Early-strength composite foam concrete foaming agent and preparation method thereof

A composite foam and composite foaming technology, applied in the field of building materials, can solve the problems of short shelf life, shrinkage and sinking, complex preparation process, etc., and achieve the effects of excellent foam stability, rapid early strength improvement, and simple preparation process.

Active Publication Date: 2014-12-03
中建商品混凝土(福建)有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The advantage of rosin soap foaming agent is that it is cheap and easy to get, but because of its poor stability, it is not suitable for production of 700kg / m 3 Low-density products below grade, such as Chinese patent CN200610034912.6 "Polymer Foam Concrete Cement Foaming Agent" is a kind of foaming agent prepared with rosin soap foaming agent as raw material. Large bleeding and poor foam stability
Protein-based foaming agents have good foamability and foam stability, but due to high requirements for synthesis technology, it has been difficult to achieve the quality of foreign products in China, and the shelf life is short and the cost is high
The advantage of synthetic surfactant foaming agent is that foaming multiple is big, easy foaming, but its weak point is that bubble diameter is big, and bubble wall is thin, and defoaming is fast, and stability is not good, as Chinese patent CN101798200A " a kind of Nonionic Concrete Foaming Agent and Its Preparation Method” discloses a surfactant-based foaming agent, but the foaming agent has high requirements on raw materials, and the preparation process is relatively complicated. It needs to be invested in a special reaction generator, and its preparation The foaming agent has the common disadvantages of surface active foaming agents
Therefore, in recent years, the blowing agent has developed into a high-performance composite blowing agent. Through multi-component compounding, the advantages of each component are fully utilized, complementary advantages or synergistic effects are achieved, and new functions are added. For example, Chinese patent CN102964081A "a kind of Composite animal and vegetable protein foaming agent》A composite foaming agent was prepared by using protein foaming agent and synthetic surfactant foaming agent, its foaming performance and foam stabilizing performance are improved compared with ordinary single foaming agent , but its function is single. When preparing foam concrete, especially low-density foam concrete, it is easy to shrink, sink, collapse, and deform.

Method used

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  • Early-strength composite foam concrete foaming agent and preparation method thereof
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  • Early-strength composite foam concrete foaming agent and preparation method thereof

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Effect test

Embodiment 1

[0023] An early-strength composite foam concrete foaming agent is composed of a composite foam component, a foam-stabilizing component, an early-strength component and water, and the distribution ratio of each component is calculated by mass percentage: composite foam component: 12 Sodium Alkyl Sulfate 15.0%, Sodium Cetyl Sulfonate 15.8%, Tea Saponin 9.2%; Foam Stabilizing Component: Lauryl Alcohol 4.0%, Cellulose Ether 1.0%; Early Strength Component: Triethanolamine 2.0%, Sodium sulfate 8.0%; water 45.0%.

[0024] A method for preparing an early-strength type composite foam concrete foaming agent, comprising the following steps: ①The container is placed in a constant temperature water bath at 100°C; ②The composite foaming component, the early-strength component and water are placed in the container; ③ Stir slowly at 60rpm for 1-5min to make it evenly mixed; ④ Add foam stabilizing components and continue stirring for 1-5min; ⑤ Cool to room temperature to obtain early-strength ...

Embodiment 2

[0029] An early-strength composite foam concrete foaming agent is composed of a composite foam component, a foam-stabilizing component, an early-strength component and water, and the distribution ratio of each component is calculated by mass percentage: composite foam component: 12 Sodium Alkyl Sulfate 20.0%, Cocamidopropyl Betaine 40.0%, Tea Saponin 10.0%, Saponin 7.0%; Foam Stabilizing Components: Lauryl Alcohol 4.0%, Cellulose Ether 1.0%; Early Strength Components : Triethanolamine 0.5%, sodium sulfate 7.5%; water 10%.

[0030] A method for preparing an early-strength composite foam concrete foaming agent, comprising the following steps: ①The container is placed in a constant temperature water bath at 70°C; ②The composite foaming component, the early-strength component and water are placed in the container; ③ Stir slowly at 300rpm for 1-5min to make it evenly mixed; ④ Add foam stabilizing components and continue stirring for 1-5min; ⑤ Cool to room temperature to obtain earl...

Embodiment 3

[0035] An early-strength composite foam concrete foaming agent is composed of a composite foam component, a foam-stabilizing component, an early-strength component and water, and the distribution ratio of each component is calculated by mass percentage: composite foam component: 12 Sodium Alkyl Sulfate 18.0%, Sodium Fatty Alcohol Polyoxyethylene Ether Sulfate 18.0%, Cocamidopropyl Betaine 36.0%, Tea Saponin 8.0%; Foam Stabilizing Component: Lauryl Alcohol 1.0%; Early Strength Component: Triethanolamine 1.0%, sodium sulfate 4.0%; water 14.0%.

[0036] A method for preparing an early-strength composite foam concrete foaming agent, comprising the following steps: ①The container is placed in a constant temperature water bath at 70°C; ②The composite foaming component, the early-strength component and water are placed in the container; ③ Stir slowly at 200rpm for 1-5min to make it evenly mixed; ④ Add foam stabilizing components and continue stirring for 1-5min; ⑤ Cool to room temper...

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Abstract

The invention belongs to the technical field of building materials, and particularly relates to an early-strength composite foam concrete foaming agent and a preparation method thereof. The early-strength composite foam concrete foaming agent comprises the following components in percentage by mass: 40%-80% of composite foaming components, 1.0%-5.0% of foam stabilizing components, 3.3%-22% of early-strength components and 10%-45% of water, wherein the composite foaming components are formed by compounding synthesized surface active agent foaming agents and protein foaming agents. The early-strength composite foam concrete foaming agent prepared through the method disclosed by the invention has the advantages of high foam expansion, excellent foam stability and good compatibility with general cement pastes; the early-strength composite foam concrete foaming agent disclosed by the invention is applied to foam concrete; the prepared foam concrete has no recess phenomenon and is fast enhanced in early strength, and the foam concrete with a density grade equal to 300 kg / m<3> or above is more easily prepared.

Description

technical field [0001] The invention belongs to the technical field of building materials, and in particular relates to an early-strength composite foam concrete foaming agent and a preparation method thereof. Background technique [0002] Foaming agent refers to a kind of substance that can make its aqueous solution produce a large amount of foam when mechanical force is introduced into the air. Its essence is its surface activity. Without surface activity, it cannot foam, and it cannot become Foaming agent, surface activity is the core of foaming. At present, there are many types of foaming agents used in foamed concrete, mainly rosin soaps, synthetic surfactants, and proteins. The advantage of rosin soap foaming agent is that it is cheap and easy to get, but because of its poor stability, it is not suitable for production of 700kg / m 3 Low-density products below grade, such as Chinese patent CN200610034912.6 "Polymer Foam Concrete Cement Foaming Agent" is a kind of foami...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B38/02C04B24/38C04B24/26C04B24/32
Inventor 季锡贤张恒春邹开波刘士红刘中心林熙殷新博赵柳
Owner 中建商品混凝土(福建)有限公司
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