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Method for comprehensively using aluminum-containing resource

A resource and alumina technology, applied in the field of comprehensive utilization of resources, can solve the problems that the production cost of alumina is greatly affected, and it is not suitable for processing low-grade bauxite aluminum resources, so as to achieve the effect of low energy consumption

Active Publication Date: 2014-09-10
SHENYANG POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because the ore grade (ore aluminum-silicon ratio) has a great influence on the current alumina production cost, the existing methods are not suitable for processing low-grade bauxite or aluminum resources

Method used

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  • Method for comprehensively using aluminum-containing resource
  • Method for comprehensively using aluminum-containing resource
  • Method for comprehensively using aluminum-containing resource

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Ammonium sulfate is heated to 300°C for decomposition to produce ammonium bisulfate and ammonia gas, and the ammonia gas is absorbed by water to produce ammonia water. Grind 1000kg of gibbsite-type bauxite and mix it with the above-mentioned ammonium bisulfate, add water, heat to 90°C for reaction, the reaction time is 60min, ammonium bisulfate and alumina in gibbsite-type bauxite And the molar ratio of iron oxide is 7. After the reaction is cooled down, solid-liquid separation and washing are carried out to obtain a solution of aluminum ions and iron ions, excess ammonium bisulfate solution and high-silicon slag, so as to realize the separation of aluminum, iron and silicon; add the ammonia water prepared by the above ammonia gas recovery to the obtained solution to obtain Aluminum hydroxide and ferric hydroxide are precipitated and ammonium sulfate solution, followed by solid-liquid separation and washing; ammonium sulfate solution is evaporated and crystallized, and ...

Embodiment 2

[0042] Ammonium sulfate is heated to 200°C for decomposition to produce ammonium bisulfate and ammonia gas, and the ammonia gas is absorbed by water to make ammonia water. Grind 1000kg boehmite-type bauxite and mix it with the above-mentioned ammonium bisulfate, add water, heat to 145°C for reaction, the reaction time is 90min, ammonium bisulfate and boehmite-type bauxite The molar ratio of alumina and iron oxide was 12. After the reaction is cooled down, solid-liquid separation and washing are carried out to obtain a solution of aluminum ions and iron ions, excess ammonium bisulfate solution and high-silicon slag, so as to realize the separation of aluminum, iron and silicon; add the ammonia water prepared by the above ammonia gas recovery to the obtained solution to obtain Aluminum hydroxide and ferric hydroxide are precipitated and ammonium sulfate solution, followed by solid-liquid separation and washing; ammonium sulfate solution is evaporated and crystallized, and the ob...

Embodiment 3

[0044]Ammonium sulfate is heated to 400°C for decomposition to produce ammonium bisulfate and ammonia gas, and the ammonia gas is absorbed with water to make ammonia water. Grind 1000kg of high-alumina fly ash and mix it with the above-mentioned ammonium bisulfate, add water, heat to 280°C for reaction, the reaction time is 30min, the molar ratio of ammonium bisulfate to alumina and iron oxide in high-alumina fly ash for 18. After the reaction is cooled down, solid-liquid separation and washing are carried out to obtain a solution of aluminum ions and iron ions, excess ammonium bisulfate solution and high-silicon slag, so as to realize the separation of aluminum, iron and silicon; add the ammonia water prepared by the above ammonia gas recovery to the obtained solution to obtain Aluminum hydroxide and ferric hydroxide are precipitated and ammonium sulfate solution, followed by solid-liquid separation and washing; ammonium sulfate solution is evaporated and crystallized, and th...

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Abstract

The invention belongs to a resource comprehensive using method, and especially relates to a method for comprehensively using aluminum-containing resource. The method comprises the following steps: 1)heating ammonium sulfate and decomposing to generate ammonium bisulfate and ammonia gas; 2)mixing the aluminium-containing resource and ammonium bisulfate in the step 1), adding water or a washing lotion; 3)cooling a reaction product and performing solid-liquid separation, washing to obtain a solution of aluminium ions and iron ions and an excessive ammonium bisulfate solution and high silicon slag; 4)adding ammoniacal liquor or ammonia gas in the solution of the step 3) to obtain aluminium hydroxide and iron hydroxide sediment and an ammonium sulfate solution, then performing solid-liquid separation, and washing; 5)performing evaporative crystallization on ammonium sulfate solution obtained in the step 4), and separating to obtain an ammonium sulfate solid; and 6)processing the aluminium hydroxide and iron hydroxide solid obtained in the step 4) to obtain metallurgy grade alumina and high iron slag. The method has the advantages of low energy consumption, high leaching rate of alumina and iron, high enrichment degree of active ingredients and low production cost.

Description

technical field [0001] The invention belongs to a method for comprehensive utilization of resources, in particular to a method for comprehensive utilization of aluminum-containing resources. Background technique [0002] Over the years, with the rapid development of the national economy, my country's aluminum industry has achieved unprecedented development. Alumina, as a raw material for electrolytic aluminum, has also developed rapidly. It has become the world's largest producer of alumina. At present, my country's alumina enterprises have reached 40 There are a number of companies with a production capacity of more than 50.5 million tons / year under construction and 37 million tons / year of processing domestic bauxite. In 2012, the national alumina output was 37.696 million tons, making it the world's largest alumina producer. However, my country is a country with relatively poor bauxite resources. At present, my country's identified and inferred bauxite resource reserves ha...

Claims

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Application Information

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IPC IPC(8): C01F7/02C01F7/26C01G49/06C01B33/113
Inventor 吴玉胜李来时
Owner SHENYANG POLYTECHNIC UNIV
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