Phenol aldehyde resin and preparation method thereof, and automobile filter paper

A technology of phenolic resin and phenolic compound, which is applied in the field of resin, can solve the problems of poor electrical conductivity, etc., and achieve the effects of good electrical conductivity, good burst resistance and stiffness

Active Publication Date: 2014-12-03
JINAN SHENGQUAN GROUP SHARE HLDG
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This graphene phenolic resin conductive composite material provided by the prior art is to add graphite oxide in the process of preparing phenolic resin, and introduce it into ...

Method used

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  • Phenol aldehyde resin and preparation method thereof, and automobile filter paper

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preparation example Construction

[0038] In the present invention, the particle size of the graphene is preferably 0.335 nm to 33.5 nm, more preferably 1 nm to 10 nm. In the present invention, the preparation method of described graphene preferably comprises the following steps:

[0039] 1), under the action of a catalyst, the biomass carbon source is subjected to catalytic treatment to obtain a first intermediate product, and the catalyst includes one or more of manganese chloride salts, iron compounds, cobalt compounds and nickel compounds Several;

[0040] 2) In the presence of a protective gas, the first intermediate product is heated from a first temperature to a second temperature and then kept warm to obtain a second intermediate product. The first temperature is 20°C to 40°C, and the The second temperature is 300°C-400°C;

[0041] 3) In the presence of a protective gas, heating the second intermediate product from the second temperature to a third temperature and then keeping it warm to obtain a thir...

Embodiment 1

[0086] At 90° C., hydrolyzing corncobs in sulfuric acid for 10 minutes to obtain lignocellulose, the mass of the sulfuric acid being 3% of the mass of the corncobs;

[0087] At 70°C, the lignocellulose was subjected to acidic sulfite treatment for 1 hour to obtain porous cellulose, the pH value in the acidic sulfite treatment process was 1, the acid was sulfuric acid, and sulfite It is magnesium sulfite, the quality of the sulfuric acid is 4% of the quality of the lignocellulose, and the liquid-solid ratio is 2:1.

[0088] The obtained porous cellulose is bleached with hydrogen peroxide, the mass of the hydrogen peroxide is 5% of the mass of the porous cellulose, the bleaching temperature of the hydrogen peroxide bleaching is 100° C., and the bleaching time is 5 hours.

[0089] Stir the porous cellulose and manganese chloride at 20°C for 2 hours for catalytic treatment, the mass ratio of the manganese chloride and porous cellulose is 0.01:1; Drying at a low temperature to obt...

Embodiment 2

[0093] At 180°C, hydrolyzing corncobs in nitric acid for 10 hours to obtain lignocellulose, the mass of the nitric acid being 20% ​​of the mass of the corncobs;

[0094] At 180°C, the lignocellulose was subjected to acidic sulfite treatment for 6 hours to obtain porous cellulose, the pH value during the acidic sulfite treatment process was 7, the acid was sulfuric acid, and sulfite It is sodium sulfite, the quality of the sulfuric acid is 30% of the quality of the lignocellulose, and the liquid-solid ratio is 20:1.

[0095] The porous cellulose is bleached with hydrogen peroxide, the mass of the hydrogen peroxide is 5% of the mass of the porous cellulose, the bleaching temperature of the hydrogen peroxide bleach is 100° C., and the bleaching time is 5 hours.

[0096] Stir the porous cellulose and ferric nitrate at 180°C for 10 hours for catalytic treatment, the mass ratio of ferric nitrate and porous cellulose is 2:1; dry the obtained catalytically treated product at 120°C , ...

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Abstract

The invention provides a phenol aldehyde resin which is prepared by reacting phenol compounds, aldehyde compounds and graphene, wherein the mole ratio of the phenol compounds to the aldehyde compounds is 1:(1.0-2.5), and the mass ratio of the graphene to the phenol compounds is (0.01-2):100. The invention provides a preparation method of the phenol aldehyde resin, which comprises the following steps: carrying out first reaction on the phenol compounds, an alkaline catalyst, the aldehyde compounds and the graphene to obtain a reaction product, wherein the temperature of the first reaction is 60-90 DEG C; and carrying out second reaction on the reaction product and alcohol compounds to obtain the phenol aldehyde resin. The invention also provides an automobile filter paper prepared from the phenol aldehyde resin in the technical scheme, or prepared from the phenol aldehyde resin prepared by the method in the technical scheme. The phenol aldehyde resin provided by the invention comprises graphene, and thus, has favorable electric conductivity.

Description

technical field [0001] The invention relates to the technical field of resins, in particular to a phenolic resin, a preparation method thereof, and an automobile filter paper. Background technique [0002] Automotive filter paper is the general term for air filter paper, oil filter paper and fuel filter paper. The main purpose of automotive filter paper is to filter the dust and impurities in the engine intake, oil and fuel, and reduce the wear and tear of dust and impurities on the key components of the engine. The automobile filter paper prepared by phenolic resin has good toughness and stiffness. Car filter paper is usually non-conductive, but during the fuel delivery process of the car, the high-speed and severe friction between the fuel and the delivery pipeline will generate a large amount of static electricity, which accumulates on the metal parts of the delivery pipeline, and local static electricity The accumulation of charge will form a large potential difference...

Claims

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Application Information

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IPC IPC(8): C08G8/10C08G8/22C08G8/20C08G8/08C08G8/04C08G8/06C08G8/12C08K3/04C01B31/04D21H27/08
Inventor 唐一林江成真张宝印隗骁健
Owner JINAN SHENGQUAN GROUP SHARE HLDG
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