, pH=5-6, keep warm at 60-80°C until the mixture is completely dissolved.

[0034] (3) Mix the above two solutions and add 0.05g nano-SiO 2 , aged at 60-80°C for 5h.

[0035] (4) Put the mixed solution into a crucible and put it in a muffle furnace at 350°C. Raise the temperature from 350°C to 600°C at a heating rate of 5°C / min, hold for 20 minutes, then raise the temperature to 1500°C at a heating rate of 10°C / min, and hold for 3 hours. Cool down to room temperature and sample. That is, the strontium alumina...

Embodiment 3

[0037] Example 3: A preparation method of strontium aluminate long afterglow luminescent material, comprising the following steps:

[0038] (1) Weigh 18g of aluminum nitrate nonahydrate and 5g of anhydrous strontium nitrate, dissolve in 100ml of distilled water, add 0.3g of boric acid, add 10g of oxalic acid and 10g of citric acid as swelling agents, and mix evenly.

[0039] (2) Weigh 0.05g of europium oxide and 0.05g of dysprosium oxide, add 0.1M nitric acid to the mixture to dissolve, pH=5-6, keep warm at 60-80°C.

[0040] (3) Mix the above two solutions and add 0.2g nano-SiO 2 and 0.6g nano-TiO 2 , aged at 60-80°C for 2h.

[0041] (4) Put the mixed solution into a crucible and put it into a muffle furnace at 450°C. Raise the temperature from 450°C to 500°C at a heating rate of 5°C / min, hold for 20 minutes, then raise the temperature to 1500°C at a heating rate of 10°C / min, and hold for 1 hour. Cool down to room temperature and sample. That is, the strontium aluminate l...

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Abstract

The invention discloses a method for preparing a strontium aluminate long-lasting phosphor material. The method includes the following steps that (1) aluminum nitrate and nitrate or carbonate of strontium are dissolved with distilled water to obtain a solution, and boric acid and swelling agents are added into the solution; (2) nitric acid is added into a mixture of europium oxide and dysprosium oxide; (3) the two solutions prepared in the step (1) and the step (2) are mixed, surface modifiers are added, and then the solution stands still for 10 minutes to 5 hours; (4) the mixed solution obtained in the step (3) is poured into a crucible, the crucible is placed into a muffle furnace at the temperature of 350-450 DEG C, the temperature is raised to 500-600 DEG C, the temperature rising rate is 5 DEG C per minute, the temperature remains for 20 minutes, then the temperature is raised to 900-1500 DEG C, the temperature rising rate is 10-20 DEG C per minute, and the temperature remains for 20 minutes to 3 hours. The method solves the problem of hard agglomeration occurring in a traditional sintering method, due to the fact that the appearance of a light-emitting material synthesized through swelling agents is foam-shaped loose body, the light-emitting material can be easily ground fine, and light-emitting brightness of products is not influenced.

Description

technical field [0001] The invention relates to a preparation method of a strontium aluminate long afterglow luminescent material. Background technique [0002] Rare earth ion activated strontium aluminate (SrAl 2 o 4 :Eu 2+ , Dy 3+ ) system energy storage luminescent materials have the advantages of high luminous brightness, long afterglow time, and no radioactive elements, and are widely used in construction, ships, aviation instruments, paint industry, ink, glaze, plastics and other fields. At present, the preparation of strontium aluminate luminescent materials mainly includes high-temperature solid-state sintering method, co-precipitation method, sol-gel method and combustion method. For example, Chinese technical invention patents CN 1188788, CN 1445330 A, CN 1699506 A, CN 1403533A, etc. disclose the use of solid-state method for high-temperature sintering to obtain luminescent materials. Chinese technical invention patents CN1389541A and CN1563171A report the pro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K11/64
Inventor 葛扣根江国祥陈军陈爱英
Owner SHUANGLE CHEM PIGMENT YANGZHOU CITY