A kind of red mud curing agent and its application

A curing agent and red mud technology, applied in the direction of solid waste management, sustainable waste treatment, climate sustainability, etc., can solve the problems of high-grade energy consumption and low red mud utilization, and achieve increased strength performance indicators and engineering Ease of use, high-strength performance, and engineering convenience

Active Publication Date: 2016-07-20
BEIJING UNIV OF CIVIL ENG & ARCHITECTURE +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Patent 201310252096 describes a method of making unburned bricks using water glass, active initiator, microsilica fume and red mud, but it requires steaming in an autoclave, which consumes high-grade energy
Patent CN200910162876 describes a method of road base and water stabilization layer: the main raw materials are low-temperature ceramic curing agent, red mud and aggregate, and the amount of red mud added is only 2-10%, and the utilization of red mud is relatively low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] The red mud solidifying agent of this embodiment includes 55kg slag powder, 25kg fly ash, 10kg Yellow River silt, 12kg catalytic activator, 1kg calcium carbonate whisker fiber. Among them, the specific surface area of ​​the slag powder is not less than 400㎡ / kg; the fly ash uses the secondary fly ash (in the present invention, the fly ash index is greater than or equal to the third-grade fly ash); the particle size of the Yellow River sediment is not greater than 100um and the 80um sieve of the Yellow River sediment is not more than 30%; the catalytic activator is made of sodium, potassium, calcium, magnesium oxides and / or sodium, potassium, calcium, magnesium salts compounded by crushing; catalytic In the activator, the weight fractions of the component containing sodium element, the component containing potassium element, the component containing calcium element and the component containing magnesium element are 55%, 10%, 25%, 10%, respectively, and the catalytic activa...

Embodiment 2

[0024] The red mud solidifying agent of this embodiment includes 55kg slag powder, 25kg fly ash, 10kg Yellow River silt, 12kg catalytic activator, 1kg calcium carbonate whisker fiber. Among them, the specific surface area of ​​the slag powder is not less than 300㎡ / kg; the fly ash uses secondary fly ash (in the present invention, the fly ash index is greater than or equal to the third-grade fly ash); the particle size of the Yellow River sediment is not greater than 100um and the 80um sieve of the Yellow River sediment is not more than 30%; the catalytic activator is made of sodium, potassium, calcium, magnesium oxides and / or sodium, potassium, calcium, magnesium salts compounded by crushing; catalytic In the activator, the weight fractions of the component containing sodium element, the component containing potassium element, the component containing calcium element and the component containing magnesium element are 55%, 10%, 25%, 10%, respectively, and the catalytic activator ...

Embodiment 3

[0028] The red mud solidifying agent in this embodiment includes 35kg slag powder, 45kg fly ash, 10kg Yellow River sediment, 12kg catalytic activator, and 1kg calcium sulfate whisker fiber. Among them, the specific surface area of ​​the slag powder is not less than 400㎡ / kg; the fly ash uses third-grade fly ash (in the present invention, the fly ash index is greater than or equal to the third-grade fly ash); the particle size of the Yellow River sediment is not greater than 100um and the 80um sieve of the Yellow River sediment is not more than 30%; the catalytic activator is made of sodium, potassium, calcium, magnesium oxides and / or sodium, potassium, calcium, magnesium salts compounded by crushing; catalytic In the activator, the weight fractions of the component containing sodium element, the component containing potassium element, the component containing calcium element and the component containing magnesium element are 45%, 15%, 25%, 15%, respectively, and the catalytic ac...

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Abstract

The invention discloses a red mud curing agent and a use thereof and belongs to the technical field of red mud comprehensive utilization. The red mud curing agent comprises 20-90 parts of slag powder, 1-50 parts of fly ash, 1-30 parts of silt, 5-15 parts of a catalysis exciting agent containing sodium, potassium, calcium and magnesium and 0.1-10 parts of whisker fibers. Fly ash and silt can well adjust a silicon-aluminum ratio of red mud and liquid-plastic limit index and improve engineering body strength performance indexes and engineering usability. Whisker fibers improve a flexural capability and crack resistance of the finished product. The red mud curing agent is powdery solid, is convenient for engineering use, and can be used by addition and stirring based on a ratio according to different engineering performance requirements. Through reasonable blending, the red mud curing agent can improve strength of a cured body containing red mud as a main component, completely satisfy building non-burnt brick, road base and surface layer engineering index requirements and realize large consumption of red mud.

Description

technical field [0001] The invention relates to the technical field of comprehensive utilization of red mud, in particular to a red mud solidifying agent and its application. Background technique [0002] Red mud is the alkali-containing solid waste produced in the process of producing alumina from bauxite. For every ton of alumina produced, about 0.8 to 1.8 tons of red mud are produced. my country is a major producer of alumina. In 2013, about 4375 tons of alumina were produced. 10,000 tons, accounting for 45.9% of the world's total output, and nearly 50 million tons of red mud produced. At present, the comprehensive utilization rate of red mud in my country is only about 4%, resulting in a large stockpiling of red mud. The statistical stockpiling in 2009 is about 200 million tons. Stockpiling not only occupies land resources, but also easily causes environmental pollution and potential safety hazards. [0003] At present, the comprehensive utilization of alumina red mud is...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/08C04B18/04
CPCY02W30/91
Inventor 王建国任淑珍任树忠
Owner BEIJING UNIV OF CIVIL ENG & ARCHITECTURE
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