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A kind of solar energy selective absorption coating with high temperature resistance and salt spray resistance in the atmosphere and preparation method thereof

An absorbing coating and high temperature resistant technology, applied in solar thermal power generation, coatings, solar thermal devices, etc., can solve problems such as low deposition rate, unstable microstructure and physical properties, complex process, etc.

Active Publication Date: 2017-03-22
北京天瑞星光热技术有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the microstructure and physical properties of cermet structural coatings are unstable at high temperatures due to the large number of metal atoms.
Moreover, the deposition rate of processes such as radio frequency sputtering is low, the production cycle is long, the process is complicated, and the cost is high

Method used

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  • A kind of solar energy selective absorption coating with high temperature resistance and salt spray resistance in the atmosphere and preparation method thereof
  • A kind of solar energy selective absorption coating with high temperature resistance and salt spray resistance in the atmosphere and preparation method thereof
  • A kind of solar energy selective absorption coating with high temperature resistance and salt spray resistance in the atmosphere and preparation method thereof

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Experimental program
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preparation example Construction

[0073] The invention provides a method for preparing a high-temperature-resistant, salt-spray-resistant solar energy selective absorption coating in the atmosphere, such as figure 2 shown, including the following steps:

[0074] Step 1: preparing a first diffusion barrier layer on the substrate;

[0075] The pure metal target intermediate frequency magnetron sputtering method is adopted. The pure metal target is Al target, Ti target, Si target or Cr target, and Ar gas is used as the sputtering gas. The substrate is made of stainless steel, and the vacuum chamber is pre-pumped before sputtering. Vacuum to 4×10 -3 ~5×10 - 3 Pa, through the inert gas Ar and O 2 as sputtering atmosphere, or Ar and N 2 As the sputtering atmosphere, the Ar gas flow rate is 100-140 sccm, the oxygen flow rate is 20-45 sccm, if nitrogen gas is used, the flow rate is 8-20 sccm, the sputtering distance is adjusted to 130-150 mm, and the sputtering pressure is adjusted to 3×10 -1 ~4×10 -1 Pa, turn...

Embodiment 1

[0109] This embodiment provides a SiO 2 and TiO 2 Atmospheric high temperature resistant, salt spray resistant solar selective absorption coating of the structure, the coating includes six coatings, divided into the first layer of diffusion barrier layer, the second layer of infrared emission layer, the third layer of diffusion barrier layer, the fourth layer of Layer absorption layer, fifth layer of anti-reflection layer, sixth layer of organic protective layer.

[0110] The first layer of TiO 2 The thickness of the film is 50nm, the total thickness of the second Cu film is 150nm, and the third layer of TiO 2 The film is 50nm, the fourth layer of SiO 2 +TiO 2 The film is 140nm, where the first sublayer SiO 2 +TiO 2 The film thickness is 80nm, the second sublayer SiO 2 +TiO 2 The film thickness is 60nm, the SiO in the first sublayer 2 The volume percentage is 40%, the rest is TiO 2 ; second sublayer SiO 2 The volume percentage is 60%, the rest is TiO 2 ; the fifth ...

Embodiment 2

[0129] This embodiment provides a Si 3 N 4 and Ni 3 N 2 Structured atmospheric high temperature resistant, salt spray resistant solar selective absorption coating, divided into the first layer of diffusion barrier layer, the second layer of infrared emission layer, the third layer of diffusion barrier layer, the fourth layer of absorption layer, the fifth layer of anti-reflection layer, the sixth organic protective layer.

[0130] The first layer is Si 3 N 4 film, the thickness is 60nm, the second layer is Cu film, the thickness is 180nm, and the third layer is Si 3 N 4 film, the thickness is 60nm, the total thickness of the fourth layer is 160nm, wherein the thickness of the first sublayer is 100nm, the thickness of the second sublayer is 60nm, and the Si in the first sublayer 3 N 4 The volume percentage is 40%, the rest is Ni 3 N 2 ; the second sublayer Si 3 N 4 The volume percentage is 60%, the rest is Ni 3 N 2 ; The fifth layer is SiO 2 film with a thickness...

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Abstract

The invention discloses a high temperature and salt spray resistance solar energy selective absorbing coating in atmosphere and a preparation method of the coating. The high temperature and salt spray resistance solar energy selective absorbing coating comprises six membrane layers which are a first diffusion barrier layer, a second infrared emission layer, a third diffusion barrier layer, a fourth absorbing layer, a fifth antireflection layer and a sixth organic protective layer in sequence from the bottom layer to the surface, wherein the first diffusion barrier layer is a nitride or oxide membrane layer, the second infrared emission layer is Cu, Ag, Al, Ti or Au, the third diffusion barrier layer is a nitride or oxide membrane layer, the fourth absorbing layer comprises two sub-layer structures, the two sub-layers are double ceramic membranes, the fifth antireflection layer is an Al2O3 membrane or an SiO2 membrane, and the sixth layer is the organic protective layer. As the high temperature and salt spray resistance solar energy selective absorbing coating comprises the organic protective layer, the high temperature and atmosphere corrosion resistance of the high temperature and salt spray resistance solar energy selective absorbing coating are greatly improved, so that the high temperature selective absorbing coating with the novel structure has good high temperature thermal stability and weather fastness.

Description

technical field [0001] The invention belongs to the technical field of solar energy utilization and coating preparation, and in particular relates to a high temperature resistant and salt fog resistant solar selective absorption coating in the atmosphere and a preparation method thereof. Background technique [0002] The solar spectrum selective absorption coating has a high absorption rate in the visible-near-infrared band and a functional film with a low emissivity in the infrared band, which is the key to improving the efficiency of light-to-heat conversion for solar collectors. With the continuous development of solar heat utilization requirements and technology, the application range of solar collector tubes has been developed from low temperature applications (≤100°C) to medium temperature applications (100°C-350°C) and high temperature applications (350°C-500°C). Meet the requirements of medium and high temperature applications such as seawater desalination and solar ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C14/35C23C14/06B32B9/04B32B15/04F24J2/48
CPCF24S70/225F24S70/30Y02E10/40
Inventor 刘雪莲张秀廷陈步亮崔孟龙曹明刚席晓敏
Owner 北京天瑞星光热技术有限公司