Preparation method of novel fast-response high-contrast electrochromic device

A technology of electrochromic devices and electrochromic materials, which is applied in the direction of instruments, nonlinear optics, optics, etc., can solve the problem that homopolar color-changing materials cannot be made into pieces, achieve good market value, improve response time, and improve limitations Effect

Inactive Publication Date: 2014-12-17
HARBIN INST OF TECH
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  • Abstract
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Problems solved by technology

[0004] In order to solve the above-mentioned problem that the homopolar color-changing material cannot be formed into pieces, the present invention designs an electrochromic device with a new structure. The preparation method of the electrochromic device is: depositing the electrochromic material on two transparent electrodes respectively , place one of the transparent electrodes with a color-changing material on the bottom, scrape-coat the configured sol transparent electrolyte on it, place a double-sided conductive transparent electrode and lead out the wires on both sides, and again on the other side of the transparent electrode Scrape-coat the sol transparent electrolyte, and finally put another layer of transparent electrode deposited with electrochromic material on the top. The wires are connected in parallel as the negative pole, forming two parallel discoloration circuits

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  • Preparation method of novel fast-response high-contrast electrochromic device
  • Preparation method of novel fast-response high-contrast electrochromic device
  • Preparation method of novel fast-response high-contrast electrochromic device

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Embodiment Construction

[0010] In the embodiment of the present invention, the step of depositing the electrochromic material on the transparent electrode usually adopts an electrodeposition method. Electrochemical polymerization refers to the use of electrochemical methods to cause polymerization of polymerized monomers on the working electrode. Compared with materials prepared by traditional chemical polymerization, the method has the advantages of simple preparation process, smooth and flat film surface, and controllable film thickness.

[0011] In the embodiment of the present invention, the electrode may use metals and metal oxides, such as indium tin oxide alloy (ITO), fluorine-doped tin oxide (FTO), tin oxide (NESA), indium zinc oxide (IZO) , Silver oxide, vanadium oxide, molybdenum oxide, gold, silver, platinum, copper, indium and chromium; silicon materials such as polysilicon and amorphous silicon; and carbon materials such as carbon black, graphite, and glassy carbon. Considering the applica...

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Abstract

The invention relates to a preparation method of a novel electrochromic device. The method changes the conventional design mode of the electrochromic device (namely the device is required to simultaneously comprise different cathodochromic and anodic color-changing material layers). Only one color-changing material (or simultaneously cathode coloring or simultaneously anode coloring material) is used during preparation of the device, so that a homopolar coloring material adhered to a transparent substrate is connected to one side in parallel and is conducted with a middle layer to form two parallel current circuits; thus, the problem that the color-changing material cannot be used for preparing the device is solved, the contrast of the device is increased, the response is fast and the method has wide applicability.

Description

Technical field: [0001] The invention relates to a method for preparing a novel electrochromic device. Background technique: [0002] Electrochromic (EC) material means that under the action of an external electric field, the material undergoes a redox reaction. Due to the change of its microstructure, the optical properties of the material (including transmittance, emissivity, and absorptivity) are in ultraviolet, visible or The infrared band has the property of reversible change. Electrochromic materials are divided into organic and inorganic systems according to their composition. Common inorganic electrochromic materials are WO 3 , NiO, V 2 O 5 , MoO, TiO 2 And other transition metal oxides and their derivatives. Organic electrochromic materials include small organic molecules such as viologen and conductive polymers such as polythiophene, polyaniline, and polypyrrole. Inorganic electrochromic materials have good cycle stability and excellent contrast, but their energy con...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02F1/153
Inventor 李垚张航川曲慧颖赵九蓬
Owner HARBIN INST OF TECH
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