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Polyolefin barium sulfate transparent masterbatch and preparation method thereof

A technology of polyolefin barium sulfate and transparent masterbatch, which is applied in the field of masterbatch manufacturing combining inorganic powder and polymer material, can solve the problems of rising haze, change of color, and decline of mechanical properties of plastic products, and achieves the production process. Simple, easy to master, reduce the effect of agglomeration

Inactive Publication Date: 2014-12-24
HUBEI HENGXU NEW MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to provide a polyolefin fully transparent masterbatch and its preparation method. The polyolefin transparent masterbatch produced by this method solves the problems of the decline in mechanical properties and color change of plastic products after using the filled masterbatch, especially It is a problem that the light transmittance of the film product decreases, the haze increases, and the whitening phenomenon is serious.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Taking materials by quality: precipitated barium sulfate powder 75kg, linear low density polyethylene 15kg, ethylene-vinyl acetate copolymer 2kg, polyethylene wax 2kg, semi-refined paraffin wax 3kg, zinc stearate 0.5kg, stearic acid 0.5kg, aluminum Acid lipid coupling agent 2kg.

[0021] The purity of the precipitated barium sulfate powder is greater than 99%, and the fineness is greater than 2000 mesh. The linear low density polyethylene is LLDPE7042, and the ethylene-vinyl acetate copolymer is EVA14-2. Polyethylene wax is a synthetic wax with a molecular weight of 2500. The coupling agent is an aluminate coupling agent.

[0022] A preparation method of polyolefin transparent masterbatch, adopts the following steps:

[0023] a. Add the precipitated barium sulfate powder into the high-speed mixer and stir, the speed of the high-speed mixer is 800r / min, and heat to 110°C;

[0024] b. Add the coupling agent for coating in three times, that is, first divide the couplin...

Embodiment 2

[0030] Taking materials by quality: precipitated barium sulfate powder 80kg, linear low density polyethylene 10kg, ethylene-vinyl acetate copolymer 4kg, polyethylene wax 1kg, semi-refined paraffin wax 2kg, zinc stearate 1kg, stearic acid 1kg, aluminate Coupling agent 1kg.

[0031] The purity of the precipitated barium sulfate powder is greater than 99%, and the fineness is greater than 2000 mesh. The linear low density polyethylene is LLDPE7042, and the ethylene-vinyl acetate copolymer is EVA14-2. Polyethylene wax is a cracking wax with a molecular weight of 3500. The coupling agent is an aluminate coupling agent.

[0032] A preparation method of polyolefin transparent masterbatch, adopts the following steps:

[0033] a. Add the precipitated barium sulfate powder into the high-speed mixer and stir, the speed of the high-speed mixer is 800r / min, and heat to 110°C;

[0034] b. Add the coupling agent for coating in three times, that is, first divide the coupling agent into th...

Embodiment 3

[0040] Taking materials by quality: precipitated barium sulfate powder 80kg, linear low density polyethylene 10.5kg, ethylene-vinyl acetate copolymer 2.5kg, polyethylene wax 1.8kg, semi-refined paraffin wax 2kg, zinc stearate 1.2kg, stearic acid 1kg , Aluminate coupling agent 1kg.

[0041] The purity of the precipitated barium sulfate powder is greater than 99%, and the fineness is greater than 2000 mesh. The linear low density polyethylene is LLDPE7042, and the ethylene-vinyl acetate copolymer is EVA14-2. Polyethylene wax is a mixture of synthetic wax and pyrolysis wax with a molecular weight of 3500. The coupling agent is an aluminate coupling agent.

[0042] A preparation method of polyolefin transparent masterbatch, adopts the following steps:

[0043] a. Add the precipitated barium sulfate powder into the high-speed mixer and stir, the speed of the high-speed mixer is 800r / min, and heat to 110°C;

[0044] b. Add the coupling agent for coating three times, that is, div...

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Abstract

The invention relates to a polyolefin barium sulfate transparent masterbatch and a preparation method thereof. The polyolefin barium sulfate transparent masterbatch is composed of the following components including, by weight percentage, 75-85% of precipitated barium sulfate powder, 2-15% of linear low-density polyethylene, 2-5% of ethylene-vinyl acetate copolymer, 1-2.5% of polyethylene wax, 2-3% of semi-refined paraffin wax, 0.5-1.5% of zinc stearate, 0.5-1% of stearic acid and 1-2% of coupling agent. The preparation method of the polyolefin barium sulfate transparent masterbatch comprises the following steps of a, adding the precipitated barium sulfate powder into a high-speed rotary feeder for high-speed mixing; b, adding the coupling agent for three times for coating; c, continuing to heat the mixture; d, feeding the mixture into a crusher for cooling and cracking, and performing plastifying, granulation, hot cutting and air cooling on the crushed mixture inside a twin-screw extruder to obtain masterbatch particles. The polyolefin barium sulfate transparent masterbatch can maintain mechanical properties, color and transparency of polyolefin products and meanwhile substantially reduce the raw material cost.

Description

technical field [0001] The invention relates to a polyolefin transparent masterbatch and a preparation method thereof, and belongs to the technical field of masterbatch manufacturing in which inorganic powders and polymer materials are combined. Background technique [0002] The plastic products industry usually reduces the cost of raw materials by adding fillers. Generally, fillers will affect the mechanical properties, color and light transmittance of the product. The patent with the publication number CN102020786A discloses a new material specially used for transparent plastics, and its components include modified ultrafine precipitated barium sulfate, transparent powder, dispersing lubricant, coupling agent and carrier resin. Although adding transparent powder can enhance the transparency of the masterbatch to a certain extent, in the process of mixing transparent powder and modified ultrafine precipitated barium sulfate powder, the requirements for adding transparent po...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08K13/06C08K9/04C08K3/30C08K5/01C08K5/098C08K5/09C08J3/22
CPCC08L23/0815C08K2201/003C08L23/0853C08L2201/10C08L2205/035C08L23/06C08L91/06C08K13/06C08K9/10C08K2003/3045C08K5/098C08K5/09
Inventor 莫汉林陈文吴昊孙杨柳
Owner HUBEI HENGXU NEW MATERIAL TECH
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