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A high temperature resistant low ablation coating and its preparation method

A technology of high temperature resistance and coating, applied in the field of surface engineering, can solve the problems of high preparation cost, complicated process, difficult to widely apply coating system, etc., and achieve the effect of good effect and simple preparation process.

Active Publication Date: 2015-09-23
AEROSPACE RES INST OF MATERIAL & PROCESSING TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These preparation methods are either complicated in process and difficult to uniformly prepare on the surface of large and complex components, or require large-scale equipment and high preparation costs
Moreover, the above-mentioned non-ablative or low-ablative coating also has an important defect, that is, the high-temperature erosion resistance is poor, and high-temperature anti-ablation and anti-erosion cannot be realized at the same time, which also means that the coating system prepared by the above method is difficult to be widely used.

Method used

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  • A high temperature resistant low ablation coating and its preparation method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Firstly, the anti-oxidation transition layer was prepared by spraying 5wt% perhydrosilazane on the composite material substrate, and brushed 3 times with an interval of 10 minutes between 2 times.

[0030]Next, prepare the heat-absorbing low-ablative layer slurry, and its raw material ratio is: polysiloxazane 35wt%, zirconia fiber 25wt%, carbon fiber 5wt%, hafnium carbide 30wt%, phenolic resin ball 5wt%, adopt brush coating Process The coating was prepared with a coating thickness of 3 mm, and then cured at room temperature for 12 hours.

[0031] Finally, a low-ablation radiation heat dissipation surface layer slurry was prepared, the raw material ratio of which was: polysiloxazane 40wt%, hafnium carbide 60wt%, using a brushing process, the coating thickness was 0.5mm, and then cured at room temperature for 12 hours.

[0032] The high-temperature-resistant and low-ablation coating is ablated by plasma flame at 2000°C for 100s, and the maximum temperature of the carbon-c...

Embodiment 2

[0034] Firstly, the anti-oxidation transition layer was prepared by spraying 15wt% perhydrosilazane on the composite material substrate, and brushed for 3 times with an interval of 15 minutes between 2 times.

[0035] Next, prepare the heat-absorbing low-ablative layer slurry, its raw material ratio is: polysiloxazane 25wt%, zirconia fiber 35wt%, carbon fiber 8wt%, hafnium boride 30wt%, phenolic resin ball 2wt%, adopt spraying Process The coating was prepared with a coating thickness of 0.3 mm, and then cured at room temperature for 24 hours.

[0036] Finally, a low-ablation radiation heat dissipation surface layer slurry is prepared, the raw material ratio of which is: polysiloxazane 20wt%, hafnium boride 80wt%, spraying process, coating thickness 0.5mm, and then curing at room temperature for 24 hours.

[0037] The high-temperature-resistant and low-ablation coating is ablated by plasma flame at 2000°C for 100s, and the maximum temperature of the carbon-carbon substrate is 5...

Embodiment 3

[0039] Firstly, the anti-oxidation transition layer was prepared by spraying 25wt% perhydrosilazane on the composite material substrate, and brushed 3 times with an interval of 20 minutes between 2 times.

[0040] Secondly, prepare the heat-absorbing low-ablative layer slurry, the raw material ratio is: polysiloxazane 30wt%, zirconia fiber 25wt%, carbon fiber 5wt%, zirconium carbide 35wt%, phenolic resin ball 5wt%, using a spraying process The coating was prepared with a coating thickness of 2 mm, and then cured at room temperature for 18 hours.

[0041] Finally, a low-ablation radiation heat dissipation surface layer slurry was prepared. The raw material ratio was: polysiloxazane 30wt%, hafnium oxide 70wt%, spraying process, coating thickness 0.05mm, and then curing at room temperature for 18 hours.

[0042] The high-temperature-resistant and low-ablation coating is ablated by plasma flame at 2000°C for 100s, and the maximum temperature of the carbon-carbon substrate is 360°C...

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Abstract

The invention discloses a high-temperature resistant low-ablation coating. The high-temperature resistant low-ablation coating comprises an antioxidant transition bottom layer, a heat-absorption low-ablation intermediate layer and a low-ablation radiation heat dissipation surface layer from inside to outside, wherein the antioxidant transition bottom layer is a silicon oxide layer; the heat-absorption low-ablation intermediate layer comprises ceramic precursor resins, ceramic fibers, ceramic powder, carbon fibers and resin small balls; the low-ablation radiation heat dissipation surface layer comprises high-temperature resistant resin binders and high-temperature high-radiation fillers. A preparation method of the high-temperature resistant low-ablation coating comprises the following steps of: firstly, preparing perhydrosilazane solution; then brushing the perhydrosilazane solution on a substrate; keeping stand for 10-30 minutes after brushing once; finishing the preparation of the antioxidant transition bottom layer after the substrate is brushed for 1-3 times; preparing intermediate layer slurries and preparing the heat-absorption low-ablation intermediate layer on the surface-dried antioxidant transition layer by means of brushing or air spraying; finally, preparing outer-layer slurries, and finishing the preparation of the low-ablation radiation heat dissipation surface layer on the cured heat-absorption low-ablation intermediate layer by means of brushing or air spraying.

Description

technical field [0001] The invention belongs to the field of surface engineering and relates to a coating and a preparation process thereof. Background technique [0002] Composite materials are structural materials widely used in the aerospace field, with excellent properties such as low density, high specific strength, low thermal expansion coefficient, and thermal shock resistance. However, composite materials are prone to ablation problems at high temperatures, and with the increase of environmental heat flow, ablation problems become more prominent, and their mechanical properties will rapidly decay and lose their bearing capacity. Therefore, it is necessary to prepare a high-temperature-resistant and low-ablation coating on the surface of the composite material, use the coating to isolate heat flow and oxygen, and reduce the temperature of the composite material as much as possible, so as to slow down or prevent the ablation of the composite material and ensure its hig...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B5/14
CPCC04B41/009C04B41/522C04B35/83C04B41/5035C04B41/5025
Inventor 李俊峰卢鹉罗正平李颖曾一兵赵立波
Owner AEROSPACE RES INST OF MATERIAL & PROCESSING TECH