Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of antifogging and antireflection film coating liquid

A technology of anti-reflection film and manufacturing method, which is applied in the direction of coating, etc., can solve the problems of glass surface clarity reduction, refractive index change, etc., achieve good optical performance, improve flexibility, and meet the effects of high-speed production

Inactive Publication Date: 2015-03-25
HARBIN INST OF TECH WUXI RES INST OF NEW MATERIALS +1
View PDF13 Cites 15 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the coating of silicon dioxide by titanium dioxide causes its refractive index to change, which in turn leads to a decrease in the clarity of the coated glass surface, and the coating is mainly suitable for glass products.
[0011] There is no report on the application of core-shell structured spherical acrylic acid and acrylate copolymer-silica colloidal nanocomposites for anti-fog and anti-reflective coatings

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of antifogging and antireflection film coating liquid
  • Preparation method of antifogging and antireflection film coating liquid
  • Preparation method of antifogging and antireflection film coating liquid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] (1) Disperse 4.625Kg of nano-silica with a particle size of 5nm in 87.875Kg of deionized water to prepare a dispersion with a concentration of 5%. Add 2.775Kg of ethanol to the dispersion to prepare a concentration of 5% by mass 3-(Methacryloyloxy)propyltrimethoxysilane solution, heated to 70°C under stirring, and kept at this temperature for 30 minutes;

[0057] (2) Add 2.9193Kg ethanol, 23.7513Kg deionized water, 1.190Kg acrylic acid, 0.158Kg methacrylic acid, 0.06625Kg ethylene glycol dimethacrylate dropwise to the solution of step (1) under stirring Mix the solution, stir and mix at 70°C for 40 minutes, then add 0.09225Kg potassium persulfate, react in a sealed reaction device for 8 hours, and obtain a core-shell structure spherical acrylic acid and difunctional methacrylate copolymer with a particle size of 35nm after cooling -Silicon dioxide colloidal nanocomposite light blue dispersion;

[0058] (3) Dilute the nanocomposite dispersion in step (2) with a deionize...

Embodiment 2

[0062] Change the consumption ratio of acrylic acid and methacrylic acid, add 1.058Kg acrylic acid, 0.315Kg methacrylic acid, repeat the manufacturing method of embodiment 1.

[0063] The performance test data of the obtained anti-fog and anti-reflection film are shown in Table 1.

Embodiment 3

[0065] Change the consumption ratio of acrylic acid and methacrylic acid, add 0.925Kg acrylic acid, 0.473Kg methacrylic acid, repeat the manufacturing method of embodiment 1.

[0066] The performance test data of the obtained anti-fog and anti-reflection film are shown in Table 1.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Particle sizeaaaaaaaaaa
Login to View More

Abstract

The invention discloses a preparation method of an antifogging and antireflection film coating liquid. The preparation method comprises the following steps: (1) dispersing nano silica in deionized water to prepare a dispersion liquid with mass percent concentration of 0.1-30%, adding a silane coupling agent to the dispersion liquid, heating to raise the temperature, and reacting for 0.2-1 hour; (2) adding a mixed solution which is formed by acrylic acids and acrylic esters and is diluted by a diluent to the solution in the step (1), stirring and mixing the solutions at 50-80 DEG C for 30-40 minutes, then adding an initiator, reacting for 5-10 hours, and cooling to obtain a nanocomposite dispersion liquid; (3) diluting the nanocomposite dispersion liquid in the step (2) into a solution with concentration of 0.1-50wt%. The preparation method has the beneficial effects that an in-situ free radical polymerization method is adopted, the coating effects are better, the coating can be ensured to have good apparent properties, and the coating is high in drying speed and has excellent antireflection and anti-dazzle effects.

Description

technical field [0001] The invention relates to the field of film materials, in particular to a method for manufacturing an anti-fog and anti-reflection film coating solution. Background technique [0002] In the case of sufficient water vapor, low wind force and stable atmosphere, if the air close to the ground is cooled to a certain extent, the water vapor in the air will condense into fine water droplets suspended in the air, reducing the visibility at the ground level. Known as fog, in autumn and winter, foggy days appear frequently. Fog is very harmful. In this weather, a layer of fog often appears on glass surfaces such as automobile glass and bathroom mirrors, which affects normal use. For example, if the windshield of a car is foggy, it will affect driving safety and even bring life danger. People who wear myopia glasses in winter often encounter the situation that a layer of fog occurs on the glasses when entering the warm room, which brings great inconvenience to ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C09D151/10C08J7/04C08L67/02C08F292/00
CPCC09D151/10C08F292/00C08J7/04C08J2367/02C08J2451/10C08F220/06
Inventor 白永平张福臣魏群黄玉东
Owner HARBIN INST OF TECH WUXI RES INST OF NEW MATERIALS
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products